Enhanced Piezoelectric Properties of (1-x)(0.8PZT-0.2PZN)-xBZT Ceramics via Phase Boundary and Domain Engineering
Source abstract
Abstract
Pb(Zr,Ti)O 3 -Pb(Zn 1/3 Nb 2/3 )O 3 (PZT-PZN) based ceramics, as important piezoelectric materials, have a wide range of applications in fields such as sensors and actuators, thus the optimization of their piezoelectric properties has been a hot research topic.This study investigated the effects of phase boundary engineering and domain engineering on (1-x)[0.8Pb(Zr0.5 Ti 0.5 )O 3 -0.2Pb(Zn1/3 Nb 2/3 )O 3 ]-xBi(Zn 0.5 Ti 0.5 )O 3 ((1-x)(0.8PZT-0.2PZN)-xBZT)ceramic to obtain excellent piezoelectric properties.The crystal phase structure and microstructure of ceramic samples were characterized.The results showed that all samples had a pure perovskite structure, and the addition of BZT gradually increased the grain size.The addition of BZT caused a phase transition in ceramic samples from the morphotropic phase boundary (MPB) towards the tetragonal phase region, which is crucial for optimizing piezoelectric properties.By adjusting content of BZT and precisely controlling position of the phase boundary, the piezoelectric performance can be optimized.Domain structure is one of the key factors affecting piezoelectric performance.By using domain engineering techniques to optimize grain size and domain size, piezoelectric properties of ceramic samples have been significantly improved.Specifically, excellent piezoelectric properties (piezoelectric constant d 33 =320 pC/N, electromechanical coupling factor k p =0.44) were obtained simultaneously for x=0.08.Based on experimental results and theoretical analysis, influence mechanisms of phase boundary engineering and domain engineering on piezoelectric properties were explored.The study shows that addition of BZT not only promotes grain growth, but also optimizes the domain structure, enabling the polarization reversal process easier, thereby improving piezoelectric properties.These research results not only provide new ideas for the design of high-performance piezoelectric ceramics, but also lay a theoretical foundation for development of related electronic devices.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (30)
Show source-provided references
1. FURUKAWA T, ISHIDA K, FUKADA E. Piezoelectric properties in the composite systems of polymers and PZT ceramics. J. Appl. Phys., 1979, 50(7): 4904.10.1063/1.325592 ↗
2. WU J, XIAO D, ZHU J. Potassium-sodium niobate lead-free piezoelectric materials: past, present, and future of phase boundaries. Chem. Rev., 2015, 115(7): 2559.10.1021/cr5006809 ↗
3. BENECH P, DUCHAMP J M. Piezoelectric materials and their applications in radio frequency domain and telecommunications. Adv. Appl. Ceram., 2015, 114(4): 220.10.1179/1743676115Y.0000000009 ↗
4. GUO R, CROSS L E, PARK S E, et al. Origin of the high piezoelectric response in PbZr1-xTixO3. Phys. Rev. Lett., 2000, 84(23): 5423.10.1103/PhysRevLett.84.5423 ↗
5. YAN Y, CHO K H, PRIYA S. Role of secondary phase in high power piezoelectric PMN-PZT ceramics. J. Am. Ceram. Soc., 2011, 94(12): 4138.10.1111/j.1551-2916.2011.04891.x ↗
6. GRINBERG I, SUCHOMEL M R, DAVIES P K, et al. Predicting morphotropic phase boundary locations and transition temperatures in Pb- and Bi-based perovskite solid solutions from crystal chemical data and first-principles calculations. J. Appl. Phys., 2005, 98(9): 094111.10.1063/1.2128049 ↗
7. REMA K P, KUMAR V. Structure-property relationship in Mn-doped (Pb0.94Sr0.06)(Zr0.53Ti0.47)O3. J. Am. Ceram. Soc., 2008, 91(1): 164.
