Stabilization of amorphous Cu2O on Ti3+-rich TiO2 via defect-mediated interfacial bonding for efficient photocatalytic CO2-to-CH4 conversion
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Catalytic Processes in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (63)
Show source-provided references
1. Global carbon budget
2. Carbon majors and the scientific case for climate liability10.1038/s41586-025-08751-3 ↗
3. Safeguarding crop photosynthesis in a rapidly warming world10.1126/science.adv5413 ↗
4. Designing a circular carbon and plastics economy for a sustainable future10.1038/s41586-023-06939-z ↗
5. High-current decoupled hydrogen and oxygen evolution via nickel–cobalt based redox mediators and bifunctional catalyst of 3D printing substrates10.1016/j.jcis.2024.10.148 ↗
6. Electrochemical cell designs for efficient carbon dioxide reduction and water electrolysis: status and perspectives
7. Hydrogenation of CO2 for sustainable fuel and chemical production10.1126/science.adn9388 ↗
8. Defects tune the strong metal–support interactions in copper supported on defected titanium dioxide catalysts for CO2 reduction10.1021/jacs.3c01336 ↗
9. Recent advances in diverse Mxenes‐based structures for photocatalytic CO2 reduction into renewable hydrocarbon fuels
10. Theoretical insights into heterogeneous (photo)electrochemical CO2 reduction10.1021/acs.chemrev.8b00481 ↗
11. Light-driven heterogeneous reduction of carbon dioxide: photocatalysts and photoelectrodes10.1021/acs.chemrev.5b00370 ↗
12. Surface strategies for catalytic CO2 reduction: from two-dimensional materials to nanoclusters to single atoms10.1039/C9CS00163H ↗
13. Photocatalytic CO2 conversion: what can we learn from conventional COx hydrogenation?10.1039/C9CS00920E ↗
14. Insight into the selectivity-determining step of various photocatalytic CO2 reduction products by inorganic semiconductors10.1021/acscatal.4c01712 ↗
15. One‐dimensional single‐crystal mesoporous TiO2 supported CuW6O24 clusters as photocatalytic cascade nanoreactor for boosting reduction of CO2 to CH4
16. Unveiling the size-dependent photothermal synergy of TiO2 in catalytic CO2 reduction10.1021/acssuschemeng.5c00354 ↗
17. Designed synthesis of Cu2O quantum dots/TiO2 nanotubes heterostructure as a photocatalyst for converting CO2 to CH4
18. Ab initio modelling of photocatalytic CO2 reduction reactions over Cu/TiO2 semiconductors including the electronic excitation effects
19. Unravelling charge dynamic effects in photocatalytic CO2 reduction over TiO2: anatase vs P2510.1016/j.cattod.2023.114279 ↗
20. Molecular dynamics characterization of Rutile-Anatase interfaces10.1021/jp0713211 ↗
21. Emerging strategies for CO2 photoreduction to CH4: from experimental to data‐driven desig
22. Bifunctional core–shell co-catalyst for boosting photocatalytic CO2 reduction to CH410.1007/s12274-023-6107-y ↗
23. Direct and indirect Z-scheme heterostructure-coupled photosystem enabling cooperation of CO2 reduction and H2O oxidation10.1038/s41467-020-16742-3 ↗
24. Facilely anchoring Cu2O nanoparticles on mesoporous TiO2 nanorods for enhanced photocatalytic CO2 reduction through efficient charge transfer10.1016/j.cclet.2021.10.047 ↗
25. Selective photocatalytic reduction of CO2 into CH4 over Pt-Cu2O TiO2 nanocrystals: the interaction between Pt and Cu2O cocatalysts10.1016/j.apcatb.2016.10.001 ↗
26. Boosting photocatalytic H2 evolution through interfacial manipulation on a lotus seedpod shaped Cu2O/g-C3N4 p-n heterojunction10.1039/D2SE01634F ↗
27. Epitaxial Cu2O thin films deposited from solution: the enabling role of Cu diffusion into the GaAs substrate10.1021/acsami.4c16485 ↗
28. Electronic metal-support interaction modulates Cu electronic structures for CO2 electroreduction to desired products10.1038/s41467-025-57307-6 ↗
29. Nature of metal-support interaction for metal catalysts on oxide supports10.1126/science.adp6034 ↗
30. Charge-mediated stable low-valence Cu on TiO2 for photocatalytic CO2-to-ethylene production10.1021/acsenergylett.4c00762 ↗
31. Synthesis of synergistic catalysts: integrating defects, SMSI, and plasmonic effects for enhanced photocatalytic CO2 reduction10.1039/D5SC01166C ↗
32. Engineering catalytic interfaces in Cuδ+ /CeO2 -TiO2 photocatalysts for synergistically boosting CO2 reduction to ethylene10.1021/acsnano.1c08505 ↗
