Electrochemical performance of quaternary (1-x)ZnMn2O4/(x)MgFe2O4 solid solution as supercapacitor electrode
Source abstract
Abstract
Abstract Novel nano quaternary metals solid solutions from MgFe2O4 and ZnMn2O4 were synthesized using a sol-gel procedure. The development of a solid solution and the formed phase were examined by phase analysis utilizing the X'Pert High Score Plus program and Fourier transform infrared (FTIR) spectroscopy technique. Rietveld analysis of X-ray diffraction data (XRD), scanning electron microscope (SEM/EDS) and transmission electron microscope (TEM) were applied to determine the lattice parameters, crystallite size, different cations distribution and elemental analysis of the formed solid solutions. The measured dielectric properties of obtained solid solutions are found to be affected by the composition ratio (x). The solid solution (1-x)ZnMn2O4/(x)MgFe2O4 samples exhibited a ferroelectric–paraelectric transition at ferroelectric Curie temperature (Tc). The different hopping mechanisms in the different samples were also examined. The electrochemical performance was tested and influence of composition ratio (x) on the cathodic and anodic potential was investigated. The specific capacitance (Cs) value of electrodes depended on the composition ratio (x) beside the type of cations forming oxides. The (0.9)MgFe2O4/(0.1)ZnMn2O4 sample showed the best performance as a supercapacitor material. The outstanding electrochemical property of the (0.9)MgFe2O4/(0.1)ZnMn2O4 electrode was further confirmed by EIS inspection. The super stability of MgFe2O4/ZnMn2O4 solid solution could be attributed to the activation of the solid solution materials during the CV cycling and the synergistic effects.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Electromagnetic wave absorption materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (69)
Show source-provided references
1. Morphology-controllable preparation of NiFe2O4 as high performance electrode material for supercapacitor10.1016/j.electacta.2018.11.054 ↗
2. Nickel/cobalt bimetallic metal-organic frameworks ultrathin nanosheets with enhanced performance for supercapacitors10.1016/j.jallcom.2020.154069 ↗
3. Dandelion-like nickel/cobalt metal-organic framework based electrode materials for high performance supercapacitors10.1016/j.jcis.2018.07.044 ↗
4. Rubik's cube-like Ni3S4/CuS2 nanocomposite for high-performance supercapacitors10.1016/j.jallcom.2020.156312 ↗
5. Low-crystalline iron oxide hydroxide nanoparticle anode for high-performance supercapacitors10.1038/ncomms14264 ↗
6. Converting rust to PEDOT nanofibers for supercapacitors10.1021/acsaem.9b00244 ↗
7. Recent progress on integrated energy conversion and storage systems10.1002/advs.201700104 ↗
8. Materials science. Electrochemical capacitors for energy management10.1126/science.1158736 ↗
9. Hybrid energy storage device from binder-free zinc-cobalt sulfide decorated biomass-derived carbon microspheres and pyrolyzed polyaniline nanotube-iron oxide10.1016/j.ensm.2019.09.022 ↗
10. One-step accurate synthesis of shell controllable CoFe2O4 hollow microspheres as high-performance electrode materials in supercapacitor10.1007/s12274-016-1093-y ↗
11. How do pseudocapacitors store energy? Theoretical analysis and experimental illustration10.1021/acsami.6b14100 ↗
12. Hierarchical porous nickel oxide and carbon as electrode materials for asymmetric supercapacitor10.1016/j.jpowsour.2008.08.032 ↗
13. Copper molybdenum sulfide nanoparticles embedded on graphene sheets as advanced electrodes for wide temperature-tolerant supercapacitors10.1016/j.electacta.2018.02.116 ↗
14. Hierarchical carbon-decorated Fe3O4 on hollow CuO nanotube array: fabrication and used as negative material for ultrahigh-energy density hybrid supercapacitor10.1016/j.cej.2018.05.120 ↗
15. Spongelike nanosized Mn3O4 as a high-capacity anode material for rechargeable lithium batteries10.1021/cm201039w ↗
16. Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation10.1021/nn100740x ↗
17. In situ synthesis of CoFe2O4–Co rods as anode materials for lithium ion batteries10.1016/j.apsusc.2013.03.095 ↗
18. Novel nanocomposite of MnFe2O4 and nitrogen-doped carbon from polyaniline carbonization as electrode material for symmetric ultra-stable supercapacitor10.1016/j.electacta.2018.05.160 ↗
19. What are batteries, fuel cells, and supercapacitors?10.1021/cr020730k ↗
20. A comparative study on the supercapacitive behaviour of solvothermally prepared metal ferrite (MFe2O4, M = Fe, Co, Ni, Mn, Cu, Zn) nanoassemblies10.1016/j.jallcom.2018.02.127 ↗
21. Magnetic and photocatalytic properties of nanocrystalline ZnMn2O410.1007/s12034-009-0035-7 ↗
22. Fabrication of MgFe2O4–ZnO heterojunction photocatalysts for application of organic pollutants10.1016/j.matlet.2013.12.106 ↗
23. Role of cerium-doping in CoFe2O4 electrodes for high performance supercapacitors10.1016/j.est.2020.101452 ↗
24. Cu doped ZnO microballs as effective sunlight driven photocatalyst10.1016/j.ceramint.2016.01.154 ↗
25. In situ synthesis of 3D Co@Co3O4 nanosheet arrays for hybrid supercapacitors with ultra-high rate performance10.1016/j.jallcom.2020.154115 ↗
26. Sol-gel citrate synthesized Zn doped MgFe2O4 nanocrystals: a promising supercapacitor electrode material
