journal article·2014-05

Diamond surface functionalization with biomimicry – Amine surface tether and thiol moiety for electrochemical sensors

James B. Sund, Corey P. Causey, Scott D. Wolter, Charles B. Parker, Brian R. Stoner, Eric J. Toone, Jeffrey T. Glass

Publisher page

Abstract

Abstract The surface of conducting diamond was functionalized with a terminal thiol group that is capable of binding and detecting nitrogen–oxygen species. The functionalization process employed multiple steps starting with doped diamond films grown by plasma enhanced chemical vapor deposition followed by hydrogen termination and photochemical attachment of a chemically protected amine alkene. The surface tether was deprotected to reveal the amine functionality, which enabled the tether to be extended with surface chemistry to add a terminal thiol moiety for electrochemical sensing applications. Each step of the process was validated using X-ray photoelectron spectroscopy analysis.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Molecular Junctions and Nanostructures · Force Microscopy Techniques and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Determination of the Tafel slope for oxygen evolution on boron-doped diamond electrodes10.1016/j.elecom.2008.02.003 ↗
2. Applications of diamond thin films in electrochemistry10.1557/S0883769400029389 ↗
3. Conductive diamond thin-films in electrochemistry10.1016/S0925-9635(03)00260-7 ↗
4. Diamond for bio-sensor applications10.1088/0022-3727/40/20/S21 ↗
5. Martin · 2005
6. The 5-V window of polarizability of fluorinated diamond electrodes in aqueous solutions10.1021/ac034717r ↗
7. Effect of electronic structures on electrochemical behaviors of surface-terminated boron-doped diamond film electrodes10.1016/j.diamond.2006.08.016 ↗
8. Effect of anodic and cathodic treatments on the charge transfer of boron doped diamond electrodes10.1016/j.diamond.2006.06.009 ↗
9. Sussmann · 2009
10. S-N dissociation energies of S-nitrosothiols: on the origins of nitrosothiol decomposition rates10.1021/ja0109390 ↗
11. Nitroxyl disulfides, novel intermediates in transnitrosation reactions10.1021/ja029655l ↗
12. Control of electron transfer kinetics at boron-doped diamond electrodes by specific surface modification
13. CasaXPS processing software offers powerful analysis techniques for both spectral and imaging data
14. Press · 1992
15. The correlation of redox potential, HOMO energy, and oxidation state in metal sulfide clusters and its application to determine the redox level of the FeMo-co active-site cluster of nitrogenase10.1021/ic060438l ↗
16. MO studies on S- to N-nitrosation rearrangement10.1021/jo00224a020 ↗
17. Photochemical functionalization of hydrogen-terminated diamond surfaces: a structural and mechanistic study10.1021/jp0545389 ↗
18. Morphology of heavily B-doped diamond films10.1557/JMR.1993.2845 ↗
19. DNA-modified nanocrystalline diamond thin-films as stable, biologically active substrates10.1038/nmat779 ↗
20. Briggs · 2003
21. Auger parameters for sulfur-containing compounds using a mixed aluminum-silver excitation source10.1016/0368-2048(90)87059-W ↗
22. Molecular spectroscopy by means of ESCA II. Sulfur compounds. Correlation of electron binding energy with structure10.1088/0031-8949/1/5-6/020 ↗
23. A novel self-assembling monolayer film containing a sulfone-substituted aromatic group10.1021/la00099a014 ↗
24. Synthesis and characterization of alkylaluminum compounds of pentafluorothiophenol. Crystal and molecular structure of [Me2Al (. mu. -SC6F5)] 210.1021/om00118a064 ↗
25. Nitrosonium-catalyzed decomposition of S-nitrosothiols in solution: a theoretical and experimental study10.1021/ja050018f ↗
26. Williams · 2004
27. Feelisch · 1996
28. High resolution X-ray photoelectron spectroscopy of L-cysteine self-assembled films10.1039/b405516k ↗
29. Interaction of acetic acid with ethylenediamine on a Ni(111) surface studied by XPS10.1016/0039-6028(86)90055-5 ↗
30. Angle-resolved XPS characterization of urea formaldehyde-epoxy systems10.1002/sia.1465 ↗
31. XPS studies of metal/polymer interfaces – Thin films of Al on polyacrylic acid and polyethylene10.1016/0169-4332(86)90107-8 ↗