Heat-resistant organic molecular layer as a joint interface for metal reduction on plastics surfaces
Source abstract
Abstract
Abstract Heat-resistant organic molecular layers have been fabricated by triazine-based silane coupling agent for metal reduction on plastic surfaces using adsorption method. These molecular layers were used as an interfacial layer between polyamide (PA6) and metal solution to reduce Ag+ ion to Ag0. The interfacial behaviors of triazine molecular layer at the interfaces between PA6 and Ag solution were investigated using quartz crystal microbalance (QCM). The kinetics of molecular adsorption on PA6 was investigated by using triazine-based silane coupling agent solutions at different pH and concentration. X-ray photoelectron spectroscopy (XPS), atomic force microscope (AFM), and local nano thermal analysis were employed to characterize the surfaces and interfaces. The nano thermal analysis results show that molecular layers of triazine-based silane coupling agent greatly improved heat resistance of PA6 resin from 170 °C up to 230 °C. This research developed an in-depth insight for molecular behaviors of triazine-based silane coupling agent at the PA6 and Ag solution interfaces and should be of significant value for interfacial research between plastics and metal solution in plating industry.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanofabrication and Lithography Techniques · Surface Modification and Superhydrophobicity · Recycling and Waste Management Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Direct electroplated metallization on indium Tin oxide plastic substrate10.1021/la404552c ↗
2. Hydrogen as an optimum reducing agent for metallization of self-assembled monolayers10.1039/c2jm32111d ↗
3. Ultra-small, high-frequency, and substrate-immune microtube inductors transformed from 2D to 3D
4. Wearable magnetic field sensors for flexible electronics10.1002/adma.201405027 ↗
5. 3D amino-induced electroless plating: a powerful toolset for localized metallization on polymer substrates10.1002/cphc.201100562 ↗
6. Microscopic study of a ligand induced electroless plating processes onto polymers10.1021/am100907j ↗
7. Selective adsorption of catalyst and copper plating for additive fabrication of conductive patterns and through-holes10.1016/j.electacta.2015.01.161 ↗
8. Electroless copper plating on PC engineering plastic with a novel palladium-free surface activation process10.1016/j.surfcoat.2014.04.005 ↗
9. Adhesion improvement of electroless copper plating on phenolic resin matrix composite through a tin-free sensitization process10.1016/j.apsusc.2013.01.188 ↗
10. Copper nanocrystal plane effect on stereoselectivity of catalytic deoxygenation of aromatic epoxides10.1021/jacs.5b01391 ↗
11. Metallic film formation using direct micropatterning with photoreactive metal complexes10.1021/la302437t ↗
12. Nickel: “The Spirited Horse” of transition metal catalysis10.1021/acscatal.5b00072 ↗
13. Recent advances on crosslinked dendritic networks10.1002/app.39876 ↗
14. Electrodeposition and radical polymerization to prepare cross-linked film of triazinethiol on aluminum surface10.1016/S1452-3981(23)11035-2 ↗
15. Hard and flexible nanocomposite coatings using nanoclay-filled hyperbranched polymers10.1021/am1001986 ↗
16. Ketocoumarin/triazine/thiol as new high speed photoinitiating system for free radical polymerization under visible light in aerated media10.1016/j.eurpolymj.2013.05.012 ↗
17. A. Veyland, N. Seeboth, Rubber Composition Including a 1,2,4-Trizaine Derivative, US Patent 0,100,323 (10.04.14).
18. Visible light sensitive photoinitiating system: recent progress in cationic and radical photopolymerization reactions under soft conditions10.1016/j.progpolymsci.2014.09.001 ↗
19. Adhesion of poly(phenylene surfide) resin with polymeric film of trazine thiol on aluminum surface modified by anodic oxidation10.1166/jbn.2015.2027 ↗
20. Sixivalent chromate-free resin plating10.4139/sfj.59.299 ↗
21. Formation of reflective and conductive silver film on ABS surface via covalent grafting and solution spray10.1016/j.apsusc.2015.05.039 ↗
22. Kinetics study of silver electrocrystallization on (3-mercaptopropyl) trimethoxysilane-grafted indium tin oxide plastic substrate10.1016/j.electacta.2015.01.117 ↗
23. Use of quartz crystal vibrator for weighting thin films on a microbalance10.1007/BF01337937 ↗
24. Effect of film thickness on the validity of the Sauerbrey equation for hydrated polyelectrolyte films10.1021/jp0481005 ↗
25. Adsorption behavior of triethoxysilyl propyl amino triazine dithiol on a polyamide surface studied by quartz crystal microbalance and nano thermal analysis of a trazine dithiol film10.4011/shikizai.87.345 ↗
26. Studies of interactions between silane coupling agents and cellulose fibers with liquid and solid-state NMR10.1002/mrc.1994 ↗
27. Kinetics of hydrolysis and self condensation reactions of silanes by NMR spectroscopy10.1016/j.colsurfa.2007.06.028 ↗
28. Competition between hydrolysis and condensation reactions of trialkoxysilanes, as a function of the amount of water and the nature of the organic group10.1016/j.colsurfa.2010.06.002 ↗
29. Plueddemann · 1991 · 55
30. Structure and antibacterial activity of silver-supporting activated carbon fibers10.1007/s10853-005-3149-3 ↗
31. Low-temperature sintered conductive silver patterns obtained by inkjet printing for plastic electronics10.1002/sia.3229 ↗
32. Single-step and rapid growth of silver nanoshells as SERS-active nanostructures for label-free detection of pesticides10.1021/am502435x ↗
33. Nanoscale thermal analysis of an energetic material10.1021/nl061196p ↗
34. Structural and mechanical characterization of γ-methacryloxypropyltrimethoxysilane (MPS) on Zn-electrocoated steel10.1163/016942410X507632 ↗
35. Surface molecular motion of the monodisperse polystyrene films10.1021/ma960582y ↗
36. Rheological analysis of surface relaxation process of monodisperse polystyrene films10.1021/ma000406w ↗
37. Effects of confinement on material behaviour at the nanometre size scale10.1088/0953-8984/17/15/R01 ↗