Formation and characterization of conductive thin layers of copper sulfide (CuxS) on the surface of polyethylene and polyamide by the use of higher polythionic acids

Abstract Layers of copper sulfide of varying composition and properties are formed on the surface of polyethylene and polyamide by a sorption–diffusion method using solutions of higher polythionic acids, H 2 S n O 6 . The concentration of sulfur adsorbed–diffused into PE and PA depends on the degree of the acid sulfurity, n , the temperature of the solution and the period of the polymer treatment. The amount of copper in a sulfide (Cu x S) layer formed after the sulfured polymer treatment with a solution of Cu(I–II) salt is strongly dependent on the concentration of sulfur in the PE and PA. By the chemical analysis of the obtained sulfide layers was determined that a value of x in the Cu x S layers varies in the interval 1 x x S layers obtained seven phases: with x = 2 (chalcocite), 1.9375 (djurleite), 1.8 (digenite), 1.75 (anilite), 1.12 (yarrowite), 1.06 (talnakhite) and 1 (covellite). The measurements of the electrical conductance of Cu x S layers (0.1–4 S cm −2 ) showed that its value greatly depends on the conditions of PE and PA interaction with H 2 S n O 6 and of further interaction with Cu(I–II) salt solution, on the chemical and phase composition of the layer.