Modulation of p–d orbital hybridization in Pt-M(p-block) dual-atom catalysts to promote the activity of electrocatalytic nitrobenzene reduction
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Nanomaterials for catalytic reactions · Catalytic Processes in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (65)
Show source-provided references
1. Highly selective electroreduction of nitrobenzene to aniline by Co-doped 1T-MoS210.1021/acsami.4c01425 ↗
2. Recent progress toward electrocatalytic conversion of nitrobenzene10.1002/smtd.202301307 ↗
3. Doped activated carbons obtained from nitrogen and sulfur-containing polymers as metal-free catalysts for application in nitroarenes hydrogenation10.1016/j.ijhydene.2023.12.005 ↗
4. Theoretical study on nitrobenzene hydrogenation to aniline catalyzed by M1/CeO2−x(111) single-atom catalysts10.1039/D4CP04459B ↗
5. Axially coordinated Co–N4 sites for the electroreduction of nitrobenzene10.1039/D2TA07751E ↗
6. Voltage dependent high selectivity synthesis of aniline from nitrobenzene in a continuous flow anion exchange membrane water electrolyzer10.1016/j.seppur.2024.130244 ↗
7. Breaking the linear scaling limit in multi-electron-transfer electrocatalysis through intermediate spillover10.1038/s41929-025-01323-8 ↗
8. Reduction of CO2 to chemicals and Fuels: Thermocatalysis versus electrocatalysis10.1016/j.cej.2023.145033 ↗
9. Advancements in catalysts for selective hydrogenation of nitriles to amines10.1016/j.ijhydene.2025.01.216 ↗
10. Two-dimensional metal–organic frameworks with dual active sites for electrochemical CO2 reduction: A computational study10.1016/j.seppur.2024.131275 ↗
11. CdS@Ni3S2/Cu2S electrode for electrocatalysis and boosted photo-assisted electrocatalysis hydrogen production10.1016/j.seppur.2023.124085 ↗
12. Atomically dispersed Cu coordinated Rh metallene arrays for simultaneously electrochemical aniline synthesis and biomass upgrading10.1038/s41467-023-41423-2 ↗
13. Electrochemical hydrogenation of nitrobenzene: From electrocatalysis to redox mediator catalysis
14. Understanding the electrocatalytic mechanism of self-template formation of hierarchical Co9S8/Ni3S2 heterojunctions for highly selective electroreduction of nitrobenzene10.1039/D2SC03585E ↗
15. Simultaneously achieving high activity and selectivity toward two-electron O2 electroreduction: The power of single-atom catalysts10.1021/acscatal.9b02778 ↗
16. Highly efficient catalytic hydrogenation of nitrobenzene on cobalt- immobilized nitrogen-doped carbon: A dual-sites synergistic effect between cobalt single atoms and cobalt nanoparticles10.1016/j.cej.2024.157057 ↗
17. First principles study on the mechanism of nitrobenzene hydrogenation by a Ni1/CeO2-x(111) single-atom catalyst10.1021/acs.jpcc.3c03666 ↗
18. Recent advances in catalysts for selective hydrogenation of nitro compound10.1016/j.ijhydene.2025.04.195 ↗
19. Structure–activity relationship for the catalytic hydrogenation of nitrobenzene by single platinum atoms supported on nitrogen-doped carbon10.1021/acsanm.2c03361 ↗
20. Theoretical study on nitrobenzene hydrogenation by N-doped carbon-supported late transition metal single-atom catalysts10.1021/acscatal.2c02373 ↗
21. From single-atom to dual-atom: A universal principle for the rational design of heterogeneous fenton-like catalysts10.1021/acs.est.4c13826 ↗
22. Progress of synergistic oxygen electrocatalysis between single atoms and nanoparticles/clusters10.1016/j.ijhydene.2025.04.081 ↗
23. Investigating the effect of active site's coordination number on the oxygen reduction reaction activity of Fe-Co dual-atom catalysts: A theoretical study10.1016/j.ijhydene.2025.02.124 ↗
24. Synergy of dual-atom catalysts deviated from the scaling relationship for oxygen evolution reaction10.1038/s41467-023-40177-1 ↗
25. Tailoring atomic strain environment for high-performance acidic oxygen reduction by Fe-Ru dual atoms communicative effect10.1016/j.matt.2024.01.019 ↗
26. Intermetallic PtSn nanosheets with p–d orbital hybridization for selective hydroxylamine electrosynthesis10.1021/acsnano.5c00544 ↗
27. Dual-atomic-site catalysts for molecular oxygen activation in heterogeneous thermo-/electro-catalysis
28. Boosting oxygen reduction reaction with Fe and Se dual-atom sites supported by nitrogen-doped porous carbon10.1016/j.apcatb.2022.121206 ↗
29. Long-range interactions in diatomic catalysts boosting electrocatalysis10.1002/anie.202213318 ↗
30. Sulfur-doping tunes p-d orbital coupling over asymmetric Zn-Sn dual-atom for boosting CO2 electroreduction to formate10.1038/s41467-025-57573-4 ↗
31. High-throughput screening of heterogeneous transition metal dual-atom cxatalysts by synergistic effect for nitrate reduction to ammonia10.1002/adfm.202301493 ↗
