journal article·2017-09

Electrochemical surface functionalization of carbon fibers for chemical affinity improvement with epoxy resins

Panayiotis Kainourgios, Ioannis A. Kartsonakis, Dimitrios A. Dragatogiannis, Elias P. Koumoulos, Panagiotis Goulis, Costas A. Charitidis

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Abstract

Abstract The purpose of this study is to increase the wetting properties of carbon fibers in order to improve the adhesion force between the fiber and the polymer matrix. Commercial carbon fibers were surface functionalized through cyclic voltammetry together with potentiostatic conditions in aqueous electrolyte solutions of H 2 SO 4 , in the presence of acrylic acid, methacrylic acid, acrylonitrile and N-vinylpyrrolidone monomers. The anodic and cathodic peaks were correlated with oxide formation and their partial reduction, respectively. The produced surface modified carbon fibers were wetted with epoxy resin so that to produce dumbbell type composites for tensile strength testing. The nature of oxygen containing groups on the fibers surface was determined by Fourier-transform infrared and Raman spectroscopy. Moreover, the wetting properties of the treated carbon fibers were evaluated via contact angle measurements whereas the morphology of the coated fibers was investigated via scanning electron microscopy. Finally, the mechanical performance of the composites was evaluated by means of tensile testing and strength measurements.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fiber-reinforced polymer composites · Advanced Sensor and Energy Harvesting Materials · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. The uses of carbon fibers
2. Optimization of interfacial properties of carbon fiber/epoxy composites via a modified polyacrylate emulsion sizing10.1016/j.apsusc.2016.12.234 ↗
3. Surface treatment and sizing of carbon fibers
4. A novel surface modification of carbon fiber for high-performance thermoplastic polyurethane composites10.1016/j.apsusc.2016.04.118 ↗
5. Optimization of surface treatment to enhance fiber–matrix interface and performance of composites10.1016/j.wear.2011.09.014 ↗
6. Effects of surface treating methods of high-strength carbon fibers on interfacial properties of epoxy resin matrix composite10.1016/j.apsusc.2016.04.075 ↗
7. Effect of plasma surface treatment of recycled carbon fiber on carbon fiber-reinforced plastics (CFRP) interfacial properties10.1016/j.apsusc.2014.12.012 ↗
8. Role of surface chemistry in modified ACF (activated carbon fiber)-catalyzed peroxymonosulfate oxidation10.1016/j.apsusc.2016.04.163 ↗
9. Effect of UV and electrochemical surface treatments on the adsorption and reaction of linear alcohols on non-porous carbon fibre10.1016/j.apsusc.2012.12.173 ↗
10. Anisotropic in-plane gradients of poly(acrylic acid) formed by electropolymerization with spatiotemporal control of the electrochemical potential10.1021/ja0400436 ↗
11. The use of electropolymerization to produce new sensing surfaces: a review emphasizing electrode position of heteroaromatic compounds10.1002/elan.1140030903 ↗
12. Electropolymerization of pyrrole on PAN-based carbon fibers: experimental observations and a multiscale modeling approach10.1016/S0009-2509(01)00313-X ↗
13. Conjugated-polymer grafting on inorganic and organic substrates: a new trend in organic electronic materials10.1016/j.progpolymsci.2014.03.003 ↗
14. Study of carbon fibre surface treatments by dynamic mechanical analysis10.1007/BF00354259 ↗
15. Electrocoating of carbon fibres with polymers: 2. Electrocopolymerization of monofunctional monomers10.1016/0032-3861(92)91065-A ↗
16. The enhancement of carbon fiber modified with electropolymer coating to the mechanical properties of epoxy resin composites10.1016/j.compositesa.2008.04.004 ↗
17. Electropolymerization on graphite fibers10.1002/pen.760180708 ↗