8. YU X, HOU Y, ZHAO H, et al. Refreshing doping concept in perovskite piezoceramics: composite modulation hidden behind lattice substitution. J. Am. Ceram. Soc., 2020, 103(11): 6378.10.1111/jace.17361 ↗
9. QUANG D A, VUONG L D. Enhanced piezoelectric properties of Fe2O3 and Li2CO3 co-doped Pb[(Zr0.48Ti0.52)0.8(Zn1/3Nb2/3)0.125(Mn1/3Nb2/3)0.075]O3 ceramics for ultrasound transducer applications. J. Sci-Adv. Mater. Dev., 2022, 7(2): 100436.10.1016/j.jsamd.2022.100436 ↗
10. ZHENG M, HOU Y, ZHU M, et al. Nanodomains in metal/ ferroelectric0-3 type composites: on the origin of the strong piezoelectric effect. Scripta. Mater., 2018, 145: 19.10.1016/j.scriptamat.2017.10.007 ↗
11. YU X, HOU Y, ZHAO H, et al. The role of secondary phase in enhancing transduction coefficient of piezoelectric energy harvesting composites. J. Mater. Chem. C, 2019, 7(12): 3479.10.1039/C9TC00322C ↗
12. KIM S W, LEE H C. Development of PZN-PMN-PZT piezoelectric ceramics with high d33 and Qm values. Materials, 2022, 15(20): 7070.10.3390/ma15207070 ↗
13. LIU Q, SUN Q, MA W, et al. Large-strain 0.7Pb(ZrxTi1-x)O3- 0.1Pb(Zn1/3Nb2/3)O3-0.2Pb(Ni1/3Nb2/3)O3 piezoelectric ceramics for high-temperature application. J. Eur. Ceram. Soc., 2014, 34(5): 1181.10.1016/j.jeurceramsoc.2013.11.024 ↗
14. XU X, FENG X, ZHOU L, et al. Phase structure and electrical properties of 0.28PIN-0.32PZN-(0.4-x)PT-xPZ piezoelectric ceramics. Crystals, 2023, 13(9): 1362.10.3390/cryst13091362 ↗
15. WANG H, ZENG K. Humidity effects on domain structure and polarization switching of Pb(Zn1/3Nb2/3)O3-x%PbTiO3 (PZN-x%PT) single crystals. Materials, 2021, 14(9): 2447.10.3390/ma14092447 ↗
16. DU J, YANG C, LI Y, et al. Microstructural, dielectric, piezoelectric and ferroelectric properties of xPZN-PZT ternary ceramics. J. Mater. Sci-Mater. El., 2023, 34(9): 780.10.1007/s10854-023-10152-z ↗
17. SUCHOMEL M R, FOGG A M, ALLIX M, et al. Bi2ZnTiO6: a lead-free closed-shell polar perovskite with a calculated ionic polarization of 150 μC·cm-2 Chem. Mater., 2006, 18(21): 4987.10.1021/cm061085r ↗
18. YAN Y, CHO K H, PRIYA S. Identification and effect of secondary phase in MnO2-doped 0.8Pb(Zr0.52Ti0.48)O3-0.2Pb(Zn1/3Nb2/3)O3 piezoelectric ceramics. J. Am. Ceram. Soc., 2011, 94(11): 3953.
19. CAO W W, RANDALL C A. Grain size and domain size relations in bulk ceramic ferroelectric materials. J. Phys. Chem. Solids, 1996, 57(10): 1499.10.1016/0022-3697(96)00019-4 ↗
20. LI F, ZHANG S, XU Z, et al. Piezoelectric activity of relaxor- PbTiO3 based single crystals and polycrystalline ceramics at cryogenic temperatures: intrinsic and extrinsic contributions. Appl. Phys. Lett., 2010, 96(19): 192903.10.1063/1.3430059 ↗
21. LI F, ZHANG S, XU Z, et al. Composition and phase dependence of the intrinsic and extrinsic piezoelectric activity of domain engineered (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 crystals. J. Appl. Phys., 2010, 108(3): 034106.10.1063/1.3466978 ↗
22. ZHENG L, YI X, ZHANG S, et al. Complete set of material constants of 0.95(Na0.5Bi0.5)TiO3-0.05BaTiO3 lead-free piezoelectric single crystal and the delineation of extrinsic contributions. Appl. Phys. Lett., 2013, 103(12): 122905.10.1063/1.4821853 ↗
23. LI L, ZHANG J, WANG R X, et al. Thermally-stable large strain in Bi(Mn0.5Ti0.5)O3 modified 0.8Bi0.5Na0.5TiO3-0.2Bi0.5K0.5TiO3 ceramics. J. Eur. Ceram. Soc., 2019, 39(5): 1827.10.1016/j.jeurceramsoc.2019.01.009 ↗
24. LI L, ZHU M, WEI Q, et al. Microstructure and suppressed thermal depolarisation behaviours of lead-free Na0.5Bi0.5TiO3:ZnO ferroelectric composite ceramics. Adv. Appl. Ceram., 2017, 117(3): 133.10.1080/17436753.2017.1374317 ↗
25. WANG S, LI X, WANG J, et al. Enhanced electromechanical properties in MnCO3-modified Pb(Ni,Nb)O3-PbZrO3-PbTiO3 ceramics via defect and domain engineering. J. Am. Ceram. Soc., 2022, 106(3): 1970.10.1111/jace.18905 ↗
26. LU X M, HUANG F Z, ZHU J S. Domains in ferroelectrics: formation, structure, mobility and related properties. Acta Phys. Sin., 2020, 69(12): 127704.10.7498/aps.69.20200312 ↗
27. XUE H, ZHENG T, WU J. Understanding the nature of temperature stability in potassium sodium niobate based ceramics from structure evolution under external field. ACS Appl. Mater. Inter., 2020, 12(29): 32925.10.1021/acsami.0c08486 ↗
28. LIU Y X, LI Z, THONG H C, et al. Grain size effect on piezoelectric performance in perovskite-based piezoceramics. Acta Phys. Sin., 2020, 69(21): 217704.10.7498/aps.69.20201079 ↗
29. LI F, ZHANG S, YANG T, et al. The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals. Nat. Commun., 2016, 7: 13807.10.1038/ncomms13807 ↗
30. LI F, ZHANG S, DAMJANOVIC D, et al. Local structural heterogeneity and electromechanical responses of ferroelectrics: learning from relaxor ferroelectrics. Adv. Funct. Mater., 2018, 28(37): 1801504.10.1002/adfm.201801504 ↗