The simplest model of adsorption of molecules with different orientations in adlayer on the stepped surface
Source abstract
Abstract
Abstract In this article we have constructed and studied using the Monte Carlo and transfer-matrix techniques the simple lattice gas models of self-assembled monolayer, which consists of molecules with different orientations in the adlayer on the stepped surfaces. It was shown that in the case of adsorption of complex molecules the surface heterogeneity of stepped type leads to a great variety of ordered structures comparatively with homogeneous one. The constructed models fairly well reproduce the main features of real SAMs consisting of molecules with different orientations with respect to interface and the model ordered phases are also analogues to the structures of real SAMs.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supramolecular Self-Assembly in Materials · Molecular Junctions and Nanostructures · nanoparticles nucleation surface interactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (36)
Show source-provided references
1. Multiple two-dimensional structures formed at monolayer and submonolayer coverages of p-sexiphenyl on the Au(111) surface10.1021/la052924b ↗
2. Controlled assembly of large π-conjugated n-type molecules on Au(111)10.1088/0957-4484/18/33/335302 ↗
3. Lehn · 1995
4. Solid-state structures of hydrogen-bonded tapes based on cyclic secondary diamides10.1021/cr00032a007 ↗
5. About supramolecular assemblies of π-conjugated systems10.1021/cr030070z ↗
6. Weak hydrogen bonds as a structural motif for two-dimensional assemblies of oligopyridines on highly oriented pyrolytic graphite: an STM investigation10.1021/jp054271d ↗
7. Porphyrin self-assembly at electrochemical interfaces: role of potential modulated surface mobility10.1021/ja026115f ↗
8. Structure formation in bis(terpyridine) derivative adlayers: molecule–substrate versus molecule–molecule interactions10.1021/la701382n ↗
9. Supramolecular nanostructures of 1,3,5-benzene-tricarboxylic acid at electrified Au(111)/0. 05M H2SO4 interfaces: an in situ scanning tunneling microscopy study10.1021/la0507737 ↗
10. Supramolecular assemblies of trimesic acid on a Cu(100) Surface10.1021/jp014214u ↗
11. Potential-induced phase transition of trimesic acid adlayer on Au(111)10.1021/jp035095g ↗
12. Multisite occupancy adsorption: comparative study of new different analytical approaches10.1021/la0209785 ↗
13. Application of the fractional statistical theory of adsorption (FSTA) to adsorption of linear and flexible k-mers on two-dimensional surfaces10.1021/ie0489397 ↗
14. Semiempirical model for adsorption of polyatomics10.1021/la053030u ↗
15. Monte Carlo study of dimer adsorption at monolayer on square lattices10.1016/S0039-6028(98)00337-9 ↗
16. Adsorption of dimer molecules on triangular and honeycomb lattices10.1021/la010465i ↗
17. Adsorption of linear k-mers on heterogeneous surfaces with simple topographies10.1021/la990643w ↗
18. Computer simulation of phase diagrams of trimers adsorbed on a square lattice10.1103/PhysRevB.67.045403 ↗
19. Monte Carlo study of adsorption of heteronuclear dimers on heterogeneous surfaces10.1016/S0040-6090(02)01261-0 ↗
20. Phase behavior of unsymmetrical dimers on a square lattice10.1016/j.susc.2005.12.014 ↗
21. Rudzinski · 1992
22. Jaroniec · 1988
23. Rudzinski · 1996
24. Zhdanov · 1991
25. Adsorption of asymmetric rigid rods or heteronuclear diatomic molecules on homogeneous surfaces10.1103/PhysRevB.70.165407 ↗
26. Phase transitions in a two-dimensional lattice gas model of orientable diatomic molecules10.1103/PhysRevB.72.165416 ↗
27. Phase transitions in a two-dimensional lattice gas model of orientable diatomic molecules. II. Order–disorder transitions of superantiferromagnetic and c(2×2)AF phases10.1103/PhysRevB.76.195409 ↗
28. The simplest self-assembled monolayer model with different orientations of complex organic molecules. Monte Carlo and transfer-matrix techniques10.1016/j.cej.2009.04.036 ↗
29. Modeling of adsorption and phase diagrams for stepped surfaces: transfer matrix approach10.1016/j.apsusc.2006.12.062 ↗
30. Exact finite method of lattice statistics. I. Square and triangular lattice gases of hard molecules10.1063/1.1727966 ↗
31. Three-state lattice gas on a triangular lattice as a model for multicomponent adsorption10.1016/0039-6028(88)90096-9 ↗
32. The effect of nearest-neighbour and next-nearest-neighbour lateral interactions on thermal desorption spectra10.1016/0009-2614(89)85063-8 ↗
33. Statistics of adsorption on top and bridge sites of a square lattice: transfer-matrix approach10.1007/BF02181238 ↗
34. Landau · 2000
35. Equation of state calculations by fast computing machines10.1063/1.1699114 ↗
36. Newman · 2001