journal article·2019-09

The ethanol-sensitive property of hierarchical MoO3-mixed SnO2 aerogels via facile ambient pressure drying

Haokun Li, Dachuan Zhu, Zhaoyun Yang, Wenrui Lu, Yong Pu

Publisher page

Abstract

Abstract Hierarchical SnO2 aerogels have attracted a wide interest for their semiconductivity. In this work, we synthesized the MoO3-mixed SnO2 aerogels via facile ambient pressure drying (APD). Simultaneously, the ethanol-sensitive property of MoO3-mixed SnO2 aerogels was studied, expected to explore their possible electrochemical applications in the future. Particularly, after the MoO3-mixed SnO2 aerogel was calcined in nitrogen, it showed a high response value (Ra/Rg) of 714 to 100 ppm ethanol at 260 °C. Besides, it also had characteristics of low response concentration, rapid response time and unique selectivity to ethanol. Combined with the analysis of various techniques, the mechanisms for gas-sensitivity have been discussed. The results demonstrate why MoO3-mixed SnO2 aerogel calcined in nitrogen has excellent gas-sensitivity to ethanol can be ascribed to its additional depletion layer and favorable hierarchical structure.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Transition Metal Oxide Nanomaterials · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Bowen Zhang, Wuyou Fu, Huayang Li, Xinglin Fu, Ying Wang, Hari Bala. Synthesis and characterization of hierarchical porous SnO2 for enhancing ethanol sensing properties. Appl. Surf. Sci. 363(2016)506–565.
2. Dongping Xue, Yan Wang, Jianliang Cao, Guang Sun, Zhanying Zhang. Improving methane gas sensing performance of flower-like SnO2 decorated by WO3 nanoplates. Talanta. 1999(2019)603–611.
3. Lei Wang, Dong Wang, Zhihui Dong, Fengxing Zhang, Jian Jin. Interface chemistry engineering for stable cycling of reduced GO/SnO2 nanocomposites for Lithium ion battery. Nano Lett. 13(2013)1711–1716.
4. Electrospun nanomaterials for supercapacitor electrodes: designed architectures and electrochemical performance10.1002/aenm.201601301 ↗
5. Felix Rechberger, Markus Niederberger. Synthesis of aerogels: from molecular routes to 3-dimensional nanoparticle assembly. Nanoscale Horiz. 2(2017)6–30.
6. Rapid synthesis of transition metal dichalcogenide-carbon aerogel composites for supercapacitor electrodes10.1038/micronano.2017.32 ↗
7. Yoon Kwang Lee, D.B. Mahadik, Taehee Kim, Wooje Han, Hyung Hee Cho, Hyung-Ho Park. Effect of differentiated textural properties of tin oxide aerogels on anode performance in lithium-ion batteries. J.Alloy.Compd. 732(2018)511–517.
8. D.B.Mahadik, Yoon Kwang Lee, Chang-Sun Park, Hee-Yoon Chung, Min-Hee Hong, Hae-Noo-Ree Jung, Wooje Han, Hyung-Ho Park. Effect of water ethanol solvents mixture on textural and gas sensing properties of tin oxide prepared using epoxide-assisted sol-gel process and dried at ambient pressure. Solid State Sci. 50(2015)1–8.
9. Ogawa H, Nishikawa M, Abe A. Hall measurement studies and electrical conduction model of tin oxide ultrafine particles films. J.Appl Phys. 253(1982)4448–4455.
10. Xu C N, Tamaki J, Miura N. Grain size effects on gas sensitivity of porous SnO2-based elements. Sensor Actuat B-Chem. 3(1991)147–155.
11. Rothchild A, Komen T. The effect of grain size on the sensitivity of nanocrystalline metal-oxide gas sensors. J.Appl Phys. 95(2004)319–336.
12. Jaya L. Mohanan, Indika U. Arachchige, Stephanie L. Brock. Porous semiconductor chalcogenide aerogels. Science. 307(2005)5708.10.1126/science.1104226 ↗
