journal article·2002-10

Phosphating of bulk α-iron and its oxidation resistance at 400 °C

S Rebeyrat, J.L Grosseau-Poussard, J.F Silvain, B Panicaud, J.F Dinhut

Applied Surface Science· Volume 199· Issue 1-4
Publisher page

Abstract

Fe bulk specimen have been treated with phosphoric acid in order to obtain a conversion surface layer and the oxidation resistance has been studied by means of in situ thermogravimetric experiments in artificial air (20% O2; 80% N2). For oxidation time of 48 h at 400 °C it shows an important decrease of the oxidation kinetic in comparison with α-Fe. Moreover, the kinetic can be described by two successive parabolic stages. This behaviour is respectively related to an X-ray photoelectron spectroscopy (XPS) analysis of the surfaces and to previous results obtained on the oxidation of α-iron.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear Materials and Properties · High-Temperature Coating Behaviors · Metallurgical Processes and Thermodynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (20)

Show source-provided references
1. Rebeyrat · Thin Solid Films · 2000 · 379 · 13910.1016/S0040-6090(00)01416-4 ↗
2. G. Lorin, La Phosphatation des Métaux, ed Eyrolles, 1973.
3. Kir’yanov · Sov. Powder Metall. Mat. Ceram. · 1978 · 17 · 11010.1007/BF00796338 ↗
4. J.F. Moulder, W.F. Stickle, P.E. Sobal, K.D. Bomben, in: J. Chastain, R.C. King Jr. (Eds.), Handbook of X-Ray Photoelectron Spectroscopy, 1995.
5. Silvain · Surf. Coatings Technol. · 1993 · 61 · 24510.1016/0257-8972(93)90233-E ↗
6. McIntyre · Anal. Chem. · 1977 · 49 · 152110.1021/ac50019a016 ↗
7. Brundle · Surf. Sci. · 1977 · 68 · 45910.1016/0039-6028(77)90239-4 ↗
8. McIntyre · Anal. Chem. · 1975 · 47 · 220810.1021/ac60363a034 ↗
9. Grosseau-Poussard · App. Surf. Sci. · 1999 · 151 · 4910.1016/S0169-4332(99)00257-3 ↗
10. Brow · Phys. Chem. Glasses · 1994 · 35 · 3
11. Nemoshkalenko · Russ. J. Inorg. Chem. · 1983 · 28 · 1239
12. Stoch · Solid State Ionics · 1989 · 34 · 1710.1016/0167-2738(89)90424-4 ↗
13. Karabulut · J. Non-Crystal. Solids · 1999 · 249 · 10610.1016/S0022-3093(99)00332-4 ↗
14. Atkinson · J. Mater. Sci. · 1983 · 18 · 237110.1007/BF00541841 ↗
15. Graham · J. Electrom. Soc. · 1969 · 116 · 143010.1149/1.2411549 ↗
16. Jutte · Oxid. Metals · 1997 · 48 · 111
17. Devaux · Corr. Sci. · 1994 · 36 · 17110.1016/0010-938X(94)90118-X ↗
18. Marcus · Corr. Sci. · 1988 · 28 · 58910.1016/0010-938X(88)90026-1 ↗
19. S. Rebeyrat, J.L. Grosseau-Poussard, P.O. Renault, B. Panicaud, J.F. Dinhut, Mater. Sci. Eng. A, submitted for publication.
20. P.C.J. Graat, M.P.H. Brongers, H.W. Zandbergen, M.A.J. Somers, E.J. Mittemeijer, in: S.B. Newcomb, J.A. Little (Eds.), Proceedings of the Third International Conference on Microscopy of Oxidation 3, Trinity Hall, The Institute of Materials, 1997.