journal article·2025-01

Highly efficient SnO2-Carbon nanosphere heterojunctions decorated with Ag for detecting isopropanol at low operating temperatures

Shixin Huang, Wei Liu, Zhicheng Wen, Chunjin Hang, Rong An, Yongfeng Li, Yanhong Tian

Publisher page

Abstract

The design of a sensing material for detecting isopropanol gas with low operating temperature is extremely important for miniaturization and wearability of gas sensors. Herein, a novel gas sensor based on SnO2-Carbon nanosphere heterojunctions decorated with Ag nanoparticles (SCA) was fabricated and its gas sensing performance was evaluated and compared systematically. The measurement results indicated that the sensing performance was influenced by the ratio of Sn/C and the length of Ag plating, and the SCA sensor provided the best response. For 100 ppm isopropanol at 100 °C, the SCA sensor exhibited a response value of 50.51, a response time of 7 s and a recovery time of 60 s. The enhanced sensing performance and reduced operating temperature of the SCA could be attributed to the synergistic effect of the SnO2-Carbon nanosphere heterojunctions and the significant catalytic performance of the decorated Ag nanoparticles. In addition, the density functional theory calculation method based on the first-principles theory was used to study the adsorption performance and electronic behavior, as well as the influence of Ag decoration on SnO2 for isopropanol detection. The calculated results were consistent with the experimental results.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Advanced Chemical Sensor Technologies · Analytical Chemistry and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (65)

