On the ways of generalization of adsorption kinetic equations for the case of energetically heterogeneous surfaces

Abstract In this work, we present three different ways of incorporation of the effects of surface energetic heterogeneity in the Statistical Rate Theory kinetic equation. These ways are critically discussed and finally, we come to the conclusion that the most consistent method is based on the assumption that the adsorbing surface should not be considered as composed from independent subsystems but it should be treated as one physical entity. As an illustration, we show the numerical analysis of the experimental data concerning the adsorption of CO 2 on scandia. The estimated best-fit parameters are physically correct and consistent with the results of calorimetric measurements.