journal article·2025-06

Mechanistic insights into the role of empty mid-gap states in Al- and Rh-doped SrTiO3 for photocatalytic water splitting

Ya-nan Jiang, Jie Zhang, Xiao Zhang, Yuchen Ma

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Electronic and Structural Properties of Oxides · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (76)

Show source-provided references
1. Heterogeneous photocatalyst materials for water splitting10.1039/B800489G ↗
2. Semiconductor-based photocatalytic hydrogen generation10.1021/cr1001645 ↗
3. Photocatalytic water splitting: recent progress and future challenges10.1021/jz1007966 ↗
4. Photocatalytic water-splitting reaction from catalytic and kinetic perspectives10.1007/s10562-014-1397-z ↗
5. Nanoparticles of SrTiO3 prepared by gel to crystallite conversion and their photocatalytic activity in the mineralization of phenol10.1016/1010-6030(96)04324-9 ↗
6. Photocatalytic decomposition of water vapor on an NiO-SrTiO3 catalyst10.1039/C39800000543 ↗
7. Overall photocatalytic water splitting with NiOx-SrTiO3-a revised mechanism10.1039/c2ee22665k ↗
8. Nanoscale strontium titanate photocatalysts for overall water splitting10.1021/nn302647u ↗
9. Photoinduced electronic and ionic effects in strontium titanate10.1039/D1MA00906K ↗
10. Recent developments of strontium titanate for photocatalytic water splitting application10.1016/j.ijhydene.2019.01.166 ↗
11. Selected perovskite oxides: characterization, preparation and photocatalytic properties—a review10.1016/j.apcatb.2015.12.035 ↗
12. Perovskite oxide based materials for energy and environment-oriented photocatalysis10.1021/acscatal.0c02947 ↗
13. ABO3-based photocatalysts for water splitting10.1016/j.pnsc.2012.12.002 ↗
14. Enhancing charge separation on high symmetry SrTiO3 exposed with anisotropic facets for photocatalytic water splitting10.1039/C6EE00526H ↗
15. Plasmon-assisted water splitting using two sides of the same SrTiO3 single-crystal substrate: conversion of visible light to chemical energy10.1002/anie.201404926 ↗
16. Exploring the impact of modulation of electronic structure via doping in the realm of environmental applications10.1016/j.nwnano.2025.100075 ↗
17. Copper doping induced band structure and morphology transformation in CaTiO3 for textile dye photodegradation applications10.1016/j.jallcom.2024.175779 ↗
18. Electronic structure engineering of BaTiO3 cuboctahedrons by doping copper to enhance the photocatalytic activity for environmental remediation10.1016/j.jallcom.2023.169600 ↗
19. Vanadium doped CaTiO3 cuboids: role of vanadium in improving the photocatalytic activity10.1039/D1NA00468A ↗
20. Insights into the dopant engineering in copper-doped SrTiO3 nanocubes
21. U. P. I, U. S. Shenoy, D. K. Bhat, Nanocubic copper-doped SrTiO3 for photoreduction of Cr(VI) and photodegradation of methyl violet, ACS Appl. Nano Mater. 6 (2023) 16798-16804.10.1021/acsanm.3c02997 ↗
22. Doped BaTiO3 cuboctahedral nanoparticles: role of copper in photocatalytic degradation of dyes10.1016/j.apsadv.2023.100408 ↗
23. Exceptional light harvesting in copper doped CaTiO3 nanocuboids with surface nanosteps for the photo remediation of toxic Cr(VI) ions and dyes
24. Silver doped barium titanate nanoparticles for enhanced visible light photocatalytic degradation of dyes10.1016/j.envpol.2024.123430 ↗
25. Rhodium doping augments photocatalytic activity of barium titanate: effect of electronic structure engineering10.1039/D0NA00702A ↗
26. Band engineering of SrTiO3: Effect of synthetic technique and site occupancy of doped rhodium10.1021/acs.jpcc.8b10083 ↗
27. Enhanced thermoelectric properties of vanadium doped SrTiO3: a resonant dopant approach10.1016/j.jallcom.2020.154958 ↗
28. Vanadium-doped BaTiO3 as high performance thermoelectric material: role of electronic structure engineering
29. The role of the dopant and structural defects on the water absorption and on the H2 formation in the Al, Co and Cu doped SrTiO3 perovskite steps10.1016/j.apsusc.2020.146850 ↗
30. Photocatalytic water splitting with a quantum efficiency of almost unity10.1038/s41586-020-2278-9 ↗
31. Flux-mediated doping of SrTiO3 photocatalysts for efficient overall water splitting10.1039/C5TA04843E ↗
32. Photocatalytic solar hydrogen production from water on a 100-m2 scale10.1038/s41586-021-03907-3 ↗
33. Theoretical investigation of the metal-doped SrTiO3 photocatalysts for water splitting10.1021/jp300910e ↗
34. Photocatalytic activities of noble metal ion doped SrTiO3 under visible light irradiation10.1021/jp049556p ↗
35. Rh-doped SrTiO3 photocatalyst electrode showing cathodic photocurrent for water splitting under visible-light irradiation10.1021/ja2050315 ↗
36. Time-resolved infrared absorption study of SrTiO3 photocatalysts codoped with rhodium and antimony10.1021/jp407040p ↗
37. Electronic engineering of ABO3 perovskite metal oxides based on d0 electronic-configuration metallic ions toward photocatalytic water splitting under visible light10.1002/sstr.202100226 ↗
