journal article·2024-05

Influence of TiO2 structure on metal-support interactions in Rh/TiO2 catalysts probed by propylene hydrogenation and other techniques

Hanqin Zhao, Li-Yin Hsiao, Nicholas G. Rudawski, Bochuan Song, Po-Chien Kuan, Lauren Hullender, Helena Hagelin-Weaver

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OpenAlex topics: Catalytic Processes in Materials Science · Nanomaterials for catalytic reactions · Catalysis and Hydrodesulfurization Studies

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References (100+)

Show source-provided references
1. Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity10.1038/s41929-019-0364-x ↗
2. Metallic nanoparticles in heterogeneous catalysis10.1007/s10562-020-03477-5 ↗
3. Structural characteristics and mechanical and thermodynamic properties of nanocrystalline TiO210.1021/cr500072j ↗
4. Titanium dioxide (Anatase and Rutile): Surface chemistry, liquid solid interface chemistry, and scientific synthesis of supported catalysts10.1021/cr300230q ↗
5. Strong metal-support interactions - group-8 noble-metals supported on TiO210.1021/ja00469a029 ↗
6. Strong metal-support interactions10.1021/ar00143a001 ↗
7. Role of different active sites in heterogeneous alkene hydrogenation on platinum catalysts revealed by means of parahydrogen-induced polarization10.1021/jp203398j ↗
8. Brookite, the least known TiO2 photocatalyst10.3390/catal3010036 ↗
9. Why is anatase a better photocatalyst than rutile? - Model studies on epitaxial TiO2 films10.1038/srep04043 ↗
10. Trapping-induced enhancement of photocatalytic activity on brookite TiO2 powders: Comparison with anatase and rutile TiO2 powders10.1021/acscatal.7b00131 ↗
11. Size effect on phase transition sequence of TiO2 nanocrystal10.1016/j.msea.2005.04.029 ↗
12. Prediction of TiO2 nanoparticle phase and shape transitions controlled by surface chemistry10.1021/nl050355m ↗
13. Sonosynthesis of nanostructured TiO2 doped with transition metals having variable bandgap10.1016/j.ceramint.2012.09.042 ↗
14. Facet-dependent oxidative strong metal-support interactions of palladium–TiO2 determined by in situ transmission electron microscopy10.1002/anie.202106805 ↗
15. Optimisation of accurate rutile TiO2 (110), (100), (101) and (001) surface models from periodic DFT calculations10.1007/s00214-006-0189-y ↗
16. Adsorption configurations and reactions of nitric acid on TiO2 rutile (110) and anatase (101) surfaces10.1021/jp810635h ↗
17. Interplay of Pt and crystal facets of TiO2: CO oxidation activity and operando XAS/DRIFTS studies10.1021/acscatal.6b01509 ↗
18. Wet-chemistry strong metal-support interactions in titania-supported Au catalysts10.1021/jacs.8b10864 ↗
19. Strong metal-support interactions achieved by hydroxide-to-oxide support transformation for preparation of sinter-resistant gold nanoparticle catalysts10.1021/acscatal.7b01947 ↗
20. Strong metal-support interactions between gold nanoparticles and ZnO nanorods in CO oxidation10.1021/ja3033235 ↗
21. Influence of TiO2 bulk defects on CO adsorption and CO oxidation on Au/TiO2: electronic metal-support interactions (EMSIs) in supported au catalysts10.1021/acscatal.7b00251 ↗
22. Adsorbate-mediated strong metal-support interactions in oxide-supported Rh catalysts10.1038/nchem.2607 ↗
23. Tuning/exploiting strong metal-support interaction (SMSI) in heterogeneous catalysis10.1016/j.jtice.2017.02.012 ↗
24. Contribution of physical blocking and electronic effect to establishment of strong metal-support interaction in rhodium/titanium dioxide catalysts10.1021/ja00043a019 ↗
25. Strong metal–support interaction in heterogeneous catalysts10.1002/aenm.202201395 ↗
26. TiO2-supported Co catalysts for the hydrogenation of γ-valerolactone to 2-methyltetrahydrofuran: influence of the support, Catal
27. The surface science of titanium dioxide10.1016/S0167-5729(02)00100-0 ↗
28. Visible-light-mediated methane activation for steam methane reforming under mild conditions: A case study of Rh/TiO2 catalysts10.1021/acscatal.8b01787 ↗
29. Mechanistic study of low temperature CO2 methanation over Rh/TiO2 catalysts10.1016/j.jcat.2013.02.009 ↗
30. Hydrogenation of carbon dioxide on supported Rh catalysts10.3390/catal10020155 ↗
31. Photoenhanced reduction of CO2 by H2 over Rh/TiO2: Characterization of supported Rh species by means of infrared and X-ray absorption spectroscopy10.1016/S1381-1169(01)00204-7 ↗
32. Mechanistic in situ investigation of heterogeneous hydrogenation over Rh/TiO2 catalysts: selectivity, pairwise route and catalyst nature10.1039/C9FD00138G ↗
