journal article·2024-07

Spherical and porous Cu2O nanocages with Cu2O/Cu(OH)2 Surface: Synthesis and their promising selectivity for catalysing CO2 electroreduction to C2H4

Tain-Kei Cheng, Nithiya Jeromiyas, Yi-Kai Lin, Cheng-Chun Yang, Chai-Lin Kao, Po-Yu Chen, Chien-Liang Lee

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. What would it take for renewably powered electrosynthesis to displace petrochemical processes?10.1126/science.aav3506 ↗
2. Production, use, and fate of all plastics ever made10.1126/sciadv.1700782 ↗
3. Boosting CO production in electrocatalytic CO2 reduction on highly porous Zn catalysts10.1021/acscatal.8b05109 ↗
4. Monodisperse Au nanoparticles for selective electrocatalytic reduction of CO2 to CO10.1021/ja409445p ↗
5. Tailoring electronic structure of bifunctional Cu/Ag layered electrocatalysts for selective CO2 reduction to CO and CH410.1016/j.nanoen.2020.105168 ↗
6. Highly selective electrocatalytic reduction of CO2 into methane on Cu–Bi nanoalloys10.1021/acs.jpclett.0c01261 ↗
7. Electrochemical fragmentation of Cu2O nanoparticles enhancing selective C-C coupling from CO2 reduction reaction10.1021/jacs.8b11237 ↗
8. Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene10.1038/ncomms12945 ↗
9. Cubic Cu2O on nitrogen-doped carbon shells for electrocatalytic CO2 reduction to C2H410.1016/j.carbon.2019.02.010 ↗
10. Boosting CO2 electroreduction to formate via in-situ formation of ultrathin bi nanosheets decorated with monodispersed Pd nanoparticles10.1016/j.jcat.2023.05.008 ↗
11. Efficient and selective electroreduction of CO2 to HCOOH over bismuth-based bromide perovskites in acidic electrolytes10.1002/chem.202201832 ↗
12. How to enhance the C2 products selectivity of copper-based catalysts towards electrochemical CO2 reduction?-a review10.1016/j.mattod.2023.05.028 ↗
13. Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes10.1016/S1381-1169(03)00016-5 ↗
14. Electrochemical CO2 reduction: a classification problem10.1002/cphc.201700736 ↗
15. New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces10.1039/c2ee21234j ↗
16. Cu2O nanoparticles with both 100 and 111 facets for enhancing the selectivity and activity of CO2 electroreduction to ethylene10.1002/advs.201902820 ↗
17. Promoting C2+ production from electrochemical CO2 reduction on shape-controlled cuprous oxide nanocrystals with high-index facets10.1021/acssuschemeng.0c04873 ↗
18. Phase engineering of Cu@Cu2O core-shell nanospheres for boosting tandem electrochemical CO2 reduction to C2+ products10.1016/j.apsusc.2023.156981 ↗
19. A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes10.1039/c1sc00277e ↗
20. Tailoring the surface and interface structures of copper-based catalysts for electrochemical reduction of CO2 to ethylene and ethanol10.1002/smll.202107450 ↗
21. Cu metal embedded in oxidized matrix catalyst to promote CO2 activation and CO dimerization for electrochemical reduction of CO210.1073/pnas.1702405114 ↗
22. Mixed copper states in anodized Cu electrocatalyst for stable and selective ethylene production from CO2 reduction10.1021/jacs.8b02173 ↗
23. Understanding the roles of hydroxide in CO2 electroreduction on a Cu electrode for achieving variable selectivity10.1021/acscatal.2c03650 ↗
24. Synergistic regulation of hydrophobicity and basicity for copper hydroxide-derived copper to promote the CO2 electroreduction reaction10.1002/cey2.328 ↗
25. Role of a hydroxide layer on cu electrodes in electrochemical CO2 reduction10.1021/acscatal.9b00896 ↗
26. Competitive enhancement of CO2 reduction reactions versus hydrogen evolution for high surface area electrodes: a comparative study for Cu and Ag nanomesh10.1016/j.electacta.2023.143495 ↗
27. Maximizing surface single-Ni sites on hollow carbon sphere for efficient CO2 electroreduction10.1021/acssuschemeng.3c06494 ↗
28. Steering C-C coupling by hollow Cu2O@C/N nanoreactors for highly efficient electroreduction of CO2 to C2+ products10.1002/adfm.202312719 ↗
29. Protecting copper oxidation state via intermediate confinement for selective CO2 electroreduction to C2+ fuels10.1021/jacs.0c01699 ↗
30. Measurement of oxygen reduction activities via the rotating disc electrode method: from Pt model surfaces to carbon-supported high surface area catalysts10.1016/j.electacta.2007.11.057 ↗
31. One-pot aqueous synthesis of two-dimensional porous bimetallic PtPd alloyed nanosheets as highly active and durable electrocatalyst for boosting oxygen reduction and hydrogen evolution10.1016/j.jcis.2019.01.122 ↗
32. Facile synthesis of platinum-rhodium alloy nanodendrites as an advanced electrocatalyst for ethylene glycol oxidation and hydrogen evolution reactions10.1016/j.jcis.2020.06.061 ↗
33. Platinum69-cobalt31 alloyed nanosheet nanoassemblies as advanced bifunctional electrocatalysts for boosting ethylene glycol oxidation and oxygen reduction10.1016/j.jcis.2018.04.050 ↗
34. Facile synthesis of low-dimensional PdPt nanocrystals for high-performance electrooxidation of alcohols10.1016/j.jcis.2021.12.022 ↗
35. Synthesis of Cu2O nanocrystals from cubic to rhombic dodecahedral structures and their comparative photocatalytic activity10.1021/ja209662v ↗
36. Supercapacitor based on the CuCo2S4@NiCoAl hydrotalcite array on Ni foam with high-performance10.1016/j.electacta.2020.136500 ↗
37. Capacitive performance of electrode materials affected by the Cu2O template morphologies in graphene/polyaniline nanotube/ZIF-67 nanocages porous composite10.1016/j.jelechem.2023.117726 ↗
38. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity10.1351/pac198557040603 ↗
39. Cu2O-Cu hybrid foams as high-performance electrocatalysts for oxygen evolution eeaction in alkaline media10.1021/acscatal.6b02911 ↗
40. Moulder · 1992
41. Stabilizing Cu2O for enhancing selectivity of CO2 electroreduction to C2H4 with the modification of Pd nanoparticles10.1016/j.cej.2022.139358 ↗
42. Rapid synthesis of Cu2O hollow spheres at low temperature and their catalytic performance for the decomposition of ammonium perchlorate10.1039/D1CE00663K ↗
43. Unveiling the synergistic effect between graphitic carbon nitride and Cu2O toward CO2 electroreduction to C2H410.1002/cssc.202002427 ↗
44. Efficient electroreduction of CO2 to C2–C3 products on Cu/Cu2O@N-doped graphene10.1016/j.jcou.2021.101594 ↗
45. Investigating the origin of enhanced C2+ selectivity in oxide-/hydroxide-derived copper electrodes during CO2 electroreduction10.1021/jacs.9b11790 ↗
46. Socrates · 1994
47. Macro- and mesoporous Cu2O/Cu3(OH)2 (CO3)2 synthesized by supercritical CO2 as an efficient catalyst for alcohol oxidation10.1016/j.jcou.2021.101551 ↗
48. comparative spectroscopic study eevealing why the CO2 electroreduction selectivity switches from CO to HCOO- at CuSn- and CuIn-based catalysts10.1021/acscatal.2c04419 ↗