journal article·2020-09

H2O2 assisted hydrothermal oxidation of partially etched vanadium carbides (MXene) and their electrochemical properties as anode for Li-ion batteries

Wei Luo, Yi Liu, Fan Li, Jinghao Huo, Dan Zhao, Jianfeng Zhu, Shouwu Guo

Publisher page

Abstract

Abstract The novel V2CTx MXenes have gained increasing attention as anode materials in lithium-ion batteries, but to boost their practical to the theoretical values is still challenging. Herein, the partially etched V2CTx was oxidized in the presence of H2O2 through a hydrothermal reaction and the electrochemical properties of as-obtained oxidized V2CTx were assessed. It is illustrated that the oxidized V2CTx possesses a large surface interlayer spacing, and enriched with VO2 (A) and O-terminate groups. Once used as anode materials for Li-ion batteries, the oxidized V2CTx shows enhanced specific lithium ion storage capacities of 318 mAh·g−1 at 100 mA·g−1 after 100 cycles, and 125 mAh·g−1 at 1000 mA·g−1 after 1000 cycles, and better cycling stability and excellent rate performance over the V2CTx.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: MXene and MAX Phase Materials · 2D Materials and Applications · Advanced Memory and Neural Computing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (64)

Show source-provided references
1. Titanium carbide (MXene) as a current collector for lithium-ion batteries10.1021/acsomega.8b02032 ↗
2. One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes10.1039/C4CC01646G ↗
3. Highly self-healable 3D microsupercapacitor with MXene-graphene composite aerogel10.1021/acsnano.7b07528 ↗
4. Nanoengineering of 2D MXene-based materials for energy storage applications
5. Layered orthorhombic Nb2O5@Nb4C3Tx and TiO2@Ti3C2Tx hierarchical composites for high performance Li-ion batteries10.1002/adfm.201600682 ↗
6. Atomic Sn4+ decorated into vanadium carbide MXene interlayers for superior lithium storage10.1002/aenm.201802977 ↗
7. MXene electrochemical microsupercapacitor integrated with triboelectric nanogenerator as a wearable self-charging power unit10.1016/j.nanoen.2018.01.004 ↗
8. Ultrathin MXene nanosheets with rich fluorine termination groups realizing efficient electrocatalytic hydrogen evolution10.1016/j.nanoen.2018.03.022 ↗
9. A. Lipatov, H. Lu, M. Alhabeb, B. Anasori, A. Gruverman, Y. Gogotsi, A. Sinitskii, Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers, Sci. Adv. 4 (2018) eaat0491.10.1126/sciadv.aat0491 ↗
10. Asymmetric flexible MXene-reduced graphene oxide micro-supercapacitor10.1002/aelm.201700339 ↗
11. Self-assembly of transition metal oxide nanostructures on MXene nanosheets for Fast and Stable Lithium Storage10.1002/adma.201707334 ↗
12. TiO2/MXene Ti3C2 composite with excellent photocatalytic CO2 reduction activity10.1016/j.jcat.2018.03.009 ↗
13. Universal strategy for HF-free facile and rapid synthesis of two-dimensional MXenes as multifunctional energy materials10.1021/jacs.9b02578 ↗
14. NMR reveals the surface functionalisation of Ti3C2 MXene10.1039/C6CP00330C ↗
15. Cold sintered ceramic nanocomposites of 2D MXene and zinc oxide10.1002/adma.201801846 ↗
16. 25th Anniversary article: MXenes: A new family of two-dimensional materials10.1002/adma.201304138 ↗
17. 2D metal carbides and nitrides (MXenes) for energy storage10.1038/natrevmats.2016.98 ↗
18. 2D Metal carbides and nitrides (MXenes) as high-performance electrode materials for lithium-based batteries10.1002/aenm.201801897 ↗
19. Applications of 2D MXenes in energy conversion and storage systems10.1039/C8CS00324F ↗
20. MXene-based materials for electrochemical energy storage10.1016/j.jechem.2017.08.004 ↗
21. Recent advances in layered Ti3C2Tx MXene for electrochemical energy storage10.1002/smll.201703419 ↗
22. Searching for highly active catalysts for hydrogen evolution reaction based on O-terminated MXenes through a simple descriptor10.1021/acs.chemmater.6b03972 ↗
23. Direct measurement of surface termination groups and their connectivity in the 2D MXene V2CTx using NMR spectroscopy10.1021/acs.jpcc.5b03038 ↗
24. Heterostructures of MXenes and N-doped graphene as highly active bifunctional electrocatalysts10.1039/C8NR01090K ↗
25. Y. Xie, Y. Dall’Agnese, M. Naguib, Y. Gogotsi, M.W. Barsoum, H.L. Zhuang, P.R.C. Kent, Prediction and characterization of MXene nanosheet anodes for non-lithium-ion batteries, ACS Nano 8 (2014) 9606–9615.10.1021/nn503921j ↗
26. MXene: a promising transition metal carbide anode for lithium-ion batteries10.1016/j.elecom.2012.01.002 ↗
27. Surface functional groups and interlayer water determine the electrochemical capacitance of Ti3C2Tx MXene10.1021/acsnano.8b00676 ↗
