journal article·2019-07

Controllable synthesis of hierarchical polysilsesquioxane surfaces: from spheres-on-sphere to bowls-on-sphere structure

Liangyu Lu, Jian Li, Hongwei Li, Chengtao Gao, Haibo Xie, Yuzhu Xiong, Zhu Luo, Qi Sun, Fuping Dong

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Abstract

Abstract Hierarchical structured materials represent an interesting platform for many potential applications such as separation, catalyst and drug delivery etc. However, controlled fabrication of this special structure still remains a big challenge. In the present work, a controllable sol-gel procedure was developed to precisely fabricate polysilsesquioxane particles with bowls-on-sphere structure from mixed organoalkoxysilane precursors with sodium ligninsulfonate as surfactant and polystyrene spheres as structure-directing agents. The morphology of the particles can be fine-tuned by judiciously adjusting the ratio of two silane precursors, amount of ammonia, surfactant content and polystyrene amount. The formation mechanism of spheres-on-sphere structured polysilsesquioxane particles was explored.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Silicone and Siloxane Chemistry · Surface Modification and Superhydrophobicity · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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