journal article·2024-07Open access

Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells

M.A. Islam, Ihsan Ahmad Siddiquee, Y.A. Wahab, S.F.W. Hatta, Jakaria Mahdi Imam, Foo Wah Low, Aziz Ahamed, Mohammad Nur-E Alam

Ceramics International· Volume 50· Issue 13

Abstract

Among the thin film-photovoltaics, perovskite solar cells (PSCs) are one of the most developing topics of research in recent times. Research records reveal that around 26 % efficiency in PSCs has already been achieved so far. However, the commercialization of those PSCs is hindered due to the toxicity of lead (Pb), and the instability of organic cations as well as structural volatility. Several inorganic materials including inorganic hole transport layer (HTL) have recently been proposed and developed to reduce the organic part in the device structure. We fabricate MoO3 thin film materials and conduct a detailed study to realize the potential of MoO3 as a unique HTL for application in PSCs. The synthesis of MoO3 thin film includes several characterization techniques e.g. XRD, FESEM, EDX, UV–Vis, and Hall Effect measurement. We design a MoO3 thin film-based, lead-free PSC structure of FTO/MoO3/PTAA/(FA)2BiCuI6/ZnO/Ag and perform numerical analysis using the SCAPS-1D simulation tool. In the device simulation process, we use the experimentally obtained optoelectrical properties of the MoO3 film and achieve a maximum efficiency of around 22.28 % in a contained lead-free PSC.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Organic Light-Emitting Diodes Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. Study of Pb-based and Pb-free perovskite solar cells using Cu-doped Ni1-xO thin films as hole transport material10.1016/j.ceramint.2022.02.051 ↗
2. Tuning the band gap edges of perovskite material by Cd doping for achieving high current density in perovskite solar cells10.1016/j.ceramint.2023.03.176 ↗
3. Sulfides as a new class of stable cost-effective materials compared to organic/inorganic hole transport materials for perovskite solar cells10.1016/j.ceramint.2022.03.163 ↗
4. High mobility reactive sputtered CuxO thin film for highly efficient and stable perovskite solar cells10.3390/cryst11040389 ↗
5. Optimizing physical properties of BiFe1-xMnxO3 perovskite thin films via a low-temperature sol-gel method10.1016/j.ceramint.2023.09.361 ↗
6. Dually-passivated planar SnO2 based perovskite solar cells with ˃2,700h ambient stability: facile fabrication, high performance and mechanism10.1016/j.ceramint.2022.07.342 ↗
7. Molecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells10.1038/s41467-018-04028-8 ↗
8. Advances in the application of perovskite materials10.1007/s40820-023-01140-3 ↗
9. A brief review of hole transporting materials commonly used in perovskite solar cells10.1007/s12598-020-01691-z ↗
10. Recent advances in spiro-MeOTAD hole transport material and its applications in organic–inorganic halide perovskite solar cells
11. Electrochromic properties of nanocrystalline MoO3 thin films10.1016/j.tsf.2007.09.019 ↗
12. MoO3 doped PTAA for high-performance inverted perovskite solar cells10.1016/j.apsusc.2021.151301 ↗
13. The effect of MoO3 interlayer on electro-physical characteristics of the perovskite solar cells10.1016/j.synthmet.2021.116903 ↗
14. Thermally-evaporated MoO3 and solution-processed PEDOT: PSS dual hole transport layer towards efficient planar perovskite solar cells
15. Photoelectrochemical study of MoO3 assorted morphology films formed by thermal evaporation10.1016/j.jechem.2016.04.005 ↗
16. Sol-gel spin coated well adhered MoO3 thin films as an alternative counter electrode for dye sensitized solar cells10.1016/j.solidstatesciences.2016.08.016 ↗
17. Nanostructured α-MoO3 thin film as a highly selective TMA sensor10.1016/j.bios.2013.09.057 ↗
18. Change of the properties of nanostructured MoO3 thin films using gamma-ray irradiation10.1016/j.ceramint.2018.04.040 ↗
