journal article·2016-01

Structural and gas sensing properties of ex-situ oxidized Sn grown by thermal evaporation

A. Amutha, S. Amirthapandian, B. Sundaravel, A.K. Prasad, B.K. Panigrahi, P. Thangadurai

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Abstract

Abstract SnO 2 thin films were obtained by ex-situ oxidation of Sn metal film deposited by thermal evaporation. The oxidation of the Sn film was carried out at 600, 700 and 900 °C for 2 h in a controlled oxygen atmosphere. GIXRD confirmed the tetragonal rutile phase of SnO 2 which was further confirmed by Raman spectroscopy. The RBS measurements provided the thickness and chemical information of the film. Thickness of the film was in the range of 6⿿12 nm and the presence of Sn and oxygen in the films are shown. Scanning electron microscopy revealed spherical particles of different sizes for films annealed at different temperatures. The SnO 2 thin film oxidized at 900 °C was tested for methane gas sensing. A sensing response of 78.46% for 100 ppm of methane at an operating temperature of 100 °C which is one of lowest reported was obtained.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · ZnO doping and properties · Advanced Chemical Sensor Technologies

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References (42)

Show source-provided references
1. Low temperature methane sensing by electrochemically grown and surface modified ZnO thin films10.1016/j.snb.2008.07.021 ↗
2. Array of chromium doped nanostructured TiO2 metal oxide gas sensors10.1016/j.proeng.2014.11.345 ↗
3. Origins of coexistence of conductivity and transparency in SnO210.1103/PhysRevLett.88.095501 ↗
4. Novel single phase vanadium dioxide nanostructured films for methane sensing near room temperature10.1016/j.snb.2013.09.102 ↗
5. Analysis of the catalytic activity and electrical characteristics of different modified SnO2 layers for gas sensors10.1016/S0925-4005(02)00010-2 ↗
6. Nanocrystalline metal oxides for methane sensors: role of noble metals
7. Plasmonic-based SnO2 gas sensor with in-void segregated silver nanoparticles10.1016/j.mee.2013.11.005 ↗
8. Study of collective efforts of catalytic activity and photoactivation to enhance room temperature response of SnO2 thin film sensor for methane10.1016/j.snb.2013.03.100 ↗
9. Nanosensors: towards morphological control of gas sensing activity. SnO2, In2O3, ZnO and WO3 case studies10.1039/C0NR00560F ↗
10. Comparison of gas sensor performance of SnO2 nano-structures on microhotplate platforms10.1016/j.snb.2011.12.045 ↗
11. Ni2O3-decorated SnO2 particulate films for methane gas sensors10.1016/j.snb.2013.10.117 ↗
12. Methane gas sensing at relatively low operating temperature by hydrothermally prepared SnO2 nanorods10.1007/s11051-015-3089-z ↗
13. Novel fabrication of an SnO2 nanowire gas sensor with high sensitivity10.1088/0957-4484/19/9/095508 ↗
14. The role of morphology and crystallographic structure of metal oxides in response of conductometric-type gas sensors10.1016/j.mser.2008.02.001 ↗
15. Insights into microstructural evolution from nanocrystalline SnO2 thin films prepared by pulsed laser deposition10.1103/PhysRevB.70.165314 ↗
16. A novel methane sensor based on porous SnO2 nanorods: room temperature to high temperature detection10.1088/0957-4484/23/45/455501 ↗
17. The role of SnO2 quantum dots in improved CH4 sensing at low temperature10.1039/C3TC31728E ↗
18. Palladium⿿silver-activated ZnO surface: highly selective methane sensor at reasonably low operating temperature10.1021/am404883x ↗
19. A Parallel solid-state NMR and sensor property study on flower-like nanostructured SnO210.1021/jp1098156 ↗
20. Influences of cooling rate on gas sensitive tin oxide thin films and a model of gradient distributed oxygen vacancies in SnO2 crystallites10.1016/j.snb.2010.01.015 ↗
21. Microstructure dependent ammonia sensing properties of nanostuctured zinc oxide thin films using in-house designed gas exposure facility
22. SIMNRA user's guide
23. Alfassi · 2000
24. Analysis of depth redistribution of implanted Fe near SiO2/Si interface10.1016/j.nimb.2013.04.064 ↗
25. Microstructural investigation of Sn nanoclusters in double-energy implanted and annealed SiO2 layers with cross-sectional TEM10.1016/S0168-583X(99)00068-3 ↗
26. Nanostructured SnO2 films prepared from evaporated Sn and their application as gas sensors10.1088/0957-4484/19/12/125504 ↗
27. The kinetics of formation of gas-sensitive RGTO-SnO2 films10.1016/0040-6090(95)06583-0 ↗
28. Ostwald · Phys. Chem. · 1900 · 34 · 495
29. One-dimensional tin-oxide-coated single-wall carbon nanotubes for gas sensor applications10.3938/jkps.54.1893 ↗
30. Oxygen vacancy density-dependent transformation from infrared to Raman active vibration mode in SnO2 nanostructures10.1364/OL.36.004296 ↗
31. Nanoparticle size, oxidation state, and sensing response of tin oxide nanopowders using Raman spectroscopy10.1016/j.jallcom.2014.04.187 ↗
32. Raman scattering by silicon and germanium10.1103/PhysRev.155.712 ↗
33. Tailored nanoparticle films from monosized tin oxide nanocrystals: particle synthesis, film formation, and size-dependent gas-sensing properties10.1063/1.1525855 ↗
34. Semiconducting metal oxides as sensors for environmentally hazardous gases10.1016/j.snb.2011.08.032 ↗
35. Liquefied petroleum gas (LPG) sensing properties of nanocrystalline CdO thin films prepared by chemical route: effect of molarities of precursor solution10.1016/j.snb.2008.02.024 ↗
36. Synthesis and ethanol sensing characteristics of single crystalline SnO2 nanorods10.1063/1.2140091 ↗
37. Hall measurement studies and an electrical conduction model of tin oxide ultrafine particle films10.1063/1.331230 ↗
38. Linear sensing response to ethanol by indium oxide nanoparticle layers10.1155/2013/540741 ↗
39. Vasiliev · Phys. Technol. Semicond. · 2006 · 40 · 108
40. Grain size effects on H2 gas sensitivity of thick film resistor using SnO2 nanoparticles10.1016/S0040-6090(96)09152-3 ↗
41. Selective detection of methane and butane by temperature modulation in iron doped tin oxide sensors10.1016/j.snb.2005.10.046 ↗
42. Enhanced response characteristics of SnO2 thin film based sensors loaded with Pd clusters for methane detection10.1016/j.snb.2012.02.026 ↗