journal article·2003-12

Diagnosis of deactivation sources for vanadium catalysts used in SO2 oxidation reaction and optimization of vanadium extraction from deactivated catalysts

Mohamed Ksibi, Elimam Elaloui, Ammar Houas, Noomen Moussa

Applied Surface Science· Volume 220· Issue 1-4
Publisher page

Abstract

Abstract Physico-chemical analysis (X-ray, FTIR) and/or methanol oxidation reaction test were performed on fresh and deactivated vanadium catalysts used in H 2 SO 4 manufacturing. It allowed the diagnosis of catalyst deactivation sources, as well as the processes of regenerating and recycling the worn out catalyst in converter. One of these processes is hydrometallurgical method. It consists in treating the deactivated catalyst with alkaline or acidic reagents and forming vanadate solution. A simple and non-costly operation of chemical attack permits the extraction of vanadium from silica in deactivated catalyst. The extracted vanadium can be used for the confection of regenerated catalysts or metallic tools. After optimization, this method can be used for industrial application.
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Research context

OpenAlex topics: Catalysis and Oxidation Reactions · Metal Extraction and Bioleaching · Minerals Flotation and Separation Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Chem. Eng. News 23 June (1997) 42.
2. Urbanek · Catal. Rev.-Sci. Eng. · 1980 · 21 · 7310.1080/03602458008068061 ↗
3. Balzhinimaev · Faraday Discuss. Chem. Soc. · 1989 · 87 · 13310.1039/dc9898700133 ↗
4. Lapina · Prog. NMR Spectrosc. · 1992 · 24 · 45710.1016/0079-6565(92)80008-4 ↗
5. Matsui · J. Soc. Chem. Ind. Jpn. · 1937 · 40 · 465
6. Borskov · React. Kinet. Catal. Lett. · 1980 · 21 · 2510.1007/BF02061259 ↗
7. Lesokhin · Zhur. Priklac. Khim. · 1950 · 23 · 345
8. A.Z. Terlibaeva, V.A. Kozlova, L.K. Batrovka, The Complex Use of Mineral Raw Material, Alma-Ata., 1985 (in Russian).
9. Nikolaev · Zhur. Priklac. Khim. · 1967 · 30 · 285
10. Jpn. Patent Application 56-22636, ICP C01 31/00, C 22B 34/22, Removing Vanadium from Raw Materials.
11. Japanese Patent Application No. 5-96487.
12. Shirokov · Russ. Chem. Ind. · 1994 · 26 · 47
13. W.W. Scott, Standard Methods of Chemical Analysis, vol. 2, Van Nostrand, New York, 1958.
14. Hassan · J. Catal. · 1976 · 43 · 24310.1016/0021-9517(76)90310-9 ↗
15. Cherepkov · Kinet. Catal. · 1976 · 17 · 172
16. Mukhlenov · Zhur. Priklac. Khim. · 1952 · 25 · 793
17. Chang · J. Catal. · 1978 · 53 · 37410.1016/0021-9517(78)90109-4 ↗
18. Bensitel · Mater. Chem. Phys. · 1988 · 19 · 14710.1016/0254-0584(88)90007-7 ↗
19. N.B. Colthup, L.H. Daly, S.E. Wiberty, Introduction to Infrared and Raman Spectroscopy, Academic Press, New York, 1964.
20. Glazyrin · Zhur. Neorg. Khim. · 1980 · 25 · 3368
21. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part B, fifth ed., Wiley, New York, 1997.
22. U. Gerloff, J. Jhan, A. Schleicher, British Patent 1067083, 3 May 1967.
23. H. Freidrich, W. Neugebaur, German Patent 2145851, 22 March 1973; US Patent 3,843,562 (22 October 1974).
24. L. Cairati, P. Forzatti, F. Trifiro, P. Villa, in: H.F. Barry, P.C.H. Mitchell (Eds.), Proceedings of the Climax 4th International Conference on the Chemistry and Uses of Molybdenium, Climax Molybdenium Company, Ann Arbor, MI, 1982, p. 402.
25. Busca · J. Mol. Catal. · 1989 · 50 · 24110.1016/0304-5102(89)85067-9 ↗
26. Ai · J. Catal. · 1978 · 54 · 42610.1016/0021-9517(78)90090-8 ↗
27. J.M. Tatibouët, Appl. Catal. A: Gen. 148 (1997) 213–252.10.1016/S0926-860X(96)00236-0 ↗
28. A. Houas, M. Ksibi, E. Elaloui, Y. Zidi, J.M. Tatiboüet, J. Barrault, II ème Colloque International Environnement, Catalyse et Génie des Procédés ECGP’2 Fès-Morroco, 18–19 May 1998.
29. A. Jellouli, A. Walha, M. Fourati, A. Charfi, M. Chabouni, 1er Colloque Franco-Maghrébin de Catalyse, Hammamet, Tunisia, 1990.
30. Nogier · Catal. Today · 1994 · 20 · 2310.1016/0920-5861(94)85012-7 ↗
31. Livage · Chem. Mater. · 1991 · 3 · 57810.1021/cm00016a006 ↗