journal article·2022-03

Pre-intercalation δ-MnO2 Zinc-ion hybrid supercapacitor with high energy storage and Ultra-long cycle life

Simin He, Zunli Mo, Chao Shuai, Wentong Liu, Ruimei Yue, Guigui Liu, Hebing Pei, Ying Chen, Nijuan Liu, Ruibin Guo

Publisher page

Abstract

Abstract As an emerging research on multivalent zinc ion hybrid supercapacitors has been made huge leap, yet low cycle stability and low energy density are always the main bottlenecks of hybrid capacitors. The layered structure material Zn-doped δ-MnO2 to promote the insertion/extraction of zinc ions is used as the cathode and activated carbon is used as the anode exploiting battery and capacitor energy storage mechanism to increase energy density without sacrificing power density. Electrochemical measurements manifested that the assembled aqueous zinc ion hybrid capacitor has a high energy density of 157.2 Wh kg-1, a power density of 16 kW kg-1 (0.2 A g-1) and good cycling stability with 80.2% capacity retention over 30,000 charge/discharge cycles. The excellent electrochemical performance of the device is attributed to the stable layered structure of pre-zincified MnO2, which makes the insertion/extraction of Zn2+ greatly reversible. This study provides a novel strategy for new generation zinc ion hybrid capacitors.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (57)

