Dielectric, ferroelectric and energy storage properties of lead-free (1-x)Ba0.9Sr0.1TiO3-xBi(Zn0.5Zr0.5)O3 ferroelectric ceramics sintered at lower temperature
Source abstract
Abstract
Abstract Recently, ferroelectric ceramics with high maximum polarization, low remnant polarization and high electric breakdown strength (BDS) have attracted much attention due to their potential applications in energy storage capacitors. In this work, we show a novel kind of (Ba,Sr)TiO3 (BST)-based lead-free ferroelectric ceramics, i.e., (1-x)Ba0.9Sr0.1TiO3-xBi(Zn0.5Zr0.5)O3 (BST-xBZZ) solid solutions, which were fabricated by the traditional solid-state reaction process. By introducing the BZZ into BST with a content from 0.05 to 0.20, purely pseudocubic perovskite phases and highly dense structures are obtained. The increase of the BZZ content not only shifts the TC toward to lower temperature, but also induces strong relaxor behaviors with diffuse phase transition characteristics, thus improving the temperature stability of dielectric properties. Of special interest is the improved energy storage properties, which were systematically evaluated by measuring the polarization-electric field (P-E) hysteresis loops as a function of electric field, frequency and loading cycle. It is found that BT-0.15BZZ ceramic achieves a maximum energy density of 1.11 J/cm3, which is attributed to the improvement of BDS. In addition, relatively good frequency stability and fatigue resistance of this composition suggest its potential application in energy storage devices.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Dielectric materials and actuators · Microwave Dielectric Ceramics Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (86)
Show source-provided references
1. Homogeneous/inhomogeneous-structured dielectrics and their energy-storage performances10.1002/adma.201601727 ↗
2. Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction10.1021/acs.chemrev.5b00563 ↗
3. Design principles for solid-state lithium superionic conductors10.1038/nmat4369 ↗
4. Porous LiNi1/3Co1/3Mn1/3O2 microsheets assembled with single crystal nanoparticles as cathode materials for lithium ion batteries10.1016/j.jallcom.2018.07.268 ↗
5. 3D d-Ti3C2 xerogel framework decorated with core-shell SnO2@C for high-performance lithium-ion batteries10.1016/j.electacta.2018.07.198 ↗
6. Toward advanced sodium-ion batteries: a wheel-inspired yolk–shell design for large-volume-change anode materials10.1039/C8TA03772H ↗
7. Fabrication of Li4Ti5O12-tio2 nanosheets with structural defects as high-rate and long-life anodes for lithium-ion batteries10.1038/s41598-017-03149-2 ↗
8. Molecular dynamics investigations of mechanical behaviours in monocrystalline silicon due to nanoindentation at cryogenic temperatures and room temperature10.1038/srep16275 ↗
9. In situ synthesis of CNTs@Ti3C2 hybrid structures by microwave irradiation for high-performance anodes in lithium ion batteries10.1039/C7TA10394H ↗
10. Experimental study of single triple-phase-boundary and platinum-yttria stabilized zirconia composite as cathodes for micro-solid oxide fuel cells10.1016/j.jpowsour.2012.01.113 ↗
11. Recent progress on advanced materials for solid-oxide fuel cells operating below 500 °C10.1002/adma.201770345 ↗
