journal article·2009-09

Synthesis and structure of PMN–PT ceramic nanopowder free from pyrochlore phase

M. Ghasemifard, S.M. Hosseini, Gh.H. Khorrami

Ceramics International· Volume 35· Issue 7
Publisher page

Abstract

Abstract Single-phase perovskite 0.65PMN–0.35PT nanopowders were synthesized at low temperature by the auto-combustion method. PMN–PT powder with 1 mol% of excess Pb(NO 3 ) 2 was prepared from the constituent nitrates and alkoxide materials. Perovskite PMN–PT powders without any pyrochlore phase were obtained after heat treatment at 850 °C. The average particles diameter is estimated to be around 25 nm. The formation of perovskite phase and the optical constants of powders have been estimated using Fourier transform infrared (FTIR) spectroscopy.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Relaxor ferroelectrics: an overview10.1080/00150199408244755 ↗
2. Evidence for MB and MC phases in the morphotropic phase boundary region of (1−x)[Pb(Mg1/3Nb2/3]–xPbTiO3: a Rietveld study10.1103/PhysRevB.67.064102 ↗
3. Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: the structure of PbZr0.52Ti0.48O310.1103/PhysRevB.61.8687 ↗
4. Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals10.1063/1.365983 ↗
5. Dielectric behavior of single crystals near the lead magnesium niobate–lead titanate (1−x)Pb(Mg1/3Nb2/3)O3–(x)PbTiO3) morphotropic phase boundary10.1080/07315179008201118 ↗
6. Piezoelectric PMN–PT ceramics from mechanochemically activated precursors10.1016/S0955-2219(03)00598-3 ↗
7. Transluant PMN and PMN–PT ceramics from high-energy ball milling derived powders10.1016/S0025-5408(01)00792-9 ↗
8. Preparation of Pb(Mg1/3Nb2/3)O3-PbTiO3 thin films by MOCVD using ultrasonic nebulization10.1007/s10832-006-5653-5 ↗
9. Fabrication and characterization of PMN–PT thin films
10. Low-temperature reactive sintering of 0.65PMN–0.35PT10.1111/j.1151-2916.2001.tb00716.x ↗
11. Double precursor solution coating approach for low-temperature sintering of [Pb(Mg1/3Nb2/3)O3]0.63[PbTiO3]0.37 solids10.1111/j.1551-2916.2007.02072.x ↗
12. Evidence for Mb and Mc phases in the morphotropic phase boundary region of (1−x)Pb(Mg1/3Nb2/3)O3–xPbTiO310.1103/PhysRevB.67.064102 ↗
13. Monoclinic structure of unpoled morphotropic high piezoelectric PMN–PT and PZN-PT compounds10.1103/PhysRevB.65.064106 ↗
14. Infrared studies of perovskite titanate10.1103/PhysRev.135.A408 ↗
15. Infrared-absorption studies on barium titanate and related materials10.1103/PhysRev.105.1740 ↗
16. Far infrared dielectric dispersion in BaTiO3, SrTiO3 and TiO310.1103/PhysRev.126.1710 ↗
17. Determination of optical constants of polymer films using a Fourier transform infrared reflection method, polyethylene terephthalate (PET)10.1366/0003702874867954 ↗
18. Optical constant determination of thin polymer films in the infrared10.1366/0003702854248539 ↗
19. Microstructural and optical characterization of PZT nanopowder prepared at low temperature10.1016/j.physe.2008.09.017 ↗
20. Determination of the thickness and optical constants of amorphous silicon10.1088/0022-3735/16/12/023 ↗
21. Optical properties of In2O3 films prepared by spray pyrolysis10.1016/j.matchemphys.2006.01.016 ↗
22. Bube · 1974
23. Elementary optical properties of solids
24. Optical constants of Germanium in the region 1 to 10eV10.1103/PhysRev.113.1002 ↗
25. Kramers-Kronig analysis of reflection data. III. Approximations, with reference to sodium iodide10.1088/0508-3443/17/10/309 ↗
26. Kramers–Kronig analysis of reflection data10.1088/0508-3443/16/8/310 ↗
27. Abramowitz · 1965
28. Reflection absorption infrared spectroscopy and the structure of molecular adsorbents on metal surfaces
29. Infrared spectra of monolayers on metal mirrors10.1364/JOSA.49.000131 ↗