19. Atomic layer deposition of MoO 3 on mesoporous γ-Al 2 O 3 prepared by sol–gel method as efficient catalyst for oxidative desulfurization of refractory dibenzothiophene compound10.1007/s10971-020-05332-w ↗
20. Structure and optical properties of MoO3 thin films prepared by chemical vapor deposition10.1002/pssa.2211090211 ↗
21. h-MoO3 microrods grown on wood substrates through a low-temperature hydrothermal route and their optical properties10.1007/s10854-016-5918-y ↗
22. Preparation of CsSnBr3 perovskite film and its all-inorganic solar cells with planar heterojunction10.1016/j.jssc.2020.121902 ↗
23. Ding · J. Cryst. Growth · 2006 · 294 · 30410.1016/j.jcrysgro.2006.07.004 ↗
24. Bouzidi · 2008 · vol. 5 · 26
25. High mobility reactive sputtered CuxO thin film for highly efficient and stable perovskite solar cells10.3390/cryst11040389 ↗
26. High mobility and transparent ZTO ETM prepared by RF reactive Co-sputtering for perovskite solar cell application10.1016/j.rinp.2019.102518 ↗
27. A statistical analysis of the elastic distortion and dislocation density fields in deformed crystals10.1016/j.jmps.2015.05.011 ↗
28. Electrochromic properties of MoO3 thin films derived by a sol–gel process10.1007/s10971-009-2055-6 ↗
29. A simple process for synthesis of transparent thin films of molybdenum trioxide in the orthorhombic phase (α-MoO3)10.1007/s11664-016-5239-1 ↗
30. Optical properties and surface morphology of evaporated (WO3)1− x–(Fe2O3)x thin films10.1016/j.tsf.2005.02.019 ↗
31. Optical band gap, local work function and field emission properties of MBE grown β-MoO3 nanoribbons10.1016/j.apsusc.2019.01.124 ↗
32. Enhanced charge carrier mobility in two‐dimensional high dielectric molybdenum oxide10.1002/adma.201203346 ↗
33. Physical investigations on Sb2S3 sprayed thin film for optoelectronic applications10.1016/j.mssp.2014.05.059 ↗
34. Low-resistance orthorhombic MoO3-x thin film derived by two-step annealing10.1016/j.tsf.2018.09.017 ↗
35. Deposition of multiphase molybdate thin films by reactive sputtering10.1016/S0040-6090(97)01031-6 ↗
36. Infrared and Raman spectra of MoO3 molybdenum trioxides and MoO3∙xH2O molybdenum trioxide hydrates10.1016/0584-8539(94)00247-9 ↗
37. Post-deposition annealed MoO3 film based high performance MSM UV photodetector fabricated on Si (100)10.1016/j.ceramint.2020.05.150 ↗
38. Postgrowth annealing effects on structural, optical, and electrical Properties of β-MoO3 films grown by molecular beam epitaxy
39. Enhanced charge carrier mobility in two-dimensional high dielectric molybdenum oxide10.1002/adma.201203346 ↗
40. Enhancement of efficiency of (FA) 2BiCuI6 based perovskite solar cells with inorganic transport layers
41. A review on the classification of organic/inorganic/carbonaceous hole transporting materials for perovskite solar cell application10.1016/j.arabjc.2018.06.006 ↗
42. A review of inorganic hole transport materials for perovskite solar cells10.1002/admi.201800882 ↗
43. NiOx/spiro hole transport bilayers for stable perovskite solar cells with efficiency exceeding 2110.1021/acsenergylett.9b02112 ↗
44. MoO3 doped PTAA for high-performance inverted perovskite solar cells10.1016/j.apsusc.2021.151301 ↗
45. The effect of MoO3 interlayer on electro-physical characteristics of the perovskite solar cells10.1016/j.synthmet.2021.116903 ↗
46. Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells10.1038/nenergy.2015.1 ↗
47. Why lead methylammonium tri-iodide perovskite-based solar cells require a mesoporous electron transporting sscaffold (but not necessarily a hole conductor)10.1021/nl404454h ↗
48. Impedance spectrometry of optimized standard and inverted P3HT-PCBM organic solar cells10.1016/j.solmat.2012.01.013 ↗
49. Simultaneously enhancing dissociation and suppressing recombination in perovskite solar cells10.1016/j.nanoen.2017.04.031 ↗
50. Device engineering for all-inorganic perovskite light-emitting diodes10.3390/nano9071007 ↗
51. Dynamic coupling between electrode interface and donor/acceptor interface via charge dissociation in organic solar cells at device-operating condition10.1021/acs.jpcc.5b00082 ↗