journal article·2018-08

Ferroelectric yttrium doped hafnium oxide films from all-inorganic aqueous precursor solution

Xuexia Wang, Dayu Zhou, Shuaidong Li, Xiaohua Liu, Peng Zhao, Nana Sun, Faizan Ali, Jingjing Wang

Ceramics International· Volume 44· Issue 12
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Abstract

Abstract We report a unique aqueous solution deposition method to prepare yttrium doped hafnium oxide (Y:HfO2) thin films using all-inorganic reagents. The composition and chemical bonding features of the films were investigated using X-ray photoelectron spectroscopy. The Y:HfO2 film was integrated into metal-insulator-semiconductor (MIS) structure capacitors for electrical measurements. A transition of the polarization behavior from apparent ferroelectric-type to linear dielectric-type was observed for films with thickness increasing from 25 nm to 80 nm, which is correlated to the dominant crystal structure change from high-symmetry phase to monoclinic phase evidenced by grazing incidence X-ray diffraction analysis.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Ferroelectric and Negative Capacitance Devices · Semiconductor materials and devices · Electronic and Structural Properties of Oxides

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References (33)

Show source-provided references
1. Development of hafnium based high-k materials—A review10.1016/j.mser.2010.12.001 ↗
2. Ferroelectricity in hafnium oxide thin films10.1063/1.3634052 ↗
3. Ferroelectric Zr0.5Hf0.5O2 thin films for nonvolatile memory applications10.1063/1.3636417 ↗
4. Incipient Ferroelectricity in Al-Doped HfO2 Thin Films10.1002/adfm.201103119 ↗
5. Ferroelectricity in yttrium-doped hafnium oxide10.1063/1.3667205 ↗
6. Ferroelectric hafnium oxide: a CMOS-compatible and highly scalable approach to future ferroelectric memories
7. Ferroelectricity in Gd-Doped HfO2 Thin Films10.1149/2.002301jss ↗
8. Strontium doped hafnium oxide thin films: wide process window for ferroelectric memories
9. Ferroelectric phase stabilization of HfO2 by nitrogen doping10.7567/APEX.9.091501 ↗
10. Ferroelectricity in Simple Binary ZrO2 and HfO210.1021/nl302049k ↗
11. Ferroelectricity in undoped hafnium oxide10.1063/1.4922272 ↗
12. On the structural origins of ferroelectricity in HfO2 thin films10.1063/1.4919135 ↗
13. Co-sputtering yttrium into hafnium oxide thin films to produce ferroelectric properties10.1063/1.4747209 ↗
14. Impact of Scaling on the Performance of HfO2-Based Ferroelectric Field Effect Transistors10.1109/TED.2014.2354833 ↗
15. Understanding ferroelectric Al:HfO2 thin films with Si-based electrodes for 3D applications10.1063/1.4984068 ↗
16. Kinetic pathway of the ferroelectric phase formation in doped HfO2 films10.1063/1.5003918 ↗
17. Growth of (111)-oriented epitaxial and textured ferroelectric Y-doped HfO2 films for downscaled devices10.1063/1.4962431 ↗
18. Chemical solution deposition of ferroelectric yttrium-doped hafnium oxide films on platinum electrodes10.1063/1.4879283 ↗
19. Low-Energy Path to Dense HfO2 Thin Films with Aqueous Precursor10.1021/cm102082j ↗
20. Thickness-dependent phase evolution and dielectric property of Hf0.5Zr0.5O2 thin films prepared with aqueous precursor10.1007/s10971-015-3871-5 ↗
21. Chemical structure of the interface in ultrathin HfO2/Si films10.1063/1.1645984 ↗
22. Atomic layer deposition of Y2O3 and yttrium-doped HfO2 using a newly synthesized Y(iPrCp)2(N-iPr-amd) precursor for a high permittivity gate dielectric10.1016/j.apsusc.2014.01.032 ↗
23. Excellent resistive switching properties of atomic layer-deposited Al2O3/HfO2/Al2O3 trilayer structures for non-volatile memory applications10.1186/s11671-015-0846-y ↗
24. Switching mechanism of double forming process phenomenon in ZrOx/HfOy bilayer resistive switching memory structure with large endurance10.1063/1.4864396 ↗
25. First-principles study on doping and phase stability of HfO210.1103/PhysRevB.78.012102 ↗
26. Evolution of phases and ferroelectric properties of thin Hf0.5Zr0.5O2 films according to the thickness and annealing temperature10.1063/1.4811483 ↗
27. The Occurrence of Metastable Tetragonal Zirconia as a Crystallite Size Effect10.1021/j100888a024 ↗
28. The origin of ferroelectricity in Hf1−xZrxO2: a computational investigation and a surface energy model10.1063/1.4916707 ↗
29. Study on the internal field and conduction mechanism of atomic layer deposited ferroelectric Hf0.5Zr0.5O2 thin films10.1039/C5TC01074H ↗
30. Wake-up effects in Si-doped hafnium oxide ferroelectric thin films10.1063/1.4829064 ↗
31. Electric field cycling behavior of ferroelectric hafnium oxide10.1021/am504837r ↗
32. Ferroelectric phenomena in Si-doped HfO2 thin films with TiN and Ir electrodes10.1116/1.4873323 ↗
33. The Rayleigh law in silicon doped hafnium oxide ferroelectric thin films10.1002/pssr.201510270 ↗