Photoelectron spectroscopy study of surface alloying in the Au/Ni (s) 5(0 0 1) × (1 1 1) system

The growth of vapor-deposited Au on the stepped [5O 00 1UO 11 1U] nickel surface at room temperature was studied by Xray photoelectron and Auger electron spectroscopy (XPS/XAES) and ultraviolet photoelectron spectroscopy (UPS) for Au coverages ranging from about 0.2 up to 13 Ml. The Au 4f7/2 binding energy is initially lower than that of metallic gold and reaches its bulk value above 4 Ml. Helium II UPS exhibits an initial Au 5d doublet splitting of 1.5 eV, which increases up to the bulk value of 2.7 eV after 13 Ml of gold deposition, as well as an abnormally strong attenuation of the Ni 3d state up to a Au coverage of about 0.5 Ml. The results suggest charge transfer from Ni to Au and Au‐Ni surface alloying in the submonolayer regime. # 2001 Elsevier Science B.V. All rights reserved.