Show source-provided references
1. Practical-scale honeycomb catalytic reactor coupled with non-thermal plasma for high-throughput removal of isopropanol10.1016/j.cej.2021.132905 ↗
2. Novel inductively-heated catalytic system for fast VOCs abatement, application to IPA in air10.1016/j.apcatb.2013.03.049 ↗
3. Isopropanol removal using MnXOY packed bed non-thermal plasma reactor: Comparison between continuous treatment and sequential sorption/regeneration10.1016/j.cej.2015.01.055 ↗
4. Bio-sniffer (gas-phase biosensor) with secondary alcohol dehydrogenase (S-ADH) for determination of isopropanol in exhaled air as a potential volatile biomarker10.1016/j.bios.2016.12.050 ↗
5. Synthesis of Pt-doped SnO2 flower-like hierarchical structure and its gas sensing properties to isopropanol10.1007/s10853-020-05655-7 ↗
6. Preparation of hollow SnO2/ZnO cubes for the high-performance detection of VOCs10.1016/j.ceramint.2022.09.352 ↗
7. Hollow ZnO@SnO2–Pt core-shell nanofibers for ethanol sensing10.1021/acsanm.2c00686 ↗
8. Highly sensitive gas sensor based on SnO2 nanorings for detection of isopropanol10.1016/j.jallcom.2016.07.248 ↗
9. Highly sensitive and ultra-fast gas sensor based on CeO2-loaded In2O3 hollow spheres for ppb-level hydrogen detection10.1016/j.snb.2017.10.139 ↗
10. Pt nanoparticle-modified SnO2–ZnO core-shell nanosheets on microelectromechanical systems for enhanced H2S detection10.1021/acsanm.2c00671 ↗
11. In2O3-SnO2 hybrid porous nanostructures delivering enhanced formaldehyde sensing performance10.1016/j.jallcom.2018.02.171 ↗
12. SnO2 quantum dots anchored on g-C3N4 for enhanced visible-light photocatalytic removal of NO and toxic NO2 inhibition10.1016/j.apsusc.2019.143630 ↗
13. Enhanced HCHO gas sensing properties by Ag-loaded sunflower-like In2O3 hierarchical nanostructures10.1039/C3TA15110G ↗
14. Single-atom Pt stabilized on one-dimensional nanostructure support via carbon nitride/SnO2 heterojunction trapping10.1021/acsnano.0c03687 ↗
15. UV-enhanced NO2 gas sensing properties of SnO2-Core/ZnO-shell nanowires at room temperature10.1021/am400500a ↗
16. Atomic Sn–enabled high-utilization, large-capacity, and long-life Na anode10.1126/sciadv.abm7489 ↗
17. Facile synthesis of ultrahigh-surface-area hollow carbon nanospheres for enhanced adsorption and energy storage10.1038/ncomms8221 ↗
18. Fabrication of poly(aniline-co-pyrrole) hollow nanospheres with Triton X-100 micelles as templates10.1002/pola.22695 ↗
19. A review on C1s XPS-spectra for some kinds of carbon materials10.1080/1536383X.2020.1794851 ↗
20. Low concentration isopropanol gas sensing properties of Ag nanoparticles decorated In2O3 hollow spheres10.1007/s40145-021-0530-x ↗
21. Preparation of Ag nanoparticles-SnO2 nanoparticles-reduced graphene oxide hybrids and their application for detection of NO2 at room temperature10.1016/j.snb.2015.09.027 ↗
22. Synergistic effects of zeolite and oxygen vacancies in SnO2 for formaldehyde sensing: Molecular simulation insights & experimental verification10.1016/j.apsusc.2022.154511 ↗
23. Nanoscale Ag-Decorated hollow Porous CuO/SnO2 heterojunctions for isopropanol detection10.1021/acsanm.3c00959 ↗
24. The Hall effect in polycrystalline and powdered semiconductors10.1088/0034-4885/43/11/001 ↗
25. Is NiCo2S4 Really a Semiconductor?10.1021/acs.chemmater.5b01843 ↗
26. Tuning the oxygen defects and Fermi levels via In3+ doping in SnO2-In2O3 nanocomposite for efficient CO detection10.1016/j.snb.2022.131412 ↗
27. Nanostructured anatase titania thin films prepared by sol-gel dip coating technique10.26713/jamcnp.v2i2.331 ↗
28. Role of oxygen vacancy in tuning of optical, electrical and NO2 sensing properties of ZnO1-x coatings at room temperature10.1016/j.snb.2017.01.105 ↗
29. Kelvin probe force microscopy and its application10.1016/j.surfrep.2010.10.001 ↗
30. Novel Ag-SnO2-βC3N4 ternary nanocomposite based gas sensor for enhanced low-concentration NO2 sensing at room temperature10.1016/j.snb.2020.128910 ↗
31. Enhanced gas sensing properties for ethanol of Ag@ZnSnO3 nano-composites10.1007/s10854-020-04407-2 ↗
32. Enhanced triethylamine sensing properties by designing Au@SnO2/MoS2 nanostructure directly on alumina tubes10.1016/j.snb.2017.05.174 ↗
33. IUPAC. Compendium of Chemical Terminology 2nd ed. (the “Gold Book”)
34. Construction of Flower-like PtOx@ZnO/In2O3 hollow microspheres for ultrasensitive and rapid trace detection of isopropanol10.1021/acsami.2c20746 ↗