13. Emerging hierarchical aerogels: self-assembly of metal and semiconductor nanocrystals10.1002/adma.201707518 ↗
14. Jaswinder Kaur, V.D.Vankar, M.C. Bhatnagar. Role of surface properties of MoO3-doped SnO2 thin films on NO2 gas sensing. Thin Solid Films. 518(2010)3982–3987.
15. Juan Pablo Correa Baena. Alexander G. Agrios. Antimony-doped tin oxide aerogels as porous electron collectors for dye-sensitized solar cells. J.Phys Chem C. 118(2014)17028–17035.
16. Juan Pablo Correa Baena, Alexander G. Agrios. Transparent conducting aerogels of antimony-doped tin oxide. ACS Appl Mater Inter. 6(2014)19127–19134.
17. Siqi Liu, Xiezhen Zhou, Weiqing Han, Jiansheng Li, Xiuyun Sun, Jinyou Shen, Lianjun Wang. Preparation of mesoporous crack-free Sb-SnO2 xerogels through ambient-pressure drying and its application as three-dimensional electrode. J.Sol-Gel Sci Techn. 86(2018)479–492.
18. Haokun Li, Dachuan Zhu, Zhaoyun Yang. Synthesis and properties of SnO2 aerogels via ambient pressure drying of sol-gel. J.Mater.Res. 33(24)(2018)4192–4198.10.1557/jmr.2018.389 ↗
19. Haokun Li, Dachuan Zhu, Zhaoyun Yang. The effect of formamide on the microstructure of SnO2 aerogels. J. Sol-Gel Sci Techn. 90(2019)305–312.10.1007/s10971-019-04937-0 ↗
20. C.G. Carvajal, C. Snow-Davis, R. Mundle, A.K. Pradhan. VLS growth of highly oriented SnO2 nanorods and ZnO hybrid films for gas sensing measurements. J. Electrochem. Soc. 161 (2014), B3151-B4.10.1149/2.021402jes ↗
21. L. Dai, L.Wang, G.J. Shao, Y.H. Li, Z.C. Hao. An amperometric NO2 sensor based on nano-structured La0.75Sr0.25Cr0.5Mn0.5O3-δ prepared by impregnating method. J. Alloys Compd. 526 (2012) 145–150.
22. M. Di Giulio, G. Micocci, A. Serra, A. Tepore, R. Rella, P. Sicilian. SnO2 thin films for gas sensor prepared by r.f. reactive sputtering. Sensor Actuat B-Chem. 24-25(1995)465–468.10.1016/0925-4005(94)01397-7 ↗
23. Jose A. Jimenez, Esteban Rosim Fachini, Chunqing Zhao. XPS and 31P NMR inquiry of Eu3+-induced structural modification in SnO-containing phosphate glass. J.Mol Struct. 1164(2018)470–474.
24. Shar S. Al-Shihry, Samih A. Halawy. Unsupported MoO3-Fe2O3 catalysts: characterization and activity during 2-propanol decomposition. J. Mol Catal A-Chem. 113(1996)479–487.
25. M. Anwar, C. A. Hogarth, R. Bulpett. An XPS study of amorphous MoO3/SiO films deposited by co-evaporation. J. Mater. Sci. 25(1990)1784–1788.10.1007/BF01045385 ↗
26. Kan Zhang, Xin Yang, Yanzhe Wang, Yifei Bing, Liang Qiao, Zhongzhu Liang, Shansheng Yua, Yi Zeng, Weitao Zheng. Pd-loaded SnO2 ultrathin nanorod-assembled hollow microspheres with the significant improvement for toluene detection. Sensor Actuat B-Chem. 243(2017)465–474.
27. Yun Chen, Wen Zhang, Qingsheng Wu. A highly sensitive room-temperature sensing material for NH3: SnO2-nanorods coupled by rGO. Sensor Actuat B-Chem. 242(2017)1216–1226.10.1016/j.snb.2016.09.096 ↗
28. Wenqi Li, Shuyi Ma, Yingfeng Li, Guijin Yang, Yuzhen Mao, Jing Luo, Duojie Gengzang, Xiaoli Xu, Shaohui Yan. Enhanced ethanol sensing performance of hollow ZnO-SnO2 core-shell nanofibers. Sensor Actuat B-Chem. 211(2015)392–402.
29. Ding Wang, Minglu Zhang, Zhenlu Chen, Huijun Li, Aiying Chen, Xianying Wang, Junhe Yang. Enhanced formaldehyde sensing properties of hollow SnO2 nanofibers by graphene oxide. Sensor Actuat B-Chem. 250(2017)533–542.
30. Yuliang Wang, Xuchuan Jiang, Younan Xia. A solution-phase, precursor route to polycrystalline SnO2 nanowires that can be used for gas sensing under ambient conditions. J. Am. Chem. Soc. 125(2003)16176–16177.10.1021/ja037743f ↗