18. Surface modification of pyrolyzed carbon fibres by cyclic voltammetry and their characterization with XPS and dye adsorption10.1016/j.electacta.2009.09.068 ↗
19. Synthesis and electropolymerization of 9-(4-vinylbenzyl)-9H-carbazole on carbon fiber microelectrode: capacitive behavior of poly(9-(4-vinylbenzyl)-9H-carbazole)10.1007/s12221-010-0331-2 ↗
20. Tensile and microindentation properties of maxillofacial elastomers after different disinfecting procedures10.1016/j.jmbbm.2013.07.013 ↗
21. Incorporation of ceramic nanocontainers into epoxy coatings for the corrosion protection of hot dip galvanized steel10.1016/j.corsci.2011.12.037 ↗
22. Droplet on a fiber: geometrical shape and contact angle10.1007/s00707-006-0349-0 ↗
23. Contact angle goniometry on single micron-scale fibers for composites10.1016/j.apsusc.2016.09.018 ↗
24. Cathodic electrografting of acrylics: from fundamentals to functional coatings10.1016/j.progpolymsci.2009.11.003 ↗
25. Effects of electrochemical and plasma treatments on carbon fibre surfaces10.1002/sia.740200506 ↗
26. Electrochemistry of N-vinyl-2-pyrrolidone and a non polymerizable analogue10.1016/S0032-3861(97)00236-X ↗
27. Production of polyacrylic acid homo- and copolymer films by electrochemically induced free-radical polymerization: preparation and swelling behavior10.1002/masy.200750222 ↗
28. The accurate measurement of contact angle, phase contact areas, drop volume, and Laplace excess pressure in drop-on-fiber systems10.1016/0021-9797(76)90227-7 ↗
29. Spreading of liquid droplets on cylindrical surfaces: accurate determination of contact angle10.1063/1.345689 ↗
30. A generalized drop length-height method for determination of contact angle in drop-on-fiber systems10.1006/jcis.1997.5218 ↗
31. Influence of absorbed moisture on surface hydrophobization of ethanol pretreated and plasma treated ramie fibers10.1016/j.apsusc.2011.12.126 ↗
32. Electro-copolymerization of acrylonitrile and methyl acrylate onto graphite fibers10.1002/app.1987.070340605 ↗
33. Generation of micro-scale finite element models from synchrotron X-ray CT images for multidirectional carbon fibre reinforced composites10.1016/j.compositesa.2016.09.010 ↗
34. Micro-CT analysis of the internal deformed geometry of a non-crimp 3D orthogonal weave E-glass composite reinforcement10.1016/j.compositesb.2013.11.024 ↗
35. Reliability evaluation of automated analysis, 2D scanner, and micro-tomography methods for measuring fiber dimensions in polymer-lignocellulosic fiber composites10.1016/j.compositesa.2016.07.020 ↗
36. Surface modification of zinc oxide nanoparticle by PMAA and its dispersion in aqueous system10.1016/j.apsusc.2005.08.004 ↗
37. Optimization of amine-terminated polyacrylonitrile synthesis and characterization10.1016/j.arabjc.2012.04.041 ↗
38. Controlling growth of ZnO rods by polyvinylpyrrolidone (PVP) and their optical properties10.1016/j.apsusc.2009.03.023 ↗
39. Microstructure evolution in γ-irradiated carbon fibers revealed by a hierarchical model and Raman spectra from fiber section10.1016/j.compscitech.2016.05.001 ↗
40. Raman spectroscopy for the nondestructive testing of carbon fiber10.1155/2008/693207 ↗
41. Microstructural heterogeneity on the cylindrical surface of carbon fibers analyzed by Raman spectroscopy10.1016/S1872-5805(15)60202-5 ↗
42. Surface structures of PAN-based carbon fibers and their influences on the interface formation and mechanical properties of carbon-carbon composites10.1016/j.compositesa.2016.08.023 ↗
43. Comparative study of the structure and microstructure of PAN-based nano- and micro-carbon fibers10.1016/j.ceramint.2016.04.055 ↗
44. Interfacially reinforced carbon fiber/epoxy composites by grafting melamine onto carbon fibers in supercritical methanol10.1039/C6RA00570E ↗
45. Amino-functionalization of carbon fibers through electron-beam irradiation technique10.1002/app.40274 ↗
46. Evaluation of fiber surface treatment on the interfacial behavior of carbon fiber-reinforced polypropylene composites10.1016/j.compositesb.2013.12.069 ↗