journal article·2025-10Open access

Synthesis of high-performance arsenic-specific adsorption microspheres using iron-magnesium modified chitosan

Jie Tan, Fangming Nan, Donghui Chen, Lu Xiang, Xiaoting Li, Qingwen Han, Wei Zhan

Abstract

Chitosan (CS) is widely recognized for its excellent gelling properties; however, its application in heavy metal removal is often limited by the scarcity of active adsorption sites. In this study, CS was employed as a matrix material to fabricate gel beads (Fe/Mg-CS) through cross-linking with Fe 3+ and Mg 2+ thereby enhancing its adsorption capacity for As(V). The Fe/Mg-CS adsorbent was thoroughly characterized, and its adsorption performance was evaluated under optimized conditions. The optimal dosage of Fe/Mg-CS was determined to be 0.06 g/L, with effective adsorption observed within a pH range of 3–7. Kinetic analysis revealed that the adsorption process followed a pseudo-second-order model, suggesting that the adsorption mechanism primarily involves complexation reactions between hydroxyl groups and As(Ⅴ). Isotherm studies indicated that the Langmuir model provided the best fit, with a maximum adsorption capacity of 147.49 mg/g. Compared to conventional powdered adsorbents, Fe/Mg-CS offers several advantages, including straightforward synthesis, ease of recycling, and high efficiency. These properties make Fe/Mg-CS a promising candidate for the remediation of As(V)-contaminated groundwater, providing a sustainable and effective solution for future water purification applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Arsenic contamination and mitigation · Carbon and Quantum Dots Applications · Adsorption and biosorption for pollutant removal