33. Selective photoconversion of CO2 to C2H4 on asymmetrical CeO2 ─Cu2O interfaces driven by oxygen vacancies
34. Ce3+ /Ce4+ ion redox shuttle stabilized Cuδ+ for efficient CO2 electroreduction to C2H4
35. Overall water splitting by Pt/g-C3N4 photocatalysts without using sacrificial agents10.1039/C5SC04572J ↗
36. Nanoferrite-modified CuO/SnO2 nanocomposites with tunable magnetic and electrical properties for prospective applications10.1016/j.inoche.2025.115019 ↗
37. Shaping and doping metal–organic framework-derived TiO2 to steer the selectivity of photocatalytic CO2 reduction toward CH410.1021/acs.inorgchem.4c02407 ↗
38. On the combination of ultraviolet photoelectron spectroscopy with optical absorption studies to investigate Cu2O||TiO2 direct Z-scheme junctions with different Cu2O loading10.1016/j.apsusc.2024.159796 ↗
39. A photofuel cell-driven self-powered genosensor with a triple-quenching tag of p-Cu2O/Ti3C2T for signal amplification10.1016/j.snb.2023.135096 ↗
40. Synergistic interplay of CuOx and Pd nanodots on TiO2 for efficient and highly selective photocatalytic oxidation of CH4 to oxygenates with O210.1016/j.jcat.2024.115840 ↗
41. TiO2 /Cu2O core/ultrathin shell nanorods as efficient and stable photocatalysts for water reduction10.1002/anie.201509115 ↗
42. Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO210.1038/s41467-023-36778-5 ↗
43. Kinetics analysis of oxygen vacancies in TiO2 solar water reduction: revealing effects and eliminating disadvantages10.1016/j.jcis.2022.10.108 ↗
44. Hydrogenated anatase: strong photocatalytic dihydrogen evolution without the use of a Co‐catalyst10.1002/anie.201408493 ↗
45. Ultrahigh photocatalytic CO2 reduction efficiency and selectivity manipulation by single‐tungsten‐atom oxide at the atomic step of TiO210.1002/adma.202109074 ↗
46. Defining the role of excess electrons in the surface chemistry of TiO210.1021/jp101155t ↗
47. Surface-driven electron localization and defect heterogeneity in ceria
48. Construction of low‐cost z‐scheme heterostructure Cu2O/PCN for highly selective CO2 photoreduction to methanol with water oxidation10.1002/smll.202103558 ↗
49. Synergetic regulation of interfacial electronic structure of Cu, N co-doped carbon modified TiO2 for efficient photocatalytic CO2 reduction10.1016/j.cej.2024.153799 ↗
50. Promoting photocatalytic CO2 methanation by the construction of cooperative copper dual-active sites10.1021/acscatal.4c00060 ↗
51. Valence state effect of Cu on photocatalytic CO2 reduction
52. Photoinduced deposition of cubic Pd on the edge active sites of BiOCl to enhance photocatalytic CO2 reduction performance10.1016/j.jallcom.2025.179865 ↗
53. Efficient photoreduction of CO2 to CO with 100% selectivity by slowing down electron transport10.1021/jacs.3c14590 ↗
54. infrared spectroscopic study of the photoinduced activation of CO2 on TiO2 and Rh/TiO2 catalysts10.1021/j100080a009 ↗
55. Artificial photosynthesis over crystalline TiO2 -based catalysts: fact or fiction?10.1021/ja101318k ↗
56. An in-situ IR study on the adsorption of CO2 and H2O on hydrotalcites10.1016/j.jcou.2018.01.008 ↗
57. Synergistic effect of Cu single atoms and Au–Cu alloy nanoparticles on TiO2 for efficient CO2 photoreduction10.1021/acsnano.1c03961 ↗
58. Controlling the oxidation state of the Cu electrode and reaction intermediates for electrochemical CO2 reduction to ethylene10.1021/jacs.9b11126 ↗
59. Enhanced photocatalytic CO2 valorization over TiO2 hollow microspheres by synergetic surface tailoring and Au decoration10.1039/C8TA09661A ↗
60. Efficient visible‐light‐driven CO2 reduction mediated by defect‐engineered BiOBr atomic layers10.1002/anie.201803514 ↗
61. Highly selective CO2 electroreduction to C2H4 using a dual‐sites Cu(II) porphyrin framework coupled with Cu2O nanoparticles via a synergetic‐tandem strategy10.1002/anie.202407090 ↗
62. Direct observation on reaction intermediates and the role of bicarbonate anions in CO2 electrochemical reduction reaction on cu surfaces10.1021/jacs.7b10462 ↗
63. Visualizing the dynamic evolution of light-sensitive Cu1+/Cu2+ sites during photocatalytic CO2 reduction with an advanced in situ EPR spectroscopy10.1016/j.scib.2025.01.047 ↗