journal article·2021-01

Large strain with enhanced energy-storage and temperature stable dielectric properties in Bi0.38Na0.38Sr0.24Ti(1-)(Mn1/3Nb2/3) O3 ceramics

Mengyuan Li, Qiang Li, Benben Yan, Arun Kumar Yadav, Hao Wang, Guangzhi Dong, Huiqing Fan

Ceramics International· Volume 47· Issue 1
Publisher page

Abstract

Abstract A series of novel Bi0.38Na0.38Sr0.24Ti(1-x)(Mn1/3Nb2/3)xO3 lead-free ceramics (BNST-100xMN) were designed and fabricated. The dielectric, ferroelectric, energy-storage, electrostrain properties, and impedance performance of these materials were systematically investigated. A large strain response under low driving electric field was obtained that benefits from the enhanced relaxor-to-ferroelectric phase transition. The optimum piezoelectric stain coefficient d33* of 930 pm/V (under 40 kV/cm) was achieved in BNST-1MN composition. The substitution by MN dopant gave rise to a homogeneous micro-morphology with small grains that gave rise to an enhanced high breakdown strength (BDS). Slim and slanted ferroelectric hysteresis was obtained by introducing a larger amount of MN, and hence the BNST-2MN ceramic exhibits a high energy-storage density of 1.30 J/cm3 at 110 kV/cm, accompanied with an excellent fatigue-free behavior. The dielectric response exhibited a stable high temperature dielectric property with low dielectric loss. These results indicate that BNST-100xMN ceramics are promising candidates for the actuator and energy storage applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Multiferroics and related materials · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Ferroelectric ceramics: history and technology10.1111/j.1151-2916.1999.tb01840.x ↗
2. Giant electrostrains accompanying the evolution of a relaxor behavior in Bi(Mg,Ti)O3-PbZrO3-PbTiO3 ferroelectric ceramics10.1016/j.actamat.2013.02.055 ↗
3. A strain-driven morphotropic phase boundary in BiFeO310.1126/science.1177046 ↗
4. First-principles study of spontaneous polarization in multiferroic BiFeO3
5. Dielectric, ferroelectric, piezoelectric properties and impedance analysis of nonstoichiometric (Bi0.5Na0.5)0.94+xBa0.06TiO3 ceramics10.1016/j.jeurceramsoc.2016.06.032 ↗
6. Perspective on the development of lead-free piezoceramics10.1111/j.1551-2916.2009.03061.x ↗
7. Large strain response with low driving field in Bi1/2Na1/2TiO3-Bi1/2K1/2TiO3-Bi(Mg2/3Nb1/3)O3 ceramics10.1111/jace.15589 ↗
8. Additive effects on electrical properties of Bi1/2Na1/2TiO3 ferroelectric ceramics10.1016/S0955-2219(01)00005-X ↗
9. Poling temperature tuned electric-field-induced ferroelectric to antiferroelectric phase transition in 0.89Bi0.5Na0.5TiO3−0.06 BaTiO3−0.05K0.5Na0.5NbO3 ceramics10.1063/1.3660283 ↗
10. Large electrocaloric response and high energy-storage properties over a broad temperature range in lead-free NBT-ST ceramics10.1016/j.jeurceramsoc.2015.10.019 ↗
11. Optimized strain with small hysteresis and high energy-storage density in Mn-doped NBT-ST system10.1016/j.jeurceramsoc.2019.05.064 ↗
12. Defect dipole induced large recoverable strain and high energy-storage density in lead-free Na0.5Bi0.5TiO3-based systems10.1063/1.4950974 ↗
13. Simultaneously high-energy storage density and responsivity in quasi-hysteresis-free Mn-doped Bi0.5Na0.5TiO3-BaTiO3-(Sr0.7Bi0.2□0.1)TiO3 ergodic relaxor ceramics10.1080/21663831.2018.1457095 ↗
14. Significantly improved energy storage properties of sol-gel derived Mn-modified SrTiO3 thin films10.1016/j.ceramint.2019.03.056 ↗
15. The influence of A-site rare earth ion size in controlling the Curie temperature of Ba1-xRExTi1-x/4O310.1002/adfm.201201705 ↗
16. Effect of alkaline earth metal doping on thermal, optical, magnetic and dielectric properties of BiFeO3 nanoparticles10.1088/0022-3727/42/6/065004 ↗
