journal article·2016-10

Intelligent saline enabled self-healing of multilayer coatings and its optimization to achieve redox catalytically provoked anti-corrosion ability

Junaid Ali Syed, Shaochun Tang, Xiangkang Meng

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Abstract

Abstract To obtain a coating with both self-healing and redox catalytic ability to protect a metal substrate from corrosion under aggressive environment is strongly desired. Herein, we report the design and fabrication of intelligent polyaniline-polyacrylic acid/polyethyleneimine (PANI-PAA/PEI) multilayer composite coatings by spin assembly. The main influencing factors, including solution concentration (c) and disk rotating speed (ω) were studied in order to gain excellent performance. The resulting multilayer coatings with thickness in a range from 0.47 to 2.94 μm can heal severe structural damages and sustain a superior anti-corrosive performance for 120 h in 3.5% NaCl. The PANI-PAA layer enhances the anti-corrosion property and PEI layer contributes to the self-healing ability as well as their multilayer combination strengthens them. The improved self-healing ability is attributed to the rearrangement and reversible non-covalent interactions of the PANI-PAA and PEI layers that facilitates electrostatic repairing.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer composites and self-healing · Conducting polymers and applications · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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