journal article·2016-09Open access

Efficient solution route to transparent ZnO semiconductor films using colloidal nanocrystals

Satoshi Suehiro, Keisuke Horita, Azzah Dyah Pramata, Masayoshi Yuasa, Yoichi Ishiwata, Kengo Shimanoe, Tetsuya Kida

Abstract

ZnO nanocrystals (NCs) were synthesized by heating Zn (II) acetylacetonate in oleic acid/oleylamine in the presence of 1,2-hexadecanediol at 220 °C. Transmission electron microscopy (TEM) and dynamic light scattering (DLS) measurements revealed the formation of monodispersed ZnO NCs of ca. 7 nm. ZnO NC assembled films were fabricated on a glass substrate by deposition with the colloidal ZnO NCs dispersed in toluene. The film composed of the NCs showed good optical transparency in the visible to near-infrared region. A device coupling the ZnO NC film with a p-type Cu2ZnSnS4 (CZTS) NC film exhibited an obvious diode-like current–voltage behavior. The results suggest that the transparent ZnO film has a potentiality to be used for an n-type window layer in some optoelectronic applications.
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Research context

OpenAlex topics: ZnO doping and properties · Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Japan Fine Ceramics Center (JFCC), Material Research and Development Laboratory2-4-1 Mutuno, Atsuta-kuNagoya 456-8587Japan

Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu UniversityKasuga Koen 6-1KasugaFukuoka816-8580Japan

Department of Applied Chemistry and Biochemistry, Kumamoto UniversityKurokami 2-29-1KumamotoKumamoto860-8555Japan

Department of Energy and Material Sciences, Kyushu UniversityKasuga Koen 6-1KasugaFukuoka816-8580Japan

Department of Physics, Saga UniversityHonjo 1SagaSaga849-8502Japan

Funding

Ministry of Education, Culture, Sports, Science and Technology of Japan · Kato Foundation for Promotion of Science

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