journal article·2014-08

Photocatalytic anatase titanium dioxide thin films deposition by an atmospheric pressure blown arc discharge

Nicolas D. Boscher, Sébastien Olivier, Rémy Maurau, Simon Bulou, Thierry Sindzingre, Thierry Belmonte, Patrick Choquet

Publisher page

Abstract

A blown arc discharge fed with TIPO and N2 is studied for the deposition of TiO2 thin films.•Fine control of the deposition parameters allows to limit homogeneous gas-phase reactions.•Highly photocatalytic coatings have been grown at a substrate temperature below 490K. TiO2 thin films are deposited by means of an atmospheric pressure blown arc discharge fed with nitrogen and titanium bis(acetylacetonate) diisopropoxide (TIPO) as precursor. Different power densities and distances between the plasma nozzle, the precursor injector and the substrate are investigated and different morphologies, compositions and crystallinities of the coatings are generated. The photocatalytic properties of the coatings, determined from the degradation of stearic acid shined by a 254nm UV light, are shown to be strongly related to the film characteristic and therefore to the deposition parameters.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · TiO2 Photocatalysis and Solar Cells · Electrohydrodynamics and Fluid Dynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (28)

Show source-provided references
1. Transition metal oxides for organic electronics: energetics, device physics and applications10.1002/adma.201201630 ↗
2. Electrochemical photolysis of water at a semiconductor electrode10.1038/238037a0 ↗
3. A surface science perspective on TiO2 photocatalysis10.1016/j.surfrep.2011.01.001 ↗
4. Photocatalytic TiO2 nanoparticles enhanced polymer antimicrobial coating10.1016/j.apsusc.2013.11.067 ↗
5. Elaboration of a wide range of TiO2 micro/nanostructures by high power impulse inverted cylindrical magnetron sputtering10.1088/0022-3727/47/19/195201 ↗
6. Photocatalytic oxidation of deposited sulfur and gaseous sulfur dioxide by TiO2 films10.1021/jp070947o ↗
7. Atmospheric pressure MOCVD of TiO2 thin films using various reactive gas mixtures10.1016/j.surfcoat.2004.08.038 ↗
8. Thick titanium dioxide films for semiconductor photocatalysis10.1016/S1010-6030(03)00206-5 ↗
9. Characterisation of the photocatalyst Pilkington Activ™: a reference film photocatalyst?10.1016/S1010-6030(03)00205-3 ↗
10. Low-temperature synthesis and characterization of TiO2 and TiO2–ZrO2 photocatalytically active thin films10.1039/b817475j ↗
11. Growth of crystalline TiO2 by plasma enhanced chemical vapour deposition10.1021/cg9001779 ↗
12. In situ spectroscopic ellipsometry study of TiO2 films deposited by plasma enhanced chemical vapour deposition10.1016/j.apsusc.2013.06.091 ↗
13. Atmospheric pressure plasmas: a review10.1016/j.sab.2005.10.003 ↗
14. Advantages of a pulsed electrical excitation mode on the corrosion performance of organosilicon thin films deposited on aluminium foil by atmospheric pressure dielectric barrier discharge10.1002/ppap.200900094 ↗
15. Single-step process for the deposition of high water contact angle and high water sliding angle surfaces by atmospheric pressure dielectric barrier discharge10.1021/am302795v ↗
16. One step growth of TiO2 crystal trees by atmospheric pressure plasma jet10.1016/j.matlet.2011.05.054 ↗
17. Tuning Effect of N2 on atmospheric-pressure cold plasma CVD of TiO2 photocatalytic films plasma science and technology10.1088/1009-0630/15/1/11 ↗
18. Atmospheric cold plasmas for synthesizing nanocrystalline anatase TiO2 using dielectric barrier discharges10.1002/ppap.200600212 ↗
19. Production of titanium dioxide powders by atmospheric pressure plasma jet10.1016/j.phpro.2011.06.076 ↗
20. Atmospheric pressure, low temperature deposition of photocatalytic TiOx thin films with a blown arc discharge10.1016/j.surfcoat.2013.05.001 ↗
21. http://imagej.nih.gov/ij/.
22. Amorphous TiO2 in LP-OMCVD TiNxOy thin films revealed by XPS10.1016/S0169-4332(01)00220-3 ↗
23. Microstructural characterization of plasma sprayed TiO2 functional coating with gradient of crystal grain size10.1016/j.surfcoat.2005.10.033 ↗
24. Mesoporous TiO2 films fabricated using atmospheric pressure dielectric barrier discharge jet10.1021/am100731w ↗
25. Phonon confinement effects in the Raman scattering by TiO2 nanocrystals10.1063/1.120648 ↗
26. Uniform-size nanosphere, crystalline TiO2 films by a novel plasma CVD process at atmospheric pressure and room temperature10.1002/cvde.200604230 ↗
27. Correlation of thickness with the photocatalytic characteristic of TiO2 thin films
28. The gas nucleation process study of anatase TiO2 in atmospheric non-thermal plasma enhanced chemical vapor deposition10.1088/1009-0630/16/1/07 ↗