journal article·2026-01

Reveal the role of (Cu0/Cu+) in CO2 reduction to methane on Cu-Cu2O heterojunction

Xinyan Deng, Taifeng Liu

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution10.1039/f19898502309 ↗
2. Electrochemical Reduction of CO at a Copper Electrode10.1021/jp970284i ↗
3. Adsorption of CO, intermediately formed in electrochemical reduction of CO2, at a copper electrode10.1039/ft9918700125 ↗
4. Electrocatalytic CO2 Reduction to Alcohols with High Selectivity over a Two-Dimensional Fe2P2S6 Nanosheet10.1021/acscatal.9b03180 ↗
5. What should we make with CO2 and how can we make it?10.1016/j.joule.2017.09.003 ↗
6. Carbon solving Carbon's Problems: recent Progress of Nanostructured Carbon-based Catalysts for the Electrochemical Reduction of CO210.1002/aenm.201700759 ↗
7. Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products10.1021/acscatal.7b03477 ↗
8. Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO2 over Cu Nanowire Arrays10.1002/anie.201601282 ↗
9. New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces10.1039/c2ee21234j ↗
10. Highly Selective Two‐Electron Electrocatalytic CO2 Reduction on Single‐Atom Cu Catalysts
11. Operando Investigation of Ag‐Decorated Cu2O Nanocube Catalysts with Enhanced CO2 Electroreduction toward liquid Products10.1002/anie.202017070 ↗
12. Engineering Cu(I)/Cu(0) interfaces for efficient ethanol production from CO2 electroreduction10.1016/j.chempr.2023.08.027 ↗
13. Strategies to Modulate the Copper Oxidation State Toward Selective C2+ production in the Electrochemical CO2 Reduction Reaction10.1002/adma.202313028 ↗
14. The Synthesis of Hexaazatrinaphthylene‐Based 2D Conjugated Copper Metal‐Organic Framework for Highly Selective and Stable Electroreduction of CO2 to methane10.1002/anie.202105966 ↗
15. Bottom‐up growth of Convex Sphere with Adjustable Cu(0)/Cu(I) Interfaces for Effective C2 production from CO2 Electroreduction
16. Stabilizing Cu0–Cu+ sites by Pb-doping for highly efficient CO2 electroreduction to C2 products10.1039/D3GC01506H ↗
17. Grain Boundary‐Derived Cu+/Cu0 Interfaces in CuO Nanosheets for Low Overpotential Carbon Dioxide Electroreduction to Ethylene
18. Fu Yi-Lu, Quantum Chemical Sutdies of the Chemisorbed Selectivity of CO and NO on CuO and Cu2O(110) Surfaces10.3866/PKU.WHXB19950505 ↗
19. Controlling the Oxidation State of the Cu Electrode and Reaction Intermediates for Electrochemical CO2 Reduction to Ethylene10.1021/jacs.9b11126 ↗
20. Projector augmented-wave method10.1103/PhysRevB.50.17953 ↗
21. From ultrasoft pseudopotentials to the projector augmented-wave method10.1103/PhysRevB.59.1758 ↗
22. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set10.1103/PhysRevB.54.11169 ↗
23. Assessment of the Perdew–Burke–Ernzerhof exchange-correlation functional10.1063/1.478401 ↗
24. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
25. Atoms, molecules, solids, and surfaces: applications of the generalized gradient approximation for exchange and correlation10.1103/PhysRevB.46.6671 ↗
26. Optimizing Cu+-Cu0 synergy by operando tracking of Cu2O nanocatalysts during the electrochemical CO2 reduction reaction10.1016/j.nanoen.2023.108920 ↗
27. Insights into an autonomously formed oxygen-evacuated Cu2O electrode for the selective production of C2H4 from CO210.1039/C4CP03172E ↗
28. Engineering Water Molecules Activation Center on Multisite Electrocatalysts for Enhanced CO2 Methanation10.1021/jacs.2c03875 ↗
29. Construction of Co-In dual single-atom catalysts for photocatalytic CO2 reduction into CH410.1016/j.apcatb.2025.125196 ↗
30. Switching CO2 Electroreduction toward C2+ Products and CH4 by Regulating the Dimerization and Protonation in Platinum/Copper Catalysts10.1002/anie.202424749 ↗
31. Accessing parity-forbidden d-d transitions for photocatalytic CO2 reduction driven by infrared light10.1038/s41467-023-39666-0 ↗
32. A climbing image nudged elastic band method for finding saddle points and minimum energy paths10.1063/1.1329672 ↗
33. CATKINAS: a large-scale catalytic microkinetic analysis software for mechanism auto-analysis and catalyst screening10.1002/jcc.26464 ↗
34. Insight into the NH3-Assisted Selective Catalytic Reduction of NO on β-MnO2(110): Reaction Mechanism, activity Descriptor, and Evolution from a Pristine State to a Steady State10.1021/acscatal.8b02114 ↗
35. Resolving the Intricate Mechanism and Selectivity of Syngas Conversion on Reduced ZnCr2Ox: a Quantitative Study from DFT and Microkinetic Simulations10.1021/acscatal.1c03579 ↗
36. CO2 Electrochemical Reduction to methane and Methanol on Copper-based Alloys: Theoretical Insight10.1021/acs.jpcc.5b01574 ↗
37. Activity Descriptors for CO2 Electroreduction to methane on Transition-Metal Catalysts10.1021/jz201461p ↗
38. Catalytic activity and Product Selectivity Trends for Carbon Dioxide Electroreduction on transition Metal-Coated Tungsten Carbides10.1021/acs.jpcc.7b05741 ↗
39. Thermodynamic and Kinetic Competition between C–H and O–H Bond Formation Pathways during Electrochemical Reduction of CO on Copper Electrodes10.1021/acscatal.0c05472 ↗
40. Degree of Rate Control: how much the Energies of Intermediates and transition states Control rates10.1021/ja9000097 ↗
41. Finding the Rate-determining step in a Mechanism: Comparing DeDonder Relations with the “Degree of Rate Control”10.1006/jcat.2001.3396 ↗