27. NiMn2−xFexO4 prepared by a reverse micelles method as conversion anode materials for Li-ion batteries10.1016/j.matchemphys.2010.05.074 ↗
28. Ternary mixed nickel cobalt iron oxide nanorods as a high-performance asymmetric supercapacitor electrode10.1016/j.mtener.2019.06.009 ↗
29. Ismail · J. Electroanal. Chem. · 2018 · 817 · 11110.1016/j.jelechem.2018.04.002 ↗
30. Simple capacitors to supercapacitors - an overview10.1016/S1452-3981(23)15517-9 ↗
31. Metal oxide modified (NH4)(Ni,Co)PO4·0.67H2O composite as high-performance electrode materials for supercapacitors10.1016/j.inoche.2019.107696 ↗
32. Effect of synthesis methods on the surface and electrochemical characteristics of metal oxide/activated carbon composites for supercapacitor applications10.1016/j.apsusc.2018.09.079 ↗
33. Preparation and characterization of CoWO4/CoMn2O4 nanoflakes composites on Ni foam for electrochemical supercapacitor applications10.1016/j.est.2020.101483 ↗
34. Effect of magnesium deficiency on magnetic properties tuning and cation redistributions of magnesium ferrite nanoparticles10.1007/s10854-018-0348-7 ↗
35. Functional properties of ZnMn2O4/MWCNT/graphene nanocomposite as anode material for Li-ion batteries10.1007/s00339-020-03513-6 ↗
36. Effect of vanadium doping on structural and magnetic properties of defective nano-nickel ferrite10.1007/s00339-018-1721-3 ↗
37. Structural phase analysis, optical and magnetic properties of nano Mn-doped LiFe5O810.1007/s00339-018-2241-x ↗
38. Recent advances in magnetic structure determination by neutron powder diffraction10.1016/0921-4526(93)90108-I ↗
39. Total pattern fitting for the combined size–strain–stress–texture determination in thin film diffraction10.1016/j.nimb.2009.09.053 ↗
40. Structural, optical, and dielectric properties of nano-ZnMn2−xVxO410.1007/s10854-020-03429-0 ↗
41. Structural, infrared spectroscopy and magnetic properties of spinel ZnMn2O410.1016/j.physb.2019.08.005 ↗
42. Synthesis and optical property of one-dimensional spinel ZnMn2O4 nanorods10.1186/1556-276X-6-323 ↗
43. Efficient electrochemical performance of ZnMn2O4 nanoparticles with rGO nanosheets for electrodes in supercapacitor applications10.1007/s10854-017-8268-5 ↗
44. ZnO-based spinels grown by electrodeposition10.1016/j.jpcs.2012.04.002 ↗
45. Bilbao Crystallographic Server
46. Phase analysis and cation distribution correlated with magnetic properties of spinel Ba1−xSrxFe2O4 ferrites prepared at different annealing temperatures10.1007/s10854-020-03795-9 ↗
47. Influence of Mg-deficiency on the functional properties of magnesium ferrite anode material10.1016/j.ssi.2019.115042 ↗
48. Maxwell · 1973
49. On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies10.1103/PhysRev.83.121 ↗
50. Magnetic and electrical properties of in doped cobalt ferrite nanoparticles10.1063/1.4759436 ↗
51. Cation distribution controlled dielectric, electrical and magnetic behavior of In3+ substituted cobalt ferrites synthesized via solid-state reaction technique10.1016/j.matchemphys.2014.09.009 ↗
52. A.c. conduction in amorphous chalcogenide and pnictide semiconductors10.1080/00018738700101971 ↗
53. Cation distribution and dielectric properties of nanocrystalline gallium substituted nickel ferrite10.1016/j.jallcom.2013.10.137 ↗
54. Design and synthesis of FeMoO4/CuO for electrochemical energy storage system10.1016/j.molliq.2020.113693 ↗
55. Hierarchical porous ZnMn2O4 synthesized by the sucrose-assisted combustion method for high-rate supercapacitors10.1007/s11581-016-1817-8 ↗
56. PANI@Co-Porphyrins composite for the construction of supercapacitors10.1016/j.est.2019.101013 ↗
57. Flexible and conductive nanocomposite electrode based on graphene sheets and cotton cloth for supercapacitor
58. Microstructure and electrochemical properties of ZnMn2O4 nanopowder synthesized using different surfactants
59. Materials science for energy technologies, sol-gel citrate synthesized Zn doped MgFe2O4 nanocrystals
60. Understanding supercapacitors based on nano-hybrid materials with interfacial conjugation10.1016/j.pnsc.2013.04.001 ↗
61. High-performance supercapacitor electrodes based on highly corrugated graphene sheets10.1016/j.carbon.2012.01.028 ↗
62. Novel micron-sized NiCo2O4 pompon directed by a co-template method as capacitor electrode10.1016/j.matlet.2019.02.048 ↗
63. Selective synthesis of hierarchical mesoporous spinel NiCo2O4 for high-performance supercapacitors10.1039/c3nr06564b ↗
64. Performance of Centaurea cyanus aqueous extract towards corrosion mitigation of carbon steel in saline formation water10.1016/j.desal.2017.10.019 ↗
65. Spherical NiCo2O4/CuS composites for supercapacitor electrodes10.1016/j.matlet.2020.127400 ↗
66. Novel epoxy/metal phthalocyanines nanocomposite coatings for corrosion protection of carbon steel10.1016/j.molliq.2016.04.115 ↗
67. Controllable synthesis of porous NiCo2O4/NiO/Co3O4 nanoflowers for asymmetric all-solid-state supercapacitors
68. Novel ZnMoO4/reduced graphene oxide hybrid as a high-performance anode material for lithium ion batteries10.1016/j.jallcom.2017.03.078 ↗
69. Different distribution of in-situ thin carbon layer in hollow cobalt sulfide nanocages and their application for supercapacitors10.1016/j.jpowsour.2016.12.013 ↗