BaTiO ₃ -based multilayer ceramic capacitors with superior stability in energy-storage and pulse properties

Abstract Dielectric capacitors exhibiting high energy-storage properties and excellent pulse performance are critical components in advanced pulsed power systems. Multilayer ceramic capacitors (MLCCs) are the most widely used capacitors due to their high integration and excellent high-temperature endurance. Nevertheless, achieving high energy density and reliable performance over a wide temperature range and prolonged cycling remains the major challenge for existing commercial MLCCs based on linear dielectrics or Pb-based antiferroelectrics. Herein, we developed BaTiO3-based relaxor ferroelectric MLCCs with X9S characteristics for high-voltage applications. The BaTiO3-based MLCCs exhibit a good energy density of 6.09 J cm−3 and an ultrahigh efficiency of 98.2%, with superior stability in temperature (< 10%, 24–250 °C) and fatigue (after 106 cycles, < 4% at 200 °C). The pulse properties of MLCCs show minimal variation (< 4.5%, 22–200 °C). Moreover, 6878-size MLCCs with 300 nF can release a peak current of 3600 A at a rated voltage of 3000 V, which exhibits higher peak currents than linear MLCCs and better stability than Pb-based MLCCs. The excellent performance and superior stability demonstrate that relaxor ferroelectric MLCCs have great potential for advanced energy storage and pulsed power applications.