33. High-resolution 3D proton MRI of hyperpolarized gas enabled by parahydrogen and Rh/TiO2 heterogeneous catalyst10.1002/chem.201403604 ↗
34. Heterogeneous parahydrogen-induced polarization of diethyl ether for magnetic resonance imaging applications10.1002/chem.202003638 ↗
35. Mechanistic insight into the heterogeneous hydrogenation of furan derivatives with the use of parahydrogen10.1002/cctc.201701653 ↗
36. 2D mapping of NMR signal enhancement and relaxation for heterogeneously hyperpolarized propane gas10.1021/acs.jpcc.7b02506 ↗
37. NMR signal enhancement for hyperpolarized fluids continuously generated in hydrogenation reactions with parahydrogen10.1021/jp510572d ↗
38. Hydroformylation of dicyclopentadiene to monoformyltricyclodecenes over supported ultra-low content Rh catalysts10.3184/146867818X15233705894356 ↗
39. Alkali and Alkaline Earth Cation-Decorated TiO2 Nanotube-Supported Rh Catalysts for Vinyl Acetate Hydroformylation10.3390/catal9020194 ↗
40. Hydroformylation of 1-Hexene over Rh/Nano-Oxide Catalysts10.3390/catal3010324 ↗
41. Synthesis and characterization of TiO2 nanotube supported Rh-nanoparticle catalysts for regioselective hydroformylation of vinyl acetate10.1039/C4RA11156G ↗
42. Correlation of Rh particle size with CO chemisorption: Effect on the catalytic oxidation of MTBE10.3390/jcs3030081 ↗
43. The influence of preparation methods on strong metal support interaction (SMSI) in Rh/TiO2 system
44. Effect of the nature of TiO2 support over the performances of Rh/TiO2 catalysts in the partial oxidation of methane10.1016/j.cattod.2012.02.039 ↗
45. Catalytic selectivity of Rh/TiO2 catalyst in syngas conversion to ethanol: probing into the mechanism and functions of TiO2 support and promoter10.1039/C6CY02350A ↗
46. Tailored TiO2 nanostructures for supporting Rh3O2 and Rh0 nanoparticles: Enhanced photocatalytic H2 production10.1016/j.jphotochem.2017.12.037 ↗
47. Direct observation of the surfaces of small metal crystallites: rhodium supported on titania10.1021/la00082a009 ↗
48. Structure of Rh/TiO2 in the normal and the SMSI state as determined by extended X-Ray absorption fine-structure and high-resolution transmission electron-microscopy10.1021/j100318a041 ↗
49. Proton NMR procedure to estimate the extent of metal surface covered by titanium oxide overlayers in reduced rhodium/titania catalysts10.1021/j100162a006 ↗
50. Studies of the effect of strong metal-support interaction (SMSI) over model catalyst Rh/TiO210.1007/BF02096674 ↗
51. Ethene hydrogenation by Rh/TiO2 under SMSI conditions10.1007/BF02069073 ↗
52. Evidence for strong metal-support interaction (SMSI) in Rh/TiO2 system10.1007/BF00767384 ↗
53. Influence of strong metal–support interaction on exchange with deuterium and other reactions of hydrocarbons. Part 1. —Studies with Rh/TiO2 and Rh/SiO210.1039/FT9959100741 ↗
54. Depth profile analysis of strong metal-support interactions on RhTiO2 model catalysts10.1016/0168-583X(95)01480-2 ↗
55. Investigation of the Rh/TiO2 system by XPS and XAES10.1016/0169-4332(91)90056-P ↗
56. Structure-activity correlations on Rh/Al2O3 and Rh/TiO2 thin film model catalysts after oxidation and reduction10.1006/jcat.1999.2555 ↗
57. Rh-induced support transformation and Rh incorporation in titanate structures and their influence on catalytic activity10.3390/catal10020212 ↗
58. Strong metal-support interactions on rhodium model catalysts10.1016/j.apcata.2010.07.051 ↗
59. NbOPO4 supported Rh nanoparticles with strong metal−support interactions for selective CO2 hydrogenation10.1002/cssc.202001784 ↗
60. Nature of SMSI effect on CO + H2 reaction over supported rhodium catalysts10.1021/j100260a023 ↗
61. Elucidation of the high CO2 reduction selectivity of isolated Rh supported on TiO2: a DFT study, Catal
62. The effects of titania and alumina overlayers on the hydrogenation of CO over rhodium10.1039/f19878302061 ↗
63. The effect of oxidative and reductive treatments of titania-supported metal catalysts on the pairwise hydrogen addition to unsaturated hydrocarbons10.1016/j.cattod.2016.02.030 ↗
64. Strong metal-support interactions enhance the pairwise selectivity of parahydrogen addition over Ir/TiO210.1021/acscatal.5b02632 ↗
65. Citral hydrogenation over Rh and Pt catalysts supported on TiO2: Influence of the preparation and activation protocols of the catalysts10.1016/j.molcata.2011.01.020 ↗
66. Hydrogenolysis of light hydrocarbons on Rh/TiO2. Catalysts reduced at low temperature10.1007/BF02063476 ↗