Show source-provided references
1. Materials for electrochemical capacitors10.1038/nmat2297 ↗
2. Hybrid energy storage: the merging of battery and supercapacitor chemistries10.1039/C4CS00266K ↗
3. Insertion-type electrodes for nonaqueous Li-ion capacitors10.1021/cr5000915 ↗
4. Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities10.1002/aenm.201300816 ↗
5. Carbon-based materials as supercapacitor electrodes10.1039/b813846j ↗
6. Flexible electrodes and supercapacitors for wearable energy storage: a review by category10.1039/C5TA10582J ↗
7. Wearable fiber-shaped energy conversion and storage devices based on aligned carbon nanotubes10.1016/j.nantod.2016.08.010 ↗
8. Where do batteries end and supercapacitors begin?10.1126/science.1249625 ↗
9. Battery-supercapacitor hybrid devices: recent progress and future prospects10.1002/advs.201600539 ↗
10. A rechargeable aqueous zinc/sodium manganese oxides battery with robust performance enabled by Na2SO4 electrolyte additive[J]10.1016/j.ensm.2021.03.019 ↗
11. POM-based metal-organic framework/reduced graphene oxide nanocomposites with hybrid behavior of battery-supercapacitor for superior lithium storage10.1016/j.nanoen.2017.02.028 ↗
12. Achieving ultrahigh capacity with self-assembled Ni(OH)2 nanosheet-decorated hierarchical flower-like MnCo2O4.5 nanoneedles as advanced electrodes of battery–supercapacitor hybrid devices10.1021/acsami.8b21803 ↗
13. A nonaqueous potassium-based battery–supercapacitor hybrid device10.1002/adma.201800804 ↗
14. A review on recent advances in hybrid supercapacitors: Design, fabrication and applications10.1016/j.rser.2018.10.026 ↗
15. Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors10.1039/C9TA02678A ↗
16. “Water in salt/ionic liquid” electrolyte for 2.8 V aqueous lithium-ion capacitor10.1016/j.scib.2020.07.009 ↗
17. Two-dimensional materials for lithium/sodium-ion capacitors10.1016/j.mtener.2018.10.013 ↗
18. High-performance sodium-ion pseudocapacitors based on hierarchically porous nanowire composites10.1021/nn300920e ↗
19. Oxygen-functionalized soft carbon nanofibers as high-performance cathode of K-ion hybrid capacitor10.1016/j.nanoen.2020.104661 ↗
20. Zn-ion hybrid supercapacitors: achievements, challenges and future perspectives10.1016/j.nanoen.2021.105942 ↗
21. Evaluation of multivalent cation insertion in single-and double-layered polymorphs of V2O510.1021/acsami.7b05556 ↗
22. A conductive polymer coated MoO3 anode enables an Al-ion capacitor with high performance10.1039/C6TA01398H ↗
23. Recent progress and challenges of carbon materials for Zn-ion hybrid supercapacitors10.1002/cey2.69 ↗
24. Building better zinc-ion batteries: A materials perspective10.1016/j.enchem.2019.100022 ↗
25. Cathode materials for rechargeable zinc-ion batteries: From synthesis to mechanism and applications10.1016/j.jpowsour.2019.227596 ↗
26. Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries10.1016/j.nanoen.2020.104523 ↗
27. Flexible zinc-ion hybrid fiber capacitors with ultrahigh energy density and long cycling life for wearable electronics10.1002/smll.201903817 ↗
28. Boosting the electrochemical performance through proton transfer for the Zn-ion hybrid supercapacitor with both ionic liquid and organic electrolytes10.1039/C9TA01256G ↗
29. Multivalent ion storage towards high-performance aqueous zinc-ion hybrid supercapacitors10.1016/j.ensm.2018.10.020 ↗
30. Research progress in MnO2–carbon based supercapacitor electrode materials[J]10.1002/smll.201702883 ↗
31. Tuning phase evolution of β-MnO2 during microwave hydrothermal synthesis for high-performance aqueous Zn ion battery10.1016/j.nanoen.2019.103942 ↗
32. Fe-regulated δ-MnO2 nanosheet assembly on carbon nanofiber under acidic condition for high performance supercapacitor and capacitive deionization[J]10.1016/j.apsusc.2020.148715 ↗
33. Structure-tunable Mn3O4-Fe3O4@ C hybrids for high-performance supercapacitor[J]10.1016/j.jcis.2020.07.094 ↗
34. 3D interconnected boron-and nitrogen-codoped carbon nanosheets decorated with manganese oxides for high-performance capacitive deionization10.1016/j.carbon.2019.12.004 ↗
35. Engineering of MnO2-based nanocomposites for high-performance supercapacitors10.1016/j.pmatsci.2015.04.003 ↗
36. A superior δ-MnO2 cathode and a self-healing Zn-δ-MnO2 battery10.1021/acsnano.9b04916 ↗
37. Mxene-reduced graphene oxide aerogel for aqueous zinc-ion hybrid supercapacitor with ultralong cycle life10.1002/aelm.201900537 ↗
38. Fe-regulated δ-MnO2 nanosheet assembly on carbon nanofiber under acidic condition for high performance supercapacitor and capacitive deionization10.1016/j.apsusc.2020.148715 ↗
39. A multicore-shell architecture with a phase-selective (α+ δ) MnO2 shell for an aqueous-KOH-based supercapacitor with high operating potential10.1016/j.cej.2020.124028 ↗
40. Zn doped δ-MnO2 nano flakes: an efficient electrode material for aqueous and solid state asymmetric supercapacitors10.1016/j.apsusc.2018.04.081 ↗
41. Simple and cost-effective approach to dramatically enhance the durability and capability of a layered δ-MnO2 based electrode for pseudocapacitors: a practical electrochemical test and mechanistic revealing10.1021/acsaem.9b00075 ↗
42. Structural and electrochemical properties of layered manganese dioxides in relation to their synthesis: classical and sol–gel routes10.1039/JM9940400875 ↗
43. Electrochemical synthesis of layered manganese oxides intercalated with tetraalkylammonium ions10.1021/la048173f ↗
44. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe Co and Ni10.1016/j.apsusc.2010.10.051 ↗
45. Roselle-like Zn2Ti3O8/rGO nanocomposite as anode for lithium ion capacitor10.1016/j.cej.2019.123881 ↗
46. Biomaterial-based flower-like MnO2@ carbon microspheres for rapid adsorption of amoxicillin from wastewater10.1016/j.molliq.2020.113074 ↗
47. Efficient degradation of sulfadiazine using magnetically recoverable MnFe2O4/δ-MnO2 hybrid as a heterogeneous catalyst of peroxymonosulfate10.1016/j.colsurfa.2020.125637 ↗
48. Two-dimensional, porous nickel–cobalt sulfide for high-performance asymmetric supercapacitors10.1021/acsami.5b05400 ↗
49. High-power and ultralong-life aqueous zinc-ion hybrid capacitors based on pseudocapacitive charge storage10.1007/s40820-019-0328-3 ↗
50. Electrochemically induced structural transformation in a γ-MnO2 cathode of a high capacity zinc-ion battery system10.1021/cm504717p ↗
51. Binary and Ternary Manganese Dioxide Composites Cathode for Aqueous Zinc-ion Battery10.1002/slct.201802954 ↗
52. An aqueous zinc-ion hybrid super-capacitor for achieving ultrahigh-volumetric energy density10.1016/j.cclet.2020.06.037 ↗
53. Reversible aqueous zinc/manganese oxide energy storage from conversion reactions10.1038/nenergy.2016.39 ↗
54. Manganese sesquioxide as cathode material for multivalent zinc ion battery with high capacity and long cycle life10.1016/j.electacta.2017.01.163 ↗
55. Unravelling the reaction chemistry and degradation mechanism in aqueous Zn/MnO2 rechargeable batteries10.1039/C8TA01031E ↗
56. Inhibition of Manganese Dissolution in Mn2O3 Cathode with Controllable Ni2+ Incorporation for High-Performance Zinc Ion Battery10.1002/adfm.202009412 ↗
57. Highly reversible and rechargeable safe Zn batteries based on a triethyl phosphate electrolyte10.1002/anie.201813223 ↗