journal article·2009-12

Hot filament CVD of Fe–Cr catalyst for thermal CVD carbon nanotube growth from liquid petroleum gas

M. Akbarzadeh Pasha, A. Shafiekhani, M.A. Vesaghi

Applied Surface Science· Volume 256· Issue 5
Publisher page

Abstract

Abstract A hot filament chemical vapor deposition (HFCVD) method was used to prepare Fe–Cr thin film on Si substrate. The produced layers were used as catalysts for growing carbon nanotubes (CNTs) from liquid petroleum gas (LPG) at 825 °C by thermal CVD (TCVD) method. To characterize the obtained catalysts or CNTs, X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Raman spectroscopy were used. CNTs were grown on HFCVD derived Fe–Cr catalyst with the LPG as carbon source successfully. It was found that an annealing process on catalysts enhances the surface concentration of Cr atoms and reduces the sizes of catalyst particles. The grown CNTs on annealed sample were morphologically denser with smaller diameters compared to the as deposited one. In addition, the effect of filament temperature on CNTs was investigated. By increasing the filament temperature from 850 to 1050 °C the surface density and diameters of CNTs were improved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Fiber-reinforced polymer composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Helical microtubules of graphitic carbon10.1038/354056a0 ↗
2. Large-scale production of single-walled carbon nanotubes by the electric-arc technique10.1038/41972 ↗
3. Crystalline ropes of metallic carbon nanotubes10.1126/science.273.5274.483 ↗
4. Carbon nanotubes: opportunities and challenges10.1016/S0039-6028(01)01558-8 ↗
5. Carbon nanotube growth by PECVD: a review10.1088/0963-0252/12/2/312 ↗
6. Carbon nanostructures by hot filament chemical vapor deposition: growth, properties, applications10.1016/j.tsf.2005.10.054 ↗
7. Study on effects of substrate temperature on growth and structure of alignment carbon nanotubes in plasma-enhanced hot filament chemical vapor deposition system10.1016/j.apsusc.2006.01.025 ↗
8. The influences of synthesis temperature and Ni catalyst on the growth of carbon nanotubes by chemical vapor deposition10.1016/j.matlet.2007.09.003 ↗
9. Production of nanotubes by the catalytic decomposition of different carbon-containing compounds10.1016/S0926-860X(99)00561-X ↗
10. The catalyst in the CCVD of carbon nanotubes—a review10.1016/j.pmatsci.2005.04.003 ↗
11. Iron–cobalt catalysts synthesized by a reverse micelle impregnation method for controlled growth of carbon nanotubes10.1016/j.diamond.2008.01.049 ↗
12. Direct growth of aligned open carbon nanotubes by chemical vapor deposition10.1016/S0009-2614(98)01240-8 ↗
13. Patterned growth of individual and multiple vertically aligned carbon nanofibres10.1063/1.126705 ↗
14. Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition10.1063/1.1410322 ↗
15. Multilayered metal catalysts for controlling the density of single-walled carbon nanotube growth10.1016/S0009-2614(01)01148-4 ↗
16. The effect of reaction temperature on the diameter distribution of carbon nanotubes grown from ethylene decomposition over a Co–La–O catalyst10.1016/j.matchemphys.2008.05.081 ↗
17. High resolution TEM studies of carbon nanotubes produced by spray pyrolysis10.1016/j.optmat.2006.03.024 ↗
18. Thin film metallic catalyst coatings for the growth of multiwalled carbon nanotubes by pyrolysis of xylene10.1016/S0008-6223(02)00033-7 ↗
19. Formation of multi-walled carbon nanotubes by Ni-catalyzed decomposition of methane at 600–750°C10.1016/j.diamond.2008.01.074 ↗
20. Effect of temperature on the kinetics of acetylene decomposition over reduced iron oxide catalyst for the production of carbon nanotubes10.1016/j.apsusc.2008.07.096 ↗
21. Liquefied petroleum gas containing sulfur as the carbon source for carbon nanotube forests10.1016/j.carbon.2007.11.044 ↗
22. Carbon nanomaterials synthesized using liquid petroleum gas: analysis toward applications in hydrogen storage and production10.1016/j.ijhydene.2008.02.007 ↗
23. Synthesis of carbon nanotube from liquefied petroleum gas containing sulfur10.1016/S0008-6223(02)00244-0 ↗
24. Catalyst deactivation10.1016/S0920-5861(99)00074-7 ↗
25. Organometallic chemistry in the gas phase10.1021/cr00006a002 ↗
26. The effect of the Cr and Mo on the surface accumulation of copper in the electrodeposited Ni–Fe/Cu alloy films10.1016/j.mseb.2005.09.007 ↗
27. Synthesis of LaCrO3 films using spray pyrolysis technique10.1016/j.matlet.2006.07.153 ↗
28. A study of the core level electrons in iron and its three oxides by means of X-ray photoelectron spectroscopy10.1088/0022-3727/16/5/005 ↗
29. Field emission properties of vertically aligned carbon nanotubes grown on bias-enhanced hydrogen plasma-pretreated Cr film10.1016/S0040-6090(03)01022-8 ↗
30. Catalytic growth of carbon nanotubes over Ni/Cr hydrotalcite-type anionic clay and their hydrogen storage properties10.1016/j.apsusc.2004.08.014 ↗
31. CVD synthesis of single wall carbon nanotube under soft conditions10.1021/nl0255101 ↗
32. Double wall carbon nanotubes promoted by sulfur in a floating iron catalyst CVD system10.1016/S0009-2614(02)00600-0 ↗
33. The effect of sulfur on the number of layers in a carbon nanotube10.1016/j.carbon.2007.07.001 ↗
34. Saito · 1998