12. Nanomaterials and technologies for low temperature solid oxide fuel cells: recent advances, challenges and opportunities10.1016/j.nanoen.2017.12.044 ↗
13. Anion exchange membrane fuel cells: current status and remaining challenges10.1016/j.jpowsour.2017.08.010 ↗
14. Ultra high energy density nanocomposite capacitors with fast discharge using Ba0.2Sr0.8TiO3 nanowires10.1021/nl3037273 ↗
15. High energy density in silver niobate ceramics10.1039/C6TA06353E ↗
16. Thermal annealing effects on the energy storage properties of BST ceramics10.1111/jace.14903 ↗
17. Phase transitions in bismuth-modified silver niobate ceramics for high power energy storage10.1039/C7TA03821F ↗
18. High-energy storage performance in lead-free (0.8-x)SrTiO3-0.2Na 0.5Bi0.5TiO3-xBaTiO3 relaxor ferroelectric ceramics10.1016/j.jallcom.2018.01.106 ↗
19. Phase transitions in tantalum-modified silver niobate ceramics for high power energy storage10.1039/C8TA10075F ↗
20. Ultrafine core-shell BaTiO3@SiO2 structures for nanocomposite capacitors with high energy density10.1016/j.nanoen.2018.07.006 ↗
21. Multilayer lead-free ceramic capacitors with ultrahigh energy density and efficiency
22. Decoding the fingerprint of ferroelectric loops: comprehension of the material properties and structures10.1111/jace.12773 ↗
23. Relaxor ferroelectric BaTiO3-Bi(Mg2/3Nb1/3)O3 ceramics for energy storage application10.1111/jace.13325 ↗
24. Dielectric and energy-storage performance of Ba0.5Sr0.5TiO3-SiO2 ceramic-glass composites10.1016/j.jallcom.2018.02.173 ↗
25. Dielectric and temperature stable energy storage properties of 0.88BaTiO3-0.12Bi(Mg1/2Ti1/2)O3 bulk ceramics10.1016/j.jallcom.2015.02.225 ↗
26. Reverse boundary layer capacitor model in glass/ceramic composites for energy storage applications10.1063/1.4775493 ↗
27. Superior energy storage properties and excellent stability of novel NaNbO3-based lead-free ceramics with A-site vacancy obtained via a Bi2O3 substitution strategy10.1039/C8TA07303A ↗
28. Energy storage properties in Ba0.4Sr0.6TiO3 ceramics with addition of semi-conductive BaO–B2O3–SiO2–Na2CO3–K2CO3 glass10.1016/j.jallcom.2014.08.038 ↗
29. Microstructure and ferroelectric properties of Nb2O5-modified BiFeO3-BaTiO3 lead-free ceramics for energy storage10.1016/j.matlet.2014.08.133 ↗
30. Lead-free relaxor ferroelectric ceramics with high optical transparency and energy storage ability10.1039/C5TC04005A ↗
31. Dielectric and energy storage properties of BaTiO3–Bi(Mg1/2Ti1/2)O3 ceramic: influence of glass addition and biasing electric field10.1016/j.ceramint.2016.08.005 ↗
32. Significantly enhanced recoverable energy storage density in potassium-sodium niobate-based lead free ceramics10.1039/C6TA04107H ↗
33. Effects of ZnNb2O6 addition on BaTiO3 ceramics for energy storage10.1016/j.mseb.2013.07.003 ↗
34. High-energy storage performance in lead-free (1-x)BaTiO3-xBi(Zn0.5Ti0.5)O3 relaxor ceramics for temperature stability applications10.1016/j.ceramint.2017.04.051 ↗
35. Novel BaTiO3-based lead-free ceramic capacitors featuring high energy storage density, high power density, and excellent stability10.1039/C8TC03003K ↗
36. Piezoelectric activity in Perovskite ferroelectric crystals10.1109/TUFFC.2014.006660 ↗
37. Electrostrictive effect in ferroelectrics: an alternative approach to improve piezoelectricity10.1063/1.4861260 ↗
38. High performance ferroelectric relaxor-PbTiO3 single crystals: status and perspective10.1063/1.3679521 ↗
