Excellent energy storage performance with outstanding thermal stability assisted by interfacial resistance of aramid-based flexible paper capacitors

Polymer-based dielectric energy storage capacitors show more potential than conventional rigidity ceramic-based capacitors. Recent studies were classified into two categories: the excellent room temperature performance in poly (vinylidene fluoride) (PVDF) systems and the enhanced thermal stability in polyimide-based systems. Only now, however, both of them are still far from commercial use because of their inferior heat resistance or poor processability. By adding BaTiO₃ (BT) particles in maturely used aramid nanofibers, we synthesized the aramid nanofiber (ANF)/BT-based flexible paper capacitors through a convenient industrialized technology in this work. Due to the intrinsic laminated structure of ANF and the uniform distribution of BT particles, the composite film with BT addition of 8 vol% exhibits outstanding dielectric thermal stability. With the help of the interfacial resistance in the organic–inorganic interface, which protected the ANF matrix from being breakdown too early by optimizing the electrical field distribution, a high and stable energy storage density of 6.70 J/cm³ was obtained in ANF/BT5. In addition, excellent energy storage frequency stability with ultrafast discharge speed was also achieved. This work offered a highly repeatable way to synthesize commercially used flexible capacitors, bridging the lab investigation and commercial use in high-power density energy storage polymers.