17. Effect of Mn doping on the microstructure and magnetic properties of CuFeO2 ceramics10.1007/s40145-020-0387-4 ↗
18. Effect of oxygen treatment on structure and electrical properties of Mn doped Ca0.6Sr0.4TiO3 ceramics10.1016/j.jeurceramsoc.2018.01.027 ↗
19. Effect of grain size on the energy storage properties of Ba0.4Sr0.6TiO3 paraelectric ceramics10.1016/j.jeurceramsoc.2013.11.039 ↗
20. Dielectric properties and energy-storage performance of Na0.5Bi0.5TiO3 thick films10.1016/j.jallcom.2014.02.137 ↗
21. Strain properties of (1-x)Bi0.5Na0.4K0.1TiO3-xBi (Mg2/3Ta1/3)O3 electroceramics10.1016/j.ceramint.2020.05.203 ↗
22. Large electrostrictive strain in Bi0.5Na0.5 TiO3-BaTiO3-Sr0.7Bi0.2TiO3 solid solutions10.1111/jace.12712 ↗
23. Dielectric temperature stability and energy storage performance of B-site Sn4+-doped BNKBST ceramics10.1007/s10854-020-03918-2 ↗
24. Bi0.5Na0.5TiO3-BaTiO3-K0.5Na0.5NbO3: ZnO relaxor ferroelectric composites with high breakdown electric field and large energy storage properties10.1016/j.jeurceramsoc.2018.07.006 ↗
25. Effects of Mn doping on dielectric and ferroelectric properties of (Pb,Sr)TiO3 films on (111) Pt/Ti/SiO2/Si substrates10.1063/1.3257168 ↗
26. Lorentz-type relationship of the temperature dependent dielectric permittivity in ferroelectrics with diffuse phase transition10.1063/1.2987733 ↗
27. Composition- and temperature-dependent large strain in (1-x)(0.8Bi0.5Na0.5TiO3-0.2Bi0.5K0.5TiO3)-xNaNbO3 ceramics10.1111/jace.13407 ↗
28. Large strain of temperature insensitive in (1–x)(0.94Bi0.5Na0.5TiO3–0.06BaTiO3) –xSr0.7La0.2TiO3 lead-free ceramics10.1016/j.ceramint.2018.03.182 ↗
29. Electric field-induced ultrahigh strain and large piezoelectric effect in Bi1/2Na1/2TiO3-based lead-free piezoceramics10.1016/j.jeurceramsoc.2015.09.043 ↗
30. Ultrahigh strain in site engineering-independent Bi0.5Na0.5TiO3-based relaxor-ferroelectrics10.1016/j.actamat.2018.01.054 ↗
31. Novel bismuth ferrite-based lead-free incipient piezoceramics with high electromechanical response10.1039/C9TC00826H ↗
32. Ultrahigh piezoelectric properties in textured (K,Na)NbO3-based lead-free ceramics
33. High temperature dielectric, ferroelectric and piezoelectric properties of Mn-modified BiFeO3-BaTiO3 lead-free ceramics10.1007/s10853-016-0325-6 ↗
34. Nanoscale origins of small hysteresis and remnant strain in Bi0.5Na0.5TiO3-based lead-free ceramics10.1016/j.jeurceramsoc.2017.04.052 ↗
35. Electric-field-induced phase transition and large strain in lead-free Nb-doped BNKT-BST ceramics10.1016/j.jeurceramsoc.2013.07.014 ↗
36. Electric-field-temperature phase diagram and electromechanical properties in lead-free (Na0.5Bi0.5)TiO3-based incipient piezoelectric ceramics10.1016/j.jeurceramsoc.2016.12.020 ↗
37. Preparation and enhanced electrical properties of grain-oriented (Bi1/2Na1/2)TiO3-based lead-free incipient piezoceramics10.1016/j.jeurceramsoc.2015.03.012 ↗
38. Enhanced energy storage properties of NaNbO3 and SrZrO3 modified Bi0.5Na0.5TiO3 based ceramics10.1016/j.jallcom.2017.05.162 ↗
39. High energy storage density of 0.55Bi0.5Na0.5TiO3−0.45Ba0.85Ca0.15Ti0.9-xZr0.1SnxO3 ceramics10.1016/j.jallcom.2016.06.181 ↗
40. Donor-doping and reduced leakage current in Nb doped Na0.5Bi0.5TiO3
41. Crystal structure and enhanced electromechanical properties of Aurivillius ferroelectric ceramics, Bi4Ti3-x(Mg1/3Nb2/3)xO1210.1016/j.scriptamat.2013.11.025 ↗
42. Impedance and modulus spectroscopy of semiconducting BaTiO3 showing positive temperature coefficient of resistance10.1063/1.344049 ↗
43. Improvement of dielectric and ferroelectric properties in bismuth sodium titanate based relaxors through Bi non-stoichiometry10.1016/j.jallcom.2019.05.321 ↗