journal article·2025-10

Adsorption-induced lattice weakening: understanding the mechanism of cysteine-accelerated pyrite oxidation

Tong Liu, Yutian Hu, Nan Chen, Hongrui Ding, Chuanping Feng, Wang Lu

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Metal Extraction and Bioleaching · Minerals Flotation and Separation Techniques · Mine drainage and remediation techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. A critical stage in the formation of acid mine drainage: Colonization of pyrite by Acidithiobacillus ferrooxidans under pH-neutral conditions10.1046/j.1472-4669.2003.00005.x ↗
2. Bio-leaching of pyrite accelerated by cysteine10.1016/S0032-9592(99)00142-9 ↗
3. Prevention of depression and anxiety symptoms in adolescents: 42 and 54 months follow-up of the Aussie Optimism Program-Positive Thinking Skills10.3389/fpsyg.2014.00364 ↗
4. Cysteine and cystine adsorption on FeS$2$(100)10.1016/j.susc.2018.03.011 ↗
5. Hopkins · Isopotential Electron Titration: Hydrogen Metal-Adsorbate Charge Transfer. · 2025
6. Advances in Microbial Leaching as a Non-conventional Technique for Metal Recovery from Ores: A Review10.1080/01490451.2025.2460506 ↗
7. Comparative study of interaction between pyrite and cysteine by thermogravimetric and electrochemical techniques10.1016/j.hydromet.2009.11.015 ↗
8. Selective Adsorption of Thiol-Containing Molecules on Copper Sulfide Surfaces via Molecule–Surface Disulfide Bridges10.1021/acs.jpcc.4c06463 ↗
9. Combined DFT and XPS Investigation of Cysteine Adsorption on the Pyrite (1 0 0) Surface10.3390/min8090366 ↗
10. Iron/sulphur centre mediated photoinduced charge transfer at (100) oriented pyrite surfaces10.1016/0022-0728(95)04223-7 ↗
11. Pyrite-based autotrophic denitrification for remediation of nitrate contaminated groundwater10.1016/j.biortech.2014.09.092 ↗
12. Influence of the Discretization Methods on the Distribution of Relaxation Times Deconvolution: Implementing Radial Basis Functions with DRTtools10.1016/j.electacta.2015.09.097 ↗
13. Implementation of Second-Generation Fourier Transform Electrochemical Impedance Spectroscopy with Commercial Potentiostat and Application to Time-Resolved Electrochemical Impedance Spectroscopy10.1021/acs.analchem.9b03226 ↗
14. QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials10.1088/0953-8984/21/39/395502 ↗
15. Generalized gradient approximation made simple
16. Lejaeghere, K., Bihlmayer, G., Bjorkman, T., Blaha, P., Blugel, S., Blum, V., Caliste, D., Castelli, I.E., Clark, S.J., Dal Corso, A., de Gironcoli, S., Deutsch, T., Dewhurst, J.K., Di Marco, I., Draxl, C., Du ak, M., Eriksson, O., Flores-Livas, J.A., Garrity, K.F., Genovese, L., Giannozzi, P., Giantomassi, M., Goedecker, S., Gonze, X., Granas, O., Gross, E.K.U., Gulans, A., Gygi, F., Hamann, D.R., Hasnip, P.J., Holzwarth, N.A.W., Iu an, D., Jochym, D.B., Jollet, F., Jones, D., Kresse, G., Koepernik, K., Kucukbenli, E., Kvashnin, Y.O., Locht, I.L.M., Lubeck, S., Marsman, M., Marzari, N., Nitzsche, U., Nordstrom, L., Ozaki, T., Paulatto, L., Pickard, C.J., Poelmans, W., Probert, M.I.J., Refson, K., Richter, M., Rignanese, G.-M., Saha, S., Scheffler, M., Schlipf, M., Schwarz, K., Sharma, S., Tavazza, F., Thunstrom, P., Tkatchenko, A., Torrent, M., Vanderbilt, D., van Setten, M.J., Van Speybroeck, V., Wills, J.M., Yates, J.R., Zhang, G.-X., Cottenier, S., 2016. Reproducibility in density functional theory calculations of solids. Science 351, aad3000–aad3000. DOI: 10.1126/science.aad3000.10.1126/science.aad3000 ↗
17. Crystal Orbital Bond Index: Covalent Bond Orders in Solids10.1021/acs.jpcc.1c00718 ↗
18. LOBSTER: A tool to extract chemical bonding from plane-wave based DFT: Tool to Extract Chemical Bonding10.1002/jcc.24300 ↗