31. G. Eranna, B. C. Joshi, D. P. Runthala, R. P. Gupta. Oxide materials for development of integrated gas sensors—a comprehensive review. Crit Rev Solid State. 29(2004)111–188.
32. Jun Zhang, Shurong Wang, Yan Wang, Mijuan Xu, Huijuan Xia, Shoumin Zhang, Weiping Huang, Xianzhi Guo, Shihua Wu. Facile synthesis of highly ethanol-sensitive SnO2 nanoparticles. Sensor Actuat B-Chem. 139 (2009) 369–374.
33. Fengdong Qu, Yao Yuan, Minghui Yang. Programmed synthesis of Sn3N4 nanoparticles via a soft chemistry approach with urea: application for ethanol vapor sensing. Chem. Mater. 29(2017)969–974.
34. Minhua Cao, Yude Wang, Ting Chen, Markus Antonietti, Markus Niederberger. A highly sensitive and fast-responding ethanol sensor based on CdIn2O4 nanocrystals synthesized by a nonaqueous sol-gel route. Chem. Mater. 20(2008)5781–5786.
35. Qingji Wang, Xueying Kou, Chang Liu, Lianjing Zhao, Tingting Lin, Fangmeng Liu, Xueli Yang, Jun Lin, Geyu Lu. Hydrothermal synthesis of hierarchical CoO/SnO2 nanostructures for ethanol gas sensor. J.Colloid Interf Sci. 513(2018)760–766.
36. Zhidong Lin, Na Li, Zhe Chen, Ping Fu. The effect of Ni doping concentration on the gas sensing properties of Ni doped SnO2. Sensor Actuat B-Chem. 239(2017)501–510.
37. Vicinisvarri Inderan, M M Arafat, Sudesh Kumar, A S M A Haseeb, Zhong-Tao Jiang, Mohammednoor Altarawneh, Hooi Ling Lee. Study of structural properties and defects of Ni-doped SnO2 nanorods as ethanol gas sensors. Nanotechnology. 28(2017)1–11.
38. W.X. Jin, S.Y. Ma, Z.Z. Tie, J.J. Wei, J. Luo, X.H. Jiang, T.T. Wang, W.Q. Li, L. Cheng, Y.Z. Mao. One-step synthesis and highly gas-sensing properties of hierarchical Cu-doped SnO2 nanoflowers. Sensor Actuat B-Chem. 213(2015)171–180.
39. Lei Li, Minmin Liu, Shuijian He, Wei Chen. Freestanding 3D mesoporous Co3O4@carbon foam nanostructures for ethanol gas sensing. Anal. Chem. 86(2014)7996–8002.
40. Fengdong Qu, Yao Yuan, Minghui Yang. Programmed synthesis of Sn3N4 nanoparticles via a soft chemistry approach with urea: application for ethanol vapor sensing. Chem. Mater. 29(2017)969−974.
41. Yuxiao Gong, Yan Wang, Guang Su, Tiekun Jia, Lei Jia, Fengmei Zhang, Long Lin, Baoqing Zhang, Jianliang Cao, Zhanying Zhang. Carbon nitride decorated ball-flower like Co3O4 hybrid composite: hydrothermal synthesis and ethanol gas sensing application. Nanomaterials. 8(2018)132.
42. Minhua Cao, Yude Wang, Ting Chen, Markus Antonietti, Markus Niederberger. A highly sensitive and fast-responding ethanol sensor based on CdIn2O4 nanocrystals synthesized by a nonaqueous sol-gel route. Chem. Mater. 20(2008)5781–5786.
43. Jianliang Cao, Yuxiao Gong, Yan Wang, Bo Zhang, Huoli Zhang, Guang Sun, Hari Bala, Zhanying Zhang. Cocoon-like ZnO decorated graphitic carbon nitride nanocomposite: hydrothermal synthesis and ethanol gas sensing application. Mater. Lett. 198(2017)76–80.
44. Chu Thi Quy, Nguyen Xuan Thai, Nguyen Duc Hoa, Dang Thi Thanh Le, Chu Manh Hung, Nguyen Van Duy, Nguyen Van Hieu. C2H5OH and NO2 sensing properties of ZnO nanostructures: correlation between crystal size, defect level and sensing performance. RSC Adv. 8(2018)5629–5639.
45. Nguyen Thi Phuong Nhung, Pham Van Tong, Chu Manh Hung, Nguyen Van Duy, Nguyen Viet Chien, Nguyen Van Vinh, Nguyen Thai Tuyen, Nguyen Duc Hoa. Nanoporous ZnO nanostructure synthesis by a facile method for superior sensitivity ethanol sensor applications. RSC Adv. 6(2016)64215–64218.