39. What can be expected from lead-free piezoelectric materials?10.1142/S1793604710000919 ↗
40. Abnormal C–V curve and clockwise hysteresis loop in ferroelectric barium stannate titanate ceramics10.1016/j.mseb.2005.02.002 ↗
41. Designing lead-free bismuth ferrite-based ceramics learning from relaxor ferroelectric behavior for simultaneous high energy density and efficiency under low electric field10.1039/C8TC03855D ↗
42. High thermal stability of electric field-induced strain in (1−x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 lead-free ferroelectrics10.1016/j.jeurceramsoc.2018.09.019 ↗
43. BaTiO3-SrTiO3 layered dielectrics for energy storage10.1016/j.matlet.2010.12.043 ↗
44. Raman and dielectric study of Ba0.4Sr0.6TiO3-MgAl2O4 tunable microwave composite10.1063/1.3000057 ↗
45. Effect of grain size on the energy storage properties of (Ba0.4Sr0.6)TiO3 paraelectric ceramics10.1016/j.jeurceramsoc.2013.11.039 ↗
46. Effects of glass additions on the microstructure and dielectric properties of barium strontium titanate (BST) ceramics10.1016/j.jeurceramsoc.2009.05.003 ↗
47. Studies on electrical and dielectric properties of Ba1−xSrxTiO310.1016/j.matchemphys.2007.02.027 ↗
48. Dielectric and energy storage properties of Ba0.65Sr0.35TiO3 ceramics modified by BiNbO410.1007/s11664-018-6101-4 ↗
49. High electric field-induced strain with ultra-low hysteresis and giant electrostrictive coefficient in barium strontium titanate lead-free ferroelectrics10.1016/j.jeurceramsoc.2018.09.005 ↗
50. Electrocaloric behavior and temperature dependent scaling of dynamic hysteresis of BaxSr1-xTiO3 (x = 0.7, 0.8 and 0.9) bulk ceramics10.1007/s41779-017-0170-3 ↗
51. Electrically tunable dielectric materials and strategies to improve their performances10.1016/j.pmatsci.2010.04.004 ↗
52. Polarization relaxation mechanism of Ba0.6Sr0.4TiO3/Ni0.8Zn0.2Fe2O4 composite with giant dielectric constant and high permeability10.1063/1.3490782 ↗
53. Structure-property relationships in pure and acceptor-doped Ba1−xSrxTiO3 thin films for tunable microwave device applications10.1063/1.1484231 ↗
54. Ag-Ba0.75Sr0.25TiO3 composites with excellent dielectric properties10.1063/1.2836764 ↗
55. Electromechanical properties of (Ba,Sr)(Zr,Ti)O3 ceramics10.1016/j.ceramint.2016.03.137 ↗
56. Nonlinear dielectrc properties of (Ba,Sr)TiO3 and Ba(Zr,Ti)O3 thin films for tunable microwave device applications10.1080/10584580500414358 ↗
57. Creating adjoining polymorphic phase transition (PPT) regions in ferroelectric (Ba,Sr)(Zr,Ti)O3 ceramics10.1016/j.jeurceramsoc.2016.11.030 ↗
58. Tuning the ferroelectric transition and magnetic ordering by the polar Ba0.1Sr0.9TiO3 substitution in the multiferroic (1-x) Ba 0.1Sr 0.9 TiO3-xBiFeO3 (0.2≤ x ≤0.8) solid solution10.1016/j.jallcom.2018.02.012 ↗
59. Dielectric and tunable properties of Zr doped BST ceramics prepared by spark plasma sintering10.1016/j.jallcom.2012.04.010 ↗
60. Dielectric properties and energy storage density in ZnO-doped Ba0.3Sr0.7TiO3 ceramics10.1016/j.ceramint.2008.11.003 ↗
61. Dielectric and piezoelectric properties of (1-x)Ba0.67Sr0.33TiO3-xBa0.9Ca0.1Ti0.9Zr0.1O3 ceramics10.1007/s10971-015-3895-x ↗
62. Ba0.6Sr0.4TiO3 and BaZr0.3Ti0.7O3 thick films as tunable microwave dielectrics10.1016/S0955-2219(03)00481-3 ↗