67. CO hydrogenation on a highly loaded Rh/TiO2 catalyst and the influence of strong metal-support interaction10.1007/BF02062955 ↗
68. Crotonaldehyde hydrogenation on Rh/TiO2 catalysts. In situ DRIFTS studies
69. Reversibility of strong metal-support interactions on RhTiO210.1016/0021-9517(89)90313-8 ↗
70. Influence of the nature of the precursor salts on the properties of Rh–Ge/TiO2 catalysts for citral hydrogenation10.1016/j.jcat.2010.07.015 ↗
71. Imaging cluster surfaces with atomic resolution: the strong metal-support interaction state of Pt supported on TiO2(110)10.1103/PhysRevLett.84.3646 ↗
72. Effects of rhodium doping on the microstructures and photocatalytic performances of TiO2 powders
73. Influence of the crystal structure of titanium oxide on the catalytic activity of Rh/TiO2 in steam reforming of propane at low temperature10.1002/chem.201800936 ↗
74. Effect of a crystalline phase of TiO2 photocatalysts on the photodeposition of Rh metal nanoparticles10.1016/j.cattod.2013.09.024 ↗
75. Hydrogenation of crotonaldehyde on Pt/TiO2 catalysts: Influence of the phase composition of titania on activity and intramolecular selectivity10.1016/S0926-860X(97)00224-X ↗
76. Phase-Dependent Stability and Substrate-Induced Deactivation by Strong Metal-Support Interaction of Ru/TiO2 Catalysts for the Hydrogenation of Levulinic Acid10.1002/cctc.201802040 ↗
77. Selective hydrodeoxygenation of guaiacol to phenolics by Ni/anatase TiO2 catalyst formed by cross-surface migration of Ni and TiO210.1021/acscatal.9b00400 ↗
78. Manifestation of the effect of strong metal-support interaction in a Pt/TiO2 rutile catalyst10.1007/BF02771425 ↗
79. Classical strong metal–support interactions between gold nanoparticles and titanium dioxide10.1126/sciadv.1700231 ↗
80. Probing the interactions of Pt, Rh and bimetallic Pt–Rh clusters with the TiO2(110) support10.1016/j.susc.2007.05.030 ↗
81. The reversibility of strong metal-support interactions. A comparison of Pt/TiO2 and Rh/TiO2 catalysts10.1016/S0166-9834(00)81234-8 ↗
82. Encapsulation of Rh nanoparticles supported on TiO2(110)-(1×1) Surface: XPS and STM Studies10.1021/jp973255g ↗
83. Rh on TiO2: Model catalyst studies of the strong metal-support interaction10.1016/0378-5963(84)90070-9 ↗
84. Metal-support interactions in metal/oxide catalysts and oxide-metal interactions in oxide/metal inverse catalysts10.1021/acscatal.1c04854 ↗
85. A comparative study of strong metal–support interaction and catalytic behavior of Pd catalysts supported on micron- and nano-sized TiO2 in liquid-phase selective hydrogenation of phenylacetylene10.1016/j.molcata.2007.10.006 ↗
86. Size-dependent Pt-TiO2 strong metal-support interaction10.1021/acs.jpclett.0c01560 ↗
87. Disentangling the size-dependent geometric and electronic effects of palladium nanocatalysts beyond selectivity
88. Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts10.1038/s41467-020-19484-4 ↗
89. Structure Sensitivity of Au-TiO2 Strong Metal-Support Interactions10.1002/anie.202101928 ↗
90. Strong metal-support interactions between Pt single atoms and TiO210.1002/anie.202003208 ↗
91. Switchable tuning CO2 hydrogenation selectivity by encapsulation of the Rh nanoparticles while exposing single atoms10.1002/smll.202204490 ↗
92. Ag-loading on brookite TiO2 quasi nanocubes with exposed {210} and {001} facets: Activity and selectivity of CO2 photoreduction to CO/CH410.1016/j.apcatb.2015.06.022 ↗
93. Heterogeneous parahydrogen induced polarization on Rh-containing silicalite-1 zeolites: effect of the catalyst structure on signal enhancement, Catal
94. Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal-Organic Frameworks10.1002/anie.201908761 ↗
95. NaY Zeolite-supported rhodium and iridium cluster catalysts: Characterization by X-ray absorption spectroscopy during propene hydrogenation catalysis10.1006/jcat.1998.2306 ↗
96. Hydrogenation of olefins. Part 3. —Reaction of ethylene and of propylene with deuterium over alumina-supported palladium and rhodium10.1039/TF9666200443 ↗
97. Catalytic hydrogenation of propene over polymer supported rhodium complexes10.1016/S0022-328X(00)80883-9 ↗
98. Structure, reactivity, and mobility of carbonaceous overlayers during olefin hydrogenation on platinum and rhodium single crystal surfaces10.1007/s11244-005-3805-5 ↗
99. Catalysis by oxide-supported clusters of iridium and rhodium: Hydrogenation of ethene, propene, and toluene10.1021/jp0548523 ↗
100. Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool10.1063/1.4928614 ↗