38. Tuning the morphology and exposed facets of SrTiO3 nanostructures for photocatalytic dye degradation and hydrogen evolution10.1021/acsanm.0c03160 ↗
39. Shape-tunable SrTiO3 crystals revealing facet-dependent optical and photocatalytic properties10.1021/acs.jpcc.9b02081 ↗
40. Fabrication of SrTiO3 exposing characteristic facets using molten salt flux and improvement of photocatalytic activity for water splitting10.1039/c3cy00014a ↗
41. Surface reconstruction of facet-functionalized SrTiO3 nanocrystals for photocatalytic hydrogen evolution10.1002/cctc.201501162 ↗
42. The adsorption of water on SrTiO3 and TiO2: a reappraisal10.1016/S0584-8539(87)80043-0 ↗
43. The formation time of Ti-O•and Ti-O•-Ti radicals at the n-SrTiO3/aqueous interface during photocatalytic water oxidation10.1021/jacs.6b09550 ↗
44. Detecting the oxyl radical of photocatalytic water oxidation at an n-SrTiO3/aqueous interface through its subsurface vibration10.1038/nchem.2497 ↗
45. Water adsorption on SrTiO3 (001): I. experimental and simulated STM10.1016/j.susc.2012.01.008 ↗
46. Adsorption of water on (001) surface of SrTiO3 and SrZrO3 cubic perovskites: hybrid HF-DFT LCAO calculations10.1016/j.susc.2007.02.010 ↗
47. A first-principles study of H2O adsorption and dissociation on the SrTiO3 (100) surface10.1080/08927021003762746 ↗
48. Water splitting on Ti-oxide-terminated SrTiO3 (001)10.1021/acs.jpcc.9b01730 ↗
49. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set10.1103/PhysRevB.54.11169 ↗
50. From ultrasoft pseudopotentials to the projector augmented-wave method10.1103/PhysRevB.59.1758 ↗
51. Semiempirical GGA-type density functional constructed with a long-range dispersion correction10.1002/jcc.20495 ↗
52. Ta-doped SrTiO3 epitaxial thin film: a promising perovskite for optoelectronics10.1063/5.0042672 ↗
53. Trends in non-metal doping of the SrTiO3 surface: a hybrid density functional study10.1039/C5CP03005F ↗
54. Microscopic structure and structuring of perovskite surfaces and interfaces: SrTiO3, RBa2Cu3O7-δ10.1007/s003390050843 ↗
55. Surface relaxation of SrTiO3(001)10.1016/S0039-6028(00)00403-9 ↗
56. Structural relaxation and longitudinal dipole moment of SrTiO3(001)(1×1) surfaces10.1103/PhysRevB.62.10409 ↗
57. Selecting between two transition states by which water oxidation intermediates decay on an oxide surface10.1038/s41929-019-0332-5 ↗
58. Coherent acoustic interferometry during the photodriven oxygen evolution reaction associates strain fields with the reactive oxygen intermediate (Ti-OH*)10.1021/jacs.1c04976 ↗
59. Vacancy clusters at domain boundaries and band bending at the SrTiO3 (110) surface
60. Water adsorption at the tetrahedral titania surface layer of SrTiO3 (110)-(4 × 1)10.1021/jp407889h ↗
61. Reconstructions on the polar SrTiO3 (110) surface: analysis using STM, LEED, and AES10.1103/PhysRevB.77.245414 ↗
62. Evolution of the surface structures on SrTiO3 (110) tuned by Ti or Sr concentration
63. Surface-alkalinization-induced enhancement of photocatalytic H2 evolution over SrTiO3-based photocatalysts10.1021/ja210610h ↗
64. Ab-initio study of the polar SrTiO3 (110) (1×1) surfaces10.1016/S0039-6028(03)00227-9 ↗
65. Ab initio calculations of the SrTiO3 (110) polar surface10.1103/PhysRevB.69.035408 ↗
66. High-resolution studies of cubic perovskites by elastic neutron diffraction. II. SrTiO3, KMnF3, RbCaF3 and CsPbCl310.1088/0022-3719/14/12/006 ↗
67. Bulk electronic structure of SrTiO3: experiment and theory10.1063/1.1415766 ↗
68. Hydrogen-induced metallicity of SrTiO3 (001) surfaces: a density functional theory study10.1103/PhysRevB.79.035311 ↗
69. Synergistic surface oxygen defect and bulk Ti3+ defect engineering on SrTiO3 for enhancing photocatalytic overall water splitting10.1016/j.jcis.2022.06.109 ↗
70. Electronic structure basis for enhanced overall water splitting photocatalysis with aluminum doped SrTiO3 in natural sunlight10.1039/C9EE00310J ↗
71. Probing photoexcited charge carrier trapping and defect formation in synergistic doping of SrTiO3
72. Elucidation of Rh induced in-gap states of Rh:SrTiO3 visible-light-driven photocatalyst by soft X-ray spectroscopy and first-principles calculations10.1021/jp3082529 ↗
73. Revealing the role of the Rh valence state, La doping level and Ru cocatalyst in determining the H2 evolution efficiency in doped SrTiO3 photocatalysts10.1039/C8SE00487K ↗
74. Construction of Z-scheme type heterogeneous photocatalysis systems for water splitting into H2 and O2 under visible light irradiation10.1246/cl.2004.1348 ↗
75. The effect of co-catalyst for Z-scheme photocatalysis systems with an Fe3+/Fe2+ electron mediator on overall water splitting under visible light irradiation10.1016/j.jcat.2008.07.017 ↗
76. Solar water splitting using powdered photocatalysts driven by Z-schematic interparticle electron transfer without an electron mediator10.1021/jp907128k ↗