19. Interaction Region Indicator: A Simple Real Space Function Clearly Revealing Both Chemical Bonds and Weak Interactions10.1002/cmtd.202100007 ↗
20. CP2K: An electronic structure and molecular dynamics software package - Quickstep: Efficient and accurate electronic structure calculations10.1063/5.0007045 ↗
21. Multiwfn: A multifunctional wavefunction analyzer10.1002/jcc.22885 ↗
22. R Core Team · 2020
23. Welcome to the tidyverse10.21105/joss.01686 ↗
24. afex: Analysis of factorial experiments
25. Emmeans: Estimated marginal means, aka least-squares means
26. Stabilization and Utilization of Pyrite under Light Irradiation: Discussion of Photocorrosion Resistance10.1021/acsomega.0c03872 ↗
27. Eghbalnia · 2012
28. Polysulfides do not cause passivation: Results from the dissolution of pyrite and implications for other sulfide minerals10.1016/j.hydromet.2013.07.006 ↗
29. Maluckov · 2018
30. Separation of charge transfer and contact resistance in LiFePO4 -cathodes by impedance modeling10.1149/2.030207jes ↗
31. Modeling graphite anodes with serial and transmission line models10.1016/j.jpowsour.2015.02.038 ↗
32. Electrochemical investigation of the oxidation of pyrite in neutral solutions10.1016/j.electacta.2021.139078 ↗
33. Eghbalnia · 2012
34. Semiconductor electrochemistry of particulate pyrite: dissolution via hole and electron pathways10.1149/1.1837186 ↗
35. Effects of L-cysteine on Ni–Cu sulfide and marmatite bioleaching by Acidithiobacillus caldus10.1016/j.biortech.2008.08.038 ↗
36. Correlations between Density-Based Bond Orders and Orbital-Based Bond Energies for Chemical Bonding Analysis10.1021/acs.jpcc.8b08934 ↗
37. New Bonding Model of Radical Adsorbate on Lattice Oxygen of Perovskites10.1021/acs.jpclett.8b02749 ↗
38. Sorption of aqueous amino acid species on sulphidic mineral surfaces—DFT study and insights on biosourced‐reagent mineral flotation10.1002/cjce.23841 ↗
39. Crystal Orbital Hamilton Population (COHP) Analysis As Projected from Plane-Wave Basis Sets10.1021/jp202489s ↗
40. Dimakis · 2019 · 150
41. Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys10.1021/jp046540q ↗
42. Stability, Structure, and Electronic Properties of the Pyrite/Arsenopyrite Solid–Solid Interface–A DFT Study10.1021/acs.jpcc.7b02642 ↗
43. A DFT investigation into the effects of As-doping on the electronic structure and electrochemical activity of pyrite (FeS2)10.1016/j.jmgm.2021.108040 ↗
44. Theoretical Investigations of Transition Metal Surface Energies under Lattice Strain and CO Environment10.1021/acs.jpcc.8b02094 ↗
45. Pyrite oxidation mechanism by oxygen in aqueous medium10.1021/acs.jpcc.5b10949 ↗
46. A mineral-based origin of Earth’s initial hydrogen peroxide and molecular oxygen10.1073/pnas.2221984120 ↗
47. The Role of Defects in Fe(II)–Goethite Electron Transfer10.1021/acs.est.7b05772 ↗
48. A Novel Surface Passivation Method of Pyrite within Rocks in Underwater Environments to Mitigate Acid Mine Drainage at Its Source10.3390/min14100973 ↗
49. The Formation of Silicate-Stabilized Passivating Layers on Pyrite for Reduced Acid Rock Drainage10.1021/acs.est.7b03232 ↗
50. Toward Sustainable Solution for Biooxidation of Waste and Refractory Materials Using Neutrophilic and Alkaliphilic Microorganisms—A Review10.1021/acsabm.0c01582 ↗
51. High redox potential promotes oxidation of pyrite under neutral conditions: Implications for optimizing pyrite autotrophic denitrification10.1016/j.jhazmat.2021.125844 ↗
52. Ab initio Studies of O2 Adsorption on (110) Nickel-Rich Pentlandite (Fe4Ni5S8) Mineral Surface10.3390/min5040516 ↗
53. In Situ Surface Reconstruction of Catalysts for Enhanced Hydrogen Evolution10.3390/catal13010120 ↗