journal article·2025-12

An effective strategy for enhancing the selective hydrogenation of acetylene by defective nickel single-atom catalysts through integration with nickel nanoclusters

Hedan Yao, Yi Qin, Guoqing Qi, Yuchen Niu, Dong Huang, Wenhong Li, Liuyi Pan, Dong Li

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Catalysis and Hydrodesulfurization Studies · Machine Learning in Materials Science · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Ag-Pd and Cu-Pd catalysts for selective hydrogenation of acetylene10.1021/acscatal.0c01536 ↗
2. C2H2 semi-hydrogenation over the supported Pd and Cu catalysts: the effects of the support types, properties and metal-support interaction on C2H4 selectivity and activity10.1016/j.apsusc.2019.144142 ↗
3. C2H2 selective hydrogenation to C2H4: engineering the surface structure of Pd-based alloy catalysts to adjust the catalytic performance10.1021/acs.jpcc.1c03157 ↗
4. Breaking the activity-selectivity trade-off of Pt nanoparticles encapsulated in UiO-66 for hydrogenation by constructing suitable hierarchical structure10.1021/acssuschemeng.2c00098 ↗
5. Highly selective acetylene semihydrogenation catalyst with an operation window exceeding 150 °C10.1021/acscatal.1c00804 ↗
6. Highly selective and stable PdNi catalyst derived from layered double hydroxides for partial hydrogenation of acetylene10.1016/j.apcata.2015.04.035 ↗
7. Selective hydrogenation of acetylene on SiO2 supported Ni-In bimetallic catalysts: promotional effect of In10.1016/j.apsusc.2016.06.067 ↗
8. Selective hydrogenation of acetylene on SiO2-supported Ni-Ga alloy and intermetallic compound10.1016/j.jechem.2018.02.001 ↗
9. Selective hydrogenation of acetylene to ethylene over bimetallic catalysts10.1021/acs.iecr.9b04604 ↗
10. Origin of the increase of activity and selectivity of nickel doped by Au, Ag, and Cu for acetylene hydrogenation10.1021/cs2006789 ↗
11. Selective CO2 electroreduction to ethanol over a carbon-coated CuOx catalyst10.1002/anie.202209629 ↗
12. Vacancy-rich MXene-immobilized Ni single atoms as a high-performance electrocatalyst for the hydrazine oxidation reaction10.1002/adma.202204388 ↗
13. Effective ensemble of pt single atoms and clusters over the (Ni, Co) (OH)2 substrate catalyzes highly selective, efficient, and stable hydrogenation reactions10.1021/acscatal.2c01901 ↗
14. Modulating Pt-O-Pt atomic clusters with isolated cobalt atoms for enhanced hydrogen evolution catalysis10.1038/s41467-022-30155-4 ↗
15. Size effect of nickel from nanoparticles to clusters to single atoms for electrochemical CO2 reduction10.1039/D4TA03404J ↗
16. Single-atom tailored atomically-precise nanoclusters for enhanced electrochemical reduction of CO2-to-CO activity
17. Selective CO2 to-HCOOH electroreduction on graphdiyne-supported bimetallic single-cluster catalyst10.1021/acscatal.4c00858 ↗
18. NiO@Ni nanoparticles embedded in N-doped carbon for efficient photothermal CO2 methanation coupled with H2O slitting10.1007/s12274-023-6226-5 ↗
19. Insights into synergistic effect of Pd single atoms and sub-nanoclusters on TiO2 for enhanced photocatalytic H2 evolution10.1016/j.cej.2022.137873 ↗
20. Synergy of Ni nanoclusters and single atom site: size effect on the performance of electrochemical CO2 Reduction reaction and rechargeable Zn−CO2 batteries10.1002/adfm.202316824 ↗
21. Phthalocyanine-derived catalysts decorated by metallic nanoclusters for enhanced CO2 electroreduction10.1016/j.gee.2021.05.006 ↗
22. Fully exposed nickel clusters for semi-hydrogenation of acetylene10.1021/acscatal.4c04462 ↗
23. Rational design of N-doped carbon-coated cobalt nanoparticles for highly efficient and durable photothermal CO2 conversion10.1002/adma.202302537 ↗
24. Nickel and oxygen-containing functional groups co-decorated graphene-like shells as catalytic sites with excellent selective hydrogenation activity and robust stability10.1016/j.cej.2022.139361 ↗
25. Hybrid catalyst coupling Zn single atoms and CuNx clusters for synergetic catalytic reduction of CO210.1002/adfm.202214215 ↗
26. Single-site metal–organic framework and copper foil tandem catalyst for highly selective CO2 electroreduction to C2H4
27. Controlling sp3 defect density of carbon-based catalysts by defining a limiting space10.1016/j.cej.2022.139221 ↗
28. Bimetallic-MOF derived carbon with single Pt anchored C4 atomic group constructing super fuel cell with ultrahigh power density and self-change ability10.1002/adma.202308989 ↗
29. Single carbon vacancy traps atomic platinum for hydrogen evolution catalysis10.1021/jacs.1c10814 ↗
30. Intrinsic carbon-defect-driven electrocatalytic reduction of carbon dioxide
31. Electrosynthesis of polymer-grade ethylene via acetylene semi-hydrogenation over undercoordinated Cu nanodots10.1038/s41467-023-37821-1 ↗
32. Tuning carbon defect in copper single-atom catalysts for efficient oxygen reduction10.1002/smll.202301075 ↗
33. Reinforced atomically dispersed Fe-N-C catalysts derived from petroleum asphalt for oxygen reduction reaction10.1016/j.jcis.2020.11.040 ↗
34. Sulphur as medium: directly converting pitch into porous carbon10.1016/j.fuel.2020.119393 ↗
35. Synthesis of carbon nanocapsules containing Fe, Ni or Co by arc discharge in aqueous solution10.1016/j.carbon.2006.04.024 ↗
36. Projector augmented wave method: ab initio molecular dynamics with full wave functions10.1007/BF02712785 ↗
37. The electronic structure and bonding of acetylene on PdGa(110)10.1021/acs.jpcc.5b04214 ↗
38. Polydopamine-assisted construction of cobalt phosphide encapsulated in N-doped carbon porous polyhedrons for enhanced overall water splitting10.1016/j.carbon.2018.12.032 ↗
39. Stable single-atom platinum catalyst trapped in carbon onion graphitic shells for improved chemoselective hydrogenation of nitroarenes10.1016/j.carbon.2018.11.021 ↗
40. Edge-rich Fe−N4 active sites in defective carbon for oxygen reduction catalysis
41. Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms10.1021/acs.chemrev.9b00230 ↗
42. Effects of intrinsic defects in Pt-based carbon supports on alkaline hydrogen evolution reaction10.1021/acsami.4c00690 ↗