28. Preparation of high-purity V2C MXene and electrochemical properties as Li-Ion batteries10.1149/2.0641704jes ↗
29. Ti-enhanced exfoliation of V2AlC into V2C MXene for lithium-ion battery anodes10.1016/j.ceramint.2017.06.016 ↗
30. Synthesis of NaV6O15 nanorods via thermal oxidation of sodium-intercalated 2D V2CTx and their electrochemical properties as anode for lithium-ion batteries10.1016/j.electacta.2017.07.143 ↗
31. Depressed phase transition in solution-grown VO2 nanostructures10.1021/ja902054w ↗
32. Graphene quantum dots coated VO2 arrays for highly durable electrodes for Li and Na ion batteries10.1021/nl504038s ↗
33. S. Lee, X.G. S, A.A. Lubimtsev, X. Gao, P. Ganesh, T.Z. Ward, G. Eres, M.F. Chisholm, S. Dai, H.N. Lee, Persistent electrochemical performance in epitaxial VO2(B), Nano Lett. 17(2017) 2229–2233.10.1021/acs.nanolett.6b04831 ↗
34. VO2 nanoflakes as the cathode material of hybrid magnesium-lithium-ion batteries with high energy density10.1021/acsami.7b02480 ↗
35. Electrospun vanadium-based oxides as electrode materials10.1016/j.jpowsour.2018.05.076 ↗
36. Recent efforts in design of TiO2 (B) anodes for high-rate lithium-ion batteries: A review10.1016/j.jpowsour.2019.227225 ↗
37. Rapid hydrothermal synthesis of VO2 (B) and its conversion to thermochromic VO2 (M1)10.1021/ic301201k ↗
38. Fabrication of composite nanoparticles based on VO2 with given structure and its optical and electrochemical performance10.1016/j.jpcs.2018.05.002 ↗
39. Polycrystalline VO2(M) with well-dispersed crystalline zones for enhanced electroactivity of lithium-ion batteries10.1016/j.jallcom.2019.152122 ↗
40. Controllable preparation of rGO/VO2 (B) intercalation thin films with high thermal sensitive properties10.1016/j.matchemphys.2018.07.030 ↗
41. VO2 (A)/graphene nanostructure: Stand up to Na ion intercalation/deintercalation for enhanced electrochemical performance as a Na-ion battery cathode10.1016/j.electacta.2018.10.010 ↗
42. Photoemission studies of fluorine functionalized porous graphitic carbon10.1063/1.3691888 ↗
43. XPS of cold pressed multilayered and freestanding delaminated 2D thin films of Mo2TiC2Tz and Mo2Ti2C3Tz (MXenes)10.1016/j.apsusc.2019.07.049 ↗
44. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni10.1016/j.apsusc.2010.10.051 ↗
45. Multi-layer Ti3C2Tx-nanoparticles (MXenes) as solid lubricants-Role of surface terminations and intercalated water10.1016/j.apsusc.2019.07.171 ↗
46. R. Deng, Bi. Chen, H. Li, K. Zhang, T. Zhang, Y. Yu, L. Song, MXene/Co3O4 composite material: Stable synthesis and its enhanced broadband microwave absorption, Appl. Surf. Sci. 488 (2019) 921–930.10.1016/j.apsusc.2019.05.058 ↗
47. New two-dimensional niobium and vanadium carbides as promising materials for Li-Ion batteries10.1021/ja405735d ↗
48. Two-dimensional vanadium carbide (MXene) as a high-capacity cathode material for rechargeable aluminum batteries10.1021/acsnano.7b05350 ↗
49. CO2 and temperature dual responsive ‘‘Smart’’ MXene phases10.1039/C4CC07220K ↗
50. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC210.1002/adma.201102306 ↗
51. Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries10.1016/j.nanoen.2017.08.002 ↗
52. In situ reaction synthesis and mechanical properties of V2AlC10.1111/j.1551-2916.2008.02774.x ↗
53. Synthesis and oxidation resistance of V2AlC powders by molten salt method10.1111/ijac.12723 ↗
54. Demonstration of a white laser with V2C MXene-based quantum dots10.1002/adma.201901117 ↗
55. Two-dimensional V4C3 MXene as high performance electrode materials for supercapacitors10.1016/j.electacta.2019.03.205 ↗
56. Synthesis and lithium ion storage performance of two-dimensional V4C3 MXene10.1016/j.cej.2019.05.037 ↗
57. Two-dimensional vanadium carbide MXene for gas sensors with ultrahigh sensitivity toward nonpolar gases10.1021/acssensors.9b00303 ↗
58. Insights into the thermal and chemical stability of multilayered V2CTx MXene under different environments10.1039/C9NR03020D ↗
59. 0D/2D NiS2/V-MXene composite for electrocatalytic H2 evolution10.1016/j.jcat.2019.05.019 ↗
60. X-ray photoelectron spectroscopy of select multi-layered transitionmetal carbides (MXenes)10.1016/j.apsusc.2015.11.089 ↗
61. Fluoride removal from liquid phase by Fe-Al-La trimetal hydroxides adsorbent prepared by iron and aluminum leaching from red mud10.1016/j.molliq.2017.04.097 ↗
62. Atomic cobalt covalently engineered interlayers for superior lithium-ion storage10.1002/adma.201802525 ↗
63. Si-based anode with hierarchical protective function and hollow ring-like carbon matrix for high performance lithium ion batteries10.1016/j.apsusc.2018.11.065 ↗
64. Porous two-dimensional transition metal carbide (MXene) flakes for high-performance Li-ion storage10.1002/celc.201600059 ↗