Influence of silicon on the microstructure and mechanical properties of Zr–Si–N composite films

Abstract A series of Zr–Si–N composite films with different Si contents were synthesized in an Ar and N 2 mixture atmosphere by the bi-target reactive magnetron sputtering method. These films’ composition, microstructure and mechanical properties were characterized by energy dispersive spectroscopy, X-ray diffraction, scanning electron microscopy, atomic force microscopy and nanoindentation. Experimental results revealed that after the addition of silicon, Si 3 N 4 interfacial phase formed on the surface of ZrN grains and prevented them from growing up. Zr–Si–N composite films were strengthened at low Si content with the hardness and elastic modulus reaching their maximum values of 29.8 and 352 GPa at 6.2 at% Si, respectively. With a further increase of Si content, the crystalline Zr–Si–N films gradually transformed into amorphous, accompanied with a remarkable fall of films’ mechanical properties. This limited enhancement of mechanical properties in the Zr–Si–N films may be due to the low wettability of Si 3 N 4 on the surface of ZrN grains.