32. A highly efficient and regenerable Ir1–Cu1 dual-atom catalyst for low-temperature alkane dehydrogenation10.1038/s41929-025-01328-3 ↗
33. Activated d-electrons of p-block metals by reconfigured electron spin for kinetically boosting sulfur conversion of lithium-sulfur batteries10.1016/j.nanoen.2025.110979 ↗
34. p-d orbital hybridization induced by asymmetrical FeSn dual atom sites promotes the oxygen reduction reaction10.1021/jacs.4c03576 ↗
35. Spin regulation for efficient electrocatalytic N2 reduction over diatomic Fe-Mo catalyst10.1016/j.jcis.2022.10.099 ↗
36. Tailoring asymmetric RuCu dual-atom electrocatalyst toward ammonia synthesis from nitrate10.1038/s41467-025-57463-9 ↗
37. Rational design of optimal bimetallic and trimetallic nickel-based single-atom alloys for bio-oil upgrading to hydrogen10.1038/s41467-025-57949-6 ↗
38. Atomically dispersed Co–Ru dimer catalyst boosts conversion of polysulfides toward high-performance lithium–sulfur batteries
39. Performance evaluation of homogeneous dual-atom site M2-N6-graphene catalysts for hydrogen evolution reaction10.26599/NR.2025.94907004 ↗
40. Hybrid double atom catalysts for hydrogen evolution reaction: A sweet marriage of metal and nonmetal
41. Heteroatom doping-induced Pt dispersion and electronic effect for boosting the catalytic performance in the hydrogenation of nitrobenzene to p-aminophenol10.1016/j.cej.2024.150329 ↗
42. Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation10.1038/s41467-021-23517-x ↗
43. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
44. Accurate molecular van der waals interactions from ground-state electron density and free-atom reference data10.1103/PhysRevLett.102.073005 ↗
45. A generalized synchronous transit method for transition state location10.1016/S0927-0256(03)00111-3 ↗
46. C2H2 hydrochlorination over the diatomic RuM catalysts anchored over the N-doped graphene: Influences of metal M type and coordination environment10.1016/j.apsusc.2022.154583 ↗
47. Asymmetric activation of the nitro group over a Ag/graphene geterointerface to boost highly selective electrocatalytic reduction of nitrobenzene10.1021/acsami.2c04533 ↗
48. Origin of the overpotential for oxygen reduction at a fuel-cell cathode10.1021/jp047349j ↗
49. Computational screening of efficient graphene-supported transition metal single atom catalysts toward the oxygen reduction reaction10.1039/D0TA06892F ↗
50. Single-atom catalysts and dual-atom catalysts for CO2 electroreduction: Competition or cooperation?10.1002/smll.202303446 ↗
51. Balancing electronic spin state via atomically-dispersed heteronuclear Fe–Co pairs for high-performance sodium–sulfur batteries10.1021/jacs.4c15408 ↗
52. Screening of dual-atom catalysts for hydrogen evolution reaction on graphdiyne10.1016/j.ijhydene.2024.12.169 ↗
53. Tackling the activity and selectivity challenges of electrocatalysts toward the nitrogen reduction reaction via atomically dispersed biatom catalysts
54. Using density functional theory to unravel the size-dependent effect of Au nanoparticles and Au dingle atoms adsorbed on carbon nitride for the hydrogenation of nitrobenzene10.1021/acsanm.2c04532 ↗
55. Highly selective dual-atom Pd heterogeneous catalyst prepared by size-selected cluster beam10.1021/acscatal.4c02500 ↗
56. Asymmetric activation of the nitro group over a Ag/graphene heterointerface to boost highly selective electrocatalytic reduction of nitrobenzene10.1021/acsami.2c04533 ↗
57. Insights into the mechanism of nitrobenzene reduction to aniline by phosphomolybdic acid supported TM1 single-atom Catalysts10.1021/acs.inorgchem.3c03106 ↗
58. Tuning the inter-metal interaction between Ni and Fe atoms in dual-atom catalysts to boost CO2 electroreduction10.1002/anie.202411543 ↗
59. High-throughput screening of heterogeneous transition metal dual-atom catalysts by synergistic effect for nitrate reduction to ammonia10.1002/adfm.202301493 ↗
60. PtN3-embedded graphene as an efficient catalyst for electrochemical reduction of nitrobenzene to aniline: a theoretical study10.1039/D0CP02389B ↗
61. Ligand engineering regulates the electronic structure of Ni-N-C sites to promote electrocatalytic acetylene semi-hydrogenation10.1016/j.jcat.2024.115784 ↗
62. Defect-triggered orbital hybridization in FeMn dual-atom catalysts toward sabatier-optimized oxygen reduction
63. Structural and Chemical origin of dual-atom sites for enhanced oxygen electroreduction10.1021/acscatal.4c03068 ↗
64. Tailoring Cu–Zn dual-atom sites with reordering d-orbital splitting manner for highly efficient acetylene semihydrogenation10.1021/acscatal.3c05779 ↗
65. Regulating second-shell soordination in cobalt single-atom catalysts toward highly selective hydrogenation10.1021/acsnano.4c05637 ↗