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Comprehensive review on toxic heavy metals in the aquatic system: sources, identification, treatment strategies, and health risk assessment10.1016/j.envres.2024.119440 ↗
2. Effect of Opuntia ficus indica Mucilage on Copper Removal from Water by Electrocoagulation-Electroflotation Technique10.1016/j.jelechem.2017.12.081 ↗
3. Selective removal of arsenic in water: A critical review10.1016/j.envpol.2020.115668 ↗
4. Uptake of arsenic(V) using iron and magnesium functionalized highly ordered mesoporous MCM-41 (Fe/Mg-MCM-41) as an effective adsorbent10.1016/j.scitotenv.2022.154858 ↗
5. Characterization of arsenic (III and V) adsorption on natural schwertmannite formed in acid coal mine drainage: Batch studies and spectroscopic observations10.1016/j.jece.2022.109170 ↗
6. Arsenic occurrence and cycling in the aquatic environment: A comparison between freshwater and seawater
7. Arsenic and human health effects: A review10.1016/j.etap.2015.09.016 ↗
8. Arsenic as an environmental and human health antagonist: A review of its toxicity and disease initiation
9. Arsenic inorganic exposure, metabolism, genetic biomarkers and its impact on human health: A mini-review10.1016/j.toxlet.2024.06.008 ↗
10. Remarkable adsorption of As(V) by Fe3+ and Mg2+ modified alginate porous beads (Fe/Mg-SA) via a facile method10.1016/j.ijbiomac.2023.127994 ↗
11. Arsenic removal approaches: A focus on chitosan biosorption to conserve the water sources10.1016/j.ijbiomac.2021.10.050 ↗
12. Adsorption of As(V) by magnetic alginate-chitosan porous beads based on iron sludge10.1016/j.jclepro.2022.132117 ↗
13. Catalytic potential of Cu/Mg/Al-chitosan for ozonation of real landfill leachate10.1016/j.psep.2017.02.013 ↗
14. Adsorption of heavy metals from wastewater by chitosan: A review10.1016/j.rineng.2024.102404 ↗
15. Adsorption study of an organo-arsenical with chitosan-based sorbents10.1016/j.jcis.2014.01.003 ↗
16. Chitosan-modified iron fillings materials for remediation of arsenic-contaminated soil10.1016/j.cej.2024.150261 ↗
17. Chitosan and its derivatives in wastewater treatment application10.1016/j.matpr.2023.10.157 ↗
18. Complexation mechanisms in arsenic and phosphorus adsorption onto iron-coated cork granulates10.1016/j.jece.2020.104184 ↗
19. Optimization of metal component, characterization, and stability of Cu/Mg/Al–chitosan catalyst in catalytic ozonation of a landfill leachate10.5004/dwt.2017.20905 ↗
20. Synthesis of chitosan zero-valent iron nanoparticles-supported for cadmium removal: characterization, optimization and modeling approach10.2166/aqua.2017.027 ↗
21. Abatement of Azo Dye from Wastewater Using Bimetal-Chitosan10.1155/2013/476271 ↗
22. The effect of sodium alginate on struvite crystallization in aqueous solution: A kinetics study10.1016/j.jcrysgro.2017.03.039 ↗
23. Preparation of novel polymethacryloyl hydrazone modified sodium alginate porous adsorbent with good stability and selective adsorption capacity towards metal ions10.1016/j.seppur.2022.122184 ↗
24. Ion Imprinted Sodium Alginate Hydrogel Beads Enhanced with Carboxymethyl Cellulose and β-Cyclodextrin to Improve Adsorption for Cu2+10.1007/s10924-022-02529-8 ↗
25. pH-dependent effect of zinc on arsenic adsorption to magnetite nanoparticles10.1016/j.watres.2010.06.023 ↗
26. Simultaneous oxidation of roxarsone and adsorption of released arsenic by FeS-activated sulfite10.1016/j.watres.2023.119979 ↗
27. Influences of co-existing species on the sorption of toxic oxyanions from aqueous solution by nanocrystalline Mg/Al layered double hydroxide10.1016/j.jhazmat.2010.04.045 ↗
28. Alpha-MnO2 nanoneedle embedded in MgO-chitosan biochar for higher removal of arsenic from groundwater: Co-effects of oxidation and adsorption10.1016/j.jallcom.2023.169643 ↗
29. Highly efficient removal of As(V) with modified electrolytic manganese residues (M-EMRs) as a novel adsorbent10.1016/j.jallcom.2019.151973 ↗
30. Investigation of boundary layer effect of intra-particle diffusion on methylene blue adsorption on activated carbon10.1016/j.nexus.2024.100294 ↗
31. Application of biopolymers as a new age sustainable material for surfactant adsorption: A brief review
32. Theoretical framework to evaluate minimum desorption temperature for IUPAC classified adsorption isotherms10.1016/j.ijheatmasstransfer.2018.01.107 ↗
33. Understanding adsorption mechanisms and metal ion selectivity of superparamagnetic beads with mesoporous CMK-3 carbon and commercial activated carbon10.1016/j.micromeso.2024.113159 ↗
34. Guidelines for the use and interpretation of adsorption isotherm models: A review10.1016/j.jhazmat.2020.122383 ↗
35. Chitosan-functionalized graphene oxide: A novel adsorbent an efficient adsorption of arsenic from aqueous solution10.1016/j.jece.2016.02.035 ↗
36. Three-dimensional honeycomb-like structured zero-valent iron/chitosan composite foams for effective removal of inorganic arsenic in water10.1016/j.jcis.2016.06.035 ↗
37. A facile one-pot hydrothermal synthesis of hydroxyapatite/biochar nanocomposites: Adsorption behavior and mechanisms for the removal of copper(II) from aqueous media10.1016/j.cej.2019.03.102 ↗
38. Effects of oxidation on the magnetization of nanoparticulate magnetite
39. Highly effective adsorption for both As(III) and As(V) in aqueous medium via magnetic chitosan-based composite microparticles: Low arsenic concentration, high column efficiency and adaptability10.1016/j.jece.2023.110874 ↗
40. Nanoarchitectonics with self-healing hydrogel for hierarchical porous carbons and its application in cadmium-arsenic complex pollution10.1016/j.jece.2024.113918 ↗
41. Enhanced removal of As(III) and As(V) from water by a novel zirconium-chitosan modified spherical sodium alginate composite10.1016/j.ijbiomac.2021.02.077 ↗
42. A novel chitosan-based hydrogel microspheres for efficient heavy metal-ion adsorption