Electrical and thermal properties of Cu-Ta films prepared by magnetron sputtering
Source abstract
Abstract
Abstract The microstructure, electrical resistivity and thermal conductivity of the sputtering deposited Cu-Ta films were investigated as a function of Ta content. The results showed that the amorphous phase formed between 20 at.% and 60 at.% Ta, and out of this range α-Cu(Ta) and β-Ta(Cu) solid solutions formed. Because the lattice distortion and β-Ta structure could significantly increase the probability of electron scattering, the electrical resistivity of the Cu-Ta films shows a ‘N’ type change with the increase of Ta content, and the inflection point appears at 50 at.% Ta and 60 at.% Ta respectively. As the thermal conductance is also dominated by electrons in metals films, an opposite variation tendency is found in the thermal conductivity of the Cu-Ta films. According to our knowledge, this is the first time to measure the thermal conductivity of Cu-Ta thin films.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Copper Interconnects and Reliability · Metal and Thin Film Mechanics · Electronic Packaging and Soldering Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (22)
Show source-provided references
1. Alloys created between immiscible elements10.1016/j.pmatsci.2004.07.001 ↗
2. The as-deposited structure of co-sputtered Cu–Ta alloys, studied by X-ray diffraction and molecular dynamics simulations10.1016/j.actamat.2014.08.066 ↗
3. An in situ X-ray diffraction study of phase separation in Cu-Ta alloy thin films10.1016/j.tsf.2015.12.028 ↗
4. Elastic modulus and hardness of Cu–Ta amorphous films10.1016/j.jallcom.2004.06.077 ↗
5. The effect of Cu: Ag atomic ratio on the properties of sputtered Cu–Ag alloy thin films10.3390/ma9110914 ↗
6. Roles of temperature and humidity in the oxidation of sputter-deposited Cu–Ta alloys in air10.1016/S0010-938X(01)00064-6 ↗
7. Phases in sputter-deposited Cu-Ta alloys10.1016/0921-5093(92)90153-R ↗
8. Effects of Sn Ca additions on thermal conductivity of Mg matrix alloys10.1179/1743284715Y.0000000128 ↗
9. The evaluation of cross-plane/in-plane thermal diffusivity using laser flash apparatus10.1016/j.tca.2017.04.011 ↗
10. Abnormal hardness behavior of Cu-Ta films prepared by magnetron sputtering10.1016/j.jallcom.2017.03.106 ↗
11. Alteration of Cu conductivity in the size effect regime10.1116/1.1642639 ↗
12. Characterization of microstructure, interfacial reaction and diffusion of immiscible Cu(Ta) alloy thin film on SiO2 at elevated temperature10.1149/1.1630597 ↗
13. An investigation of structural phase transformation and electrical resistivity in Ta films10.1016/j.apsusc.2010.08.023 ↗
14. Kittel · 1996
15. The mean free path of electrons in metals10.1080/00018735200101151 ↗
16. Electrical-resistivity model for polycrystalline films: the case of arbitrary reflection at external surfaces10.1103/PhysRevB.1.1382 ↗
17. T.S. Kuan, C.K. Inoki, G.S. Oehrlein, K. Rose, Y.P. Zhao, G.C. Wang, S.M. Rossnagel, C. Cabral, Fabrication and performance limits of sub-0.1 µm Cu interconnects, MRS Proc. 612 (2011).10.1557/PROC-612-D7.1.1 ↗
18. Evaluation of the thermal diffusivity of thin specimens from laser flash data10.1007/s10765-009-0561-y ↗
19. Tritt · 2005
20. Synthesis and characterization of nitrogen-doped graphene nanosheets/copper composite film for thermal dissipation10.1016/j.carbon.2017.03.025 ↗
21. Ueber die Wärme-Leitungsfähigkeit der Metalle10.1002/andp.18531650802 ↗
22. Deposition and structure of W-Cu multilayer coatings by magnetron sputtering10.1088/0022-3727/36/21/018 ↗