35. Rationally designed mesoporous In2O3 nanofibers functionalized Pt catalysts for high-performance acetone gas sensors10.1016/j.snb.2019.126871 ↗
36. Isopropanol sensing properties of coral-like ZnO–CdO composites by flash preparation via self-sustained decomposition of metal–organic complexes10.1016/j.snb.2014.03.093 ↗
37. Gas sensor towards n-butanol at low temperature detection: Hierarchical flower-like Ni-doped Co3O4 based on solvent-dependent synthesis10.1016/j.snb.2020.129028 ↗
38. Conductometric isopropanol gas sensor: Ce-doped In2O3 nanosheet-assembled hierarchical microstructure10.1016/j.snb.2022.133007 ↗
39. Impact of reduced graphene oxide on the ethanol sensing performance of hollow SnO2 nanoparticles under humid atmosphere10.1016/j.snb.2017.01.015 ↗
40. Rational design of CuO/In2O3 heterostructures with flower-like structures for low temperature detection of formaldehyde
41. Influence of humidity on CO sensing with p-type CuO thick film gas sensors10.1016/j.snb.2010.10.046 ↗
42. Vertical SnO2 nanosheet@SiC nanofibers with hierarchical architecture for high-performance gas sensors10.1039/C5TC02792F ↗
43. Controlled synthesis of porous Ni-doped SnO2 microstructures and their enhanced gas sensing properties10.1016/j.jallcom.2016.09.103 ↗
44. Synthesis of double-shelled SnO2 hollow cubes for superior isopropanol sensing performance10.1039/C9NJ00292H ↗
45. Novel mixed phase SnO2 nanorods assembled with SnO2 nanocrystals for enhancing gas-sensing performance toward isopropanol gas10.1021/jp501550w ↗
46. Novel combined waveform temperature modulation method of NiO-In2O3 based gas sensor for measuring and identifying VOC gases10.1016/j.jallcom.2022.165510 ↗
47. Changes in the crystal structure of SnO2 nanoparticles and improved H2S gas-sensing characteristics by Al doping10.1016/j.apsusc.2021.150493 ↗
48. Exploration of the use of p-TeO2-branch/n-SnO2 core nanowires nanocomposites for gas sensing10.1016/j.apsusc.2019.04.122 ↗
49. Preparation of Pd nanoparticle-decorated hollow SnO2 nanofibers and their enhanced formaldehyde sensing properties10.1016/j.jallcom.2015.08.174 ↗
50. Semiconductor metal oxide gas sensors: A review10.1016/j.mseb.2017.12.036 ↗
51. Facile synthesis of Pr-doped In2O3 nanoparticles and their high gas sensing performance for ethanol10.1016/j.snb.2019.127377 ↗
52. Enhanced isopropanol sensing of coral-like ZnO–ZrO2 composites10.1088/1361-6528/ab6fd9 ↗
53. Electrospun nanofibers of ZnO− SnO2 heterojunction with high photocatalytic activity10.1021/jp100262q ↗
54. Uncovering the key role of the fermi level of the electron mediator in a Z-scheme photocatalyst by detecting the charge transfer process of WO3-metal-gC3N4 (Metal = Cu, Ag, Au)10.1021/acsami.5b10613 ↗
55. Nanoscale metal oxide-based heterojunctions for gas sensing: A review10.1016/j.snb.2014.07.074 ↗
56. Role of the heterojunctions in In2O3-composite SnO2 nanorod sensors and their remarkable gas-sensing performance for NOx at room temperature10.1039/C5NR03796D ↗
57. MOF-on-MOF nanoarchitecturing of Fe2O3@ZnFe2O4 radial-heterospindles towards multifaceted superiorities for acetone detection10.1016/j.cej.2022.136094 ↗
58. Hierarchical assembly of graphene-bridged SnO2-rGO/SnS2 heterostructure with interfacial charge transfer highway for high-performance NO2 detection10.1016/j.apsusc.2021.150926 ↗
59. Enhanced gas sensing performance of electrospun Pt-Functionalized NiO nanotubes with chemical and electronic sensitization10.1021/am4017347 ↗
60. Investigation of electronic and chemical sensitization effects promoted by Pt and Pd nanoparticles on single-crystalline SnO nanobelt-based gas sensors10.1016/j.snb.2019.127055 ↗
61. Striking sensing improvement of n-type oxide nanowires by electronic sensitization based on work function difference10.1039/C4TC02057J ↗
62. Ag nanocrystal as a promoter for carbon nanotube-based room-temperature gas sensors10.1039/c2nr31556d ↗
63. An emphatic study on role of spill-over sensitization and surface defects on NO2 gas sensor properties of ultralong ZnO@Au heterojunction NRs10.1016/j.jallcom.2017.04.123 ↗
64. Highly sensitive NO2 detection on ppb level by devices based on Pd-loaded In2O3 hierarchical microstructures10.1016/j.snb.2017.05.113 ↗
65. Synthesis and acetone gas sensing properties of Ag activated hollow sphere structured ZnFe2O410.1016/j.ceramint.2018.08.064 ↗