journal article·2001-02

The transport mechanism of YSZ thin films prepared by MOCVD

Sung-Yong Chun, Nobuyasu Mizutani

Applied Surface Science· Volume 171· Issue 1-2
Publisher page

Abstract

Abstract The effect of microstructure and substrate on the electrical conductivity of yttria stabilized zirconia film (YSZ), prepared by metal–organic chemical vapor deposition (MOCVD), was investigated by complex impedance analysis. The electrical conductivity of the thin films with columnar structure was controlled by the oxygen ion conduction across the columnar grain boundary. The YSZ thin film deposited on Al 2 O 3 (1 0 2), MgO (1 0 0) and SiO 2 with columnar grains exhibit the electrical response of polycrystalline ceramic specimen. The dependence of activation energy and impedance diagram on substrate is increased according to the mismatch of thermal expansion coefficient between film and substrate.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Advanced ceramic materials synthesis · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (10)

Show source-provided references
1. Zirconia fuel cells and electrolyzers
2. Composants microioniques10.1016/0167-2738(83)90087-5 ↗
3. S. Chandra, Superionic Solids, North Holland, Amsterdam, 1981 (Chapter 6).
4. B.C.H. Steele, in: F.W. Poulsen, J.J. Bentzen, T. Jacobsen, E. Skou, M.J.L. Ostergard (Eds.), Proceedings of the Sixteenth Riso International Symposium on Material Science, Denmark, 1993, pp. 423–430.
5. J.A. Kilner, B.C.H. Steele, in: O.T. Sorenson (Ed.), Non-stoichiometric Oxides, Academic Press, London, 1981, pp. 233.10.1016/B978-0-12-655280-5.50010-9 ↗
6. Effect of impurities on sintering and conductivity of yttria-stabilized zirconia10.1007/BF01203473 ↗
7. Electronic conductivity of single crystal and polycrystalline yttria-stabilized zirconia
8. Experimental approach to the impedance spectroscopy technique10.1149/1.2086040 ↗
9. N. Ishizawa, A. saiki, N. Mizutani, M. Gato, Microstructure of the pore-free crystal of yttria-partially stabilized zirconia grown by an arc image floating-zone method, in: S. Somiya, N. Yamamoto, H. Yanagida (Eds.), Advances in Ceramics, Vol. 24, The Am. Ceram. Soc. Columbus, Ohio, 1988, pp. 479–484.
10. J.R. McDonald, Impedance Spectroscopy, Wiley, New York, 1987, pp. 217–223.