journal article·2020-07

Grain engineering inducing high energy storage in CdCu3Ti4O12 ceramics

Zhanhui Peng, Jitong Wang, Xiaobin Zhou, Jie Zhu, Xiaoping Lei, Pengfei Liang, Xiaolian Chao, Zupei Yang

Ceramics International· Volume 46· Issue 10
Publisher page

Abstract

Abstract ACu3Ti4O12-type ( A C T O ) perovskite ceramics with colossal permittivity always display a low energy storage density since its low breakdown field strength ( E b ). In this work, we designed an effective grain engineering strategy achieving a high energy storage density in CdCu3Ti4O12( C d C T O ) ceramics via a mixed oxides method based on sol-gel technique. Al2O3 was selected as grain engineering dopant enhancing E b for achieving the high energy storage density of C d C T O ceramics. Remarkably, at an Al2O3 doping level of 3.0 wt%, a decent dielectric energy storage performance with a high nonlinear coefficient ( α ) ~ 4.98 and energy storage density ( η ) ~ 1.52 mJ/cm3 was obtained in C d C T O -3.0 wt% Al2O3 ceramic. Besides, enhanced E b is strongly associated with the decreased grain size that induced upon Al2O3 doping. This work not only proposes an effective strategy enhancing E b but also provides new ideas for how to simultaneously achieve a high permittivity and high energy storage density in A C T O dielectric materials.
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Research context

OpenAlex topics: Dielectric properties of ceramics · Ferroelectric and Piezoelectric Materials · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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