journal article·2015-10

Band alignment at the Cu2SnS3/In2S3 interface measured by X-ray photoemission spectroscopy

Hongjie Jia, Shuying Cheng, Hong Zhang, Jinling Yu, Yunfeng Lai

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Abstract

Abstract This paper focused on investigating the band alignment at the Cu2SnS3 (CTS)/In2S3 heterojunction interface by X-ray photoemission spectroscopy. An In2S3 over-layer was grown on a CTS thin film, which was grown by sulfurization of vacuum thermal evaporated Sn–Cu metallic precursors in a H2S:N2 atmosphere. The valence band offset (VBO) at the CTS/In2S3 interface was measured to be 1.27 ± 0.10 eV. The conduction band offset (CBO) was calculated from the measured VBO, giving (0.58 ± 0.10) eV. These values show that the CBO has a spike-like behavior and the interface is a ‘type I’.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications

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References (24)

Show source-provided references
1. Cu2SnS3 and Cu4SnS4 thin films via chemical deposition for photovoltaic application10.1149/1.3384660 ↗
2. CuxSnSx+1 (x=2, 3) thin films grown by sulfurization of metallic precursors deposited by dc magnetron sputtering10.1002/pssc.200982746 ↗
3. Growth of Cu2SnS3 thin films by solid reaction under sulphur atmosphere10.1016/j.vacuum.2010.10.001 ↗
4. A study of ternary Cu2SnS3 and Cu3SnS4 thin films prepared by sulfurizing stacked metal precursors10.1088/0022-3727/43/21/215403 ↗
5. Cu2SnS3 as a potential absorber for thin film solar cells10.1063/1.4710361 ↗
6. Fabrication of highly crystallized Cu2SnS3 thin films through sulfurization of Sn-rich metallic precursors10.1016/j.jallcom.2014.03.014 ↗
7. Control of doping in Cu2SnS3 through defects and alloying10.1021/cm501339v ↗
8. Fabrication of Cu2SnS3 thin films by sulfurization of evaporated Cu–Sn precursors for solar cells10.1002/pssc.201200866 ↗
9. Preparation of Cu2SnS3 thin films by sulfurization of Cu/Sn stacked precursors10.7567/JJAP.51.10NC35 ↗
10. Fabrication of ternary Cu–Sn–S sulfides by a modified successive ionic layer adsorption and reaction (SILAR) method10.1039/c2jm31669b ↗
11. Cu2SnS3 thin-film solar cells from electroplated precursors10.7567/JJAP.51.10NC34 ↗
12. Synthesis of earth-abundant Cu2SnS3 powder using solid state reaction10.1016/j.jpcs.2013.11.012 ↗
13. Synthesis, electrical conductivity, and crystal structure of Cu4Sn7S16 and structure refinement of Cu2SnS310.1006/jssc.1998.7822 ↗
14. Structural and optical properties of Cu2SnS3 sprayed thin films10.1016/j.tsf.2008.11.039 ↗
15. Facile solvothermal synthesis of Cu2SnS3 architectures and their visible-light-driven photocatalytic properties10.1016/j.matlet.2012.08.117 ↗
16. Valence band offset at the CdS/Cu2ZnSnS4 interface probed by X-ray photoelectron spectroscopy10.1088/0022-3727/46/17/175101 ↗
17. Study and enhance the photovoltaic properties of narrow-bandgap Cu2SnS3 solar cell by p-n junction interface modification10.1016/j.jcis.2012.03.015 ↗
18. Hydrazine processed Cu2SnS3 thin film and their application for photovoltaic devices
19. Thin film solar cells based on the ternary compound Cu2SnS310.1016/j.tsf.2012.05.085 ↗
20. Band alignment of SnS/Zn(O,S) heterojunctions in SnS thin film solar cells10.1063/1.4821433 ↗
21. Theoretical analysis of the effect of conduction band offset of window/CIS layers on performance of CIS solar cells using device simulation10.1016/S0927-0248(00)00266-X ↗
22. Precise determination of the valence-band edge in X-ray photoemission spectra: application to measurement of semiconductor interface potentials10.1103/PhysRevLett.44.1620 ↗
23. Alignment of energy levels at the ZnS/Cu(In,Ga)Se2 interface10.1039/c1ee01292d ↗
24. The band alignment at CdS/Cu2ZnSnSe4 heterojunction interface10.1002/sia.5095 ↗