63. Phase structure, microstructure, and electrical properties of bismuth modified potassium-sodium niobium lead-free ceramics10.1063/1.2775997 ↗
64. Ultrahigh energy density and improved discharged efficiency in bismuth sodium titanate based relaxor ferroelectrics with A-site vacancy10.1016/j.jmat.2018.05.006 ↗
65. BaTiO3-BiYbO3 perovskite materials for energy storage applications10.1039/C5TA03614C ↗
66. Relaxor ferroelectric 0.9BaTiO3-0.1Bi(Zn0.5Zr0.5)O3 ceramic capacitors with high energy density and temperature stable energy storage properties10.1039/C7TC02478A ↗
67. Evolution of phase transformation behavior and dielectric temperature stability of BaTiO3-Bi(Zn0.5Zr0.5)O3 ceramics system10.1016/j.jallcom.2012.09.127 ↗
68. Influence of structural evolution on energy storage properties in Bi0.5Na0.5TiO3-SrTiO3-NaNbO3 lead-free ferroelectric ceramics10.1063/1.4975409 ↗
69. Barium strontium titanate-based perovskite materials for microwave applications10.1016/j.progsolidstchem.2007.01.017 ↗
70. The dielectric properties and microstructure of BaTiO3 ceramics with ZnO-Nb2O5 composite addition10.1016/j.jallcom.2015.05.260 ↗
71. Revised effective ionic-radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
72. Dielectric properties of Zr substituted BST ceramics10.1016/j.ceramint.2011.03.080 ↗
73. A comparative study on electrical conduction properties of Sr-substituted Ba1-xSrxZr0.1Ti0.9O3 (x = 0.00-0.15) ceramics10.1007/s11581-017-2085-y ↗
74. Structural, dielectric and ferroelectric studies of Ba1-xSrxTiO3 ceramics prepared by mechanochemical activation technique10.1007/s10854-016-5060-x ↗
75. MgO-mixed Ba0.6Sr0.4TiO3 bulk ceramics and thin films for tunable microwave applications10.1063/1.1505669 ↗
76. Diffuse phase transitions and giant electrostrictive coefficients in lead-free Fe3+-doped 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 ferroelectric ceramics10.1021/acsami.6b08879 ↗
77. Influence of Zr substitution on ferroelectric properties of BST ceramics10.1080/07315171.2011.623609 ↗
78. Dielectric relaxation and phase transition behavior of (1-x)Pb(Zn1/3Nb2/3)O3-xBaTiO3 binary solid solutions10.1016/j.ceramint.2018.07.069 ↗
79. Effects of sintering temperature and KBT content on microstructure and electrical properties of (Bi.5Na.5)TiO3-BaTiO3-(Bi.5K.5)TiO3 Pb-free ceramics10.1016/j.ceramint.2018.02.142 ↗
80. Dielectric and microwave properties of barium strontium titanate (BST) thick films on alumina substrates10.1016/S0955-2219(03)00171-7 ↗
81. Electric-field-induced phase transition and large strain in lead-free Nb-doped BNKT-BST ceramics10.1016/j.jeurceramsoc.2013.07.014 ↗
82. Novel barium titanate based capacitors with high energy density and fast discharge performance10.1039/C7TA05392D ↗
83. Core-satellite BaTiO3@SrTiO3 assemblies for a local compositionally graded relaxor ferroelectric capacitor with enhanced energy storage density and high energy efficiency10.1039/C4TC02291B ↗
84. High field properties and energy storage in nanocomposite dielectrics of poly(vinylidene fluoride-hexafluoropropylene)10.1063/1.3609082 ↗
85. Domain wall contributions in Pb(Zr,Ti)O3 ceramics at morphotropic phase boundary: a study of dielectric dispersion10.1063/1.3455328 ↗
86. Dielectric relaxation and Maxwell-Wagner interface polarization in Nb2O5 doped 0.65BiFeO3–0.35BaTiO3 ceramics10.1063/1.4977107 ↗