journal article·2010-08

Microstructural features and electrical properties of copper oxide added potassium sodium niobate ceramics

Ebru Mensur Alkoy, Melih Papila

Ceramics International· Volume 36· Issue 6
Publisher page

Abstract

Abstract In this study, effects of 0.5, 1.0 and 1.5 mole% CuO addition on the properties of potassium sodium niobate (K 0.5 Na 0.5 )NbO 3 -KNN ceramics were investigated. Pure KNN and CuO-added KNN pellet samples were sintered at 1100 and 1090 °C for 4 h, respectively. Phase analysis showed that all samples crystallized in pure orthorhombic perovskite phase. Addition of 1.0 and 1.5 mole% CuO caused grain growth, densification and formation of a liquid phase at the grain boundaries. Curie temperature has shifted from 480 to 435 °C with increasing CuO ratio. The most remarkable characteristic of the hysteresis loops were the constricted nature of the 0.5 mole% CuO-added KNN's curve and the antiferroelectric-like appearance of the 1.5 mole% CuO-added KNN's curve. Piezeoelectric properties of d 33 = 120 pC/N, k p = 0.27 and Q m = 772 were obtained from the 1.5 mole% CuO-added KNN.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Multiferroics and related materials

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References (32)

Show source-provided references
1. Ferroelectric ceramics: history and technology10.1111/j.1151-2916.1999.tb01840.x ↗
2. Lead-free piezoceramics10.1038/nature03028 ↗
3. Dielectric and piezoelectric properties of Cu2+-doped alkali niobates10.1016/j.jeurceramsoc.2009.01.003 ↗
4. Sintering and piezoelectric properties of potassium sodium niobate ceramics with newly developed sintering aid10.1143/JJAP.44.258 ↗
5. Piezoelectric and dielectric properties of ceramics in the system potassium–sodium niobate10.1111/j.1151-2916.1959.tb12971.x ↗
6. Microstructure, dielectric and piezoelectric properties of (K0.5Na0.5)NbO3–Ba(Ti0.95Zr0.05)O3 lead-free ceramics with CuO sintering aid10.1007/s00339-007-3967-z ↗
7. Piezoelectric and ferroelectric properties of KxNa1−xNbO3 lead-free ceramics with MnO2 and CuO doping10.1016/j.jallcom.2007.06.128 ↗
8. Sinterability and piezoelectric properties of (K,Na)NbO3 ceramics with novel sintering aid10.1143/JJAP.43.7159 ↗
9. Influence of CuO on the structure and piezoelectric properties of the alkaline niobate-based lead-free ceramics10.1111/j.1551-2916.2006.01465.x ↗
10. Sintering, microstructure and piezoelectric properties of CuO and SnO2 co-modified sodium potassium niobate ceramics10.1016/j.materresbull.2009.09.033 ↗
11. Piezoelectric properties of Li- and Ta-modified (K0.5Na0.5)NbO3 ceramics10.1063/1.2123387 ↗
12. Electric-field-induced strain in Mn-doped KNbO3 ferroelectric ceramics10.1016/j.ceramint.2007.09.026 ↗
13. Phase transitional behavior and piezoelectric properties of (Na0.5K0.5)NbO3–LiNbO3 ceramics10.1063/1.1813636 ↗
14. Hydrothermal synthesis and piezoelectric property of Ta-doping K0.5Na0.5NbO3 lead-free piezoelectric ceramic10.1016/j.ceramint.2009.05.018 ↗
15. Structure and piezoelectric properties of Cu-doped potassium sodium tantalate niobate ceramics10.1016/j.matlet.2007.01.051 ↗
16. Property-processing relationship in lead-free (K, Na, Li)NbO3-solid solution system10.1007/s10832-007-9171-x ↗
17. Hot pressing of potassium-sodium niobates10.1111/j.1151-2916.1962.tb11127.x ↗
18. Normal sintering of (Na0.5K0.5)NbO3-based lead-free piezoelectric ceramics10.1016/j.ceramint.2007.09.025 ↗
19. The effects of sintering temperature on the properties of (Na0.5K0.5)NbO3–CaTiO3 based lead-free ceramics10.1016/j.sna.2007.05.020 ↗
20. Fabrication of lead zirconate titanate ceramic fibers by gelation of sodium alginate10.1016/j.ceramint.2005.09.021 ↗
21. Double hysteresis loop in Cu-doped K0.5Na0.5NbO3 lead-free piezoelectric ceramics10.1063/1.2746087 ↗
22. Enhancement of Qm by co-doping of Li and Cu to potassium sodium niobate lead-free ceramics10.1109/TUFFC.2008.743 ↗
23. Abnormal grain growth and new core–shell structure in (K,Na)NbO3-based lead-free piezoelectric ceramics10.1111/j.1551-2916.2007.01977.x ↗
24. Effect of CuO on the sintering temperature and piezoelectric properties of (Na0.5K0.5)NbO3 lead-free piezoelectric ceramics10.1111/j.1551-2916.2008.02408.x ↗
25. Templated grain growth of textured piezoelectric ceramics10.1080/10408430490490905 ↗
26. Grain size and domain size relations in bulk ceramic ferroelectric materials10.1016/0022-3697(96)00019-4 ↗
27. Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics10.1088/0034-4885/61/9/002 ↗
28. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenide10.1107/S0567739476001551 ↗
29. Piezoelectric and ferroelectric properties of Cu-doped K0.5Na0.5NbO3 lead-free ceramics10.1088/0022-3727/41/4/045401 ↗
30. Aging and the double hysteresis loop of PbλCa1−λTiO3 ceramics10.1111/j.1151-2916.1959.tb12939.x ↗
31. Aging behavior in single-domain Mn-doped BaTiO3 crystals: Implication for a unified microscopic explanation of ferroelectric aging10.1103/PhysRevB.73.094121 ↗
32. Double hysteresis loop and aging effect in K0.5Na0.5NbO3-K5.4Cu1.3Ta10O9 lead-free ceramics10.1111/j.1551-2916.2009.03062.x ↗