journal article·2013-04

Synthesis of C, Ag co-modified TiO2 photocatalyst and its application in waste water purification

Hui Liu, Xiaonan Dong, Guangjun Li, Xing Su, Zhenfeng Zhu

Publisher page

Abstract

Monodispersed C, Ag co-modified TiO2 microspheres were successfully synthesized through a two-step method. Firstly, monodisperse spherical TiO2 particles were obtained via controlled hydrolysis of TBOT (tetrabutyltitanate) in ethanol. Secondly, the C, Ag co-modified TiO2 microspheres were prepared through a simple calcination process, in which the AgNO3 and citric acid was used as Ag and C source, respectively. The physical and chemical properties of C, Ag co-modified TiO2 microspheres were carefully studied by using XRD, SEM, TEM, Raman, PL spectra and UV–vis diffuse reflectance spectra (DRS), while the chemical states of C and Ag were discussed via EDS (energy dispersive spectrometer) and XPS. The photocatalytic activity of the as-prepared products was evaluated by photocatalytic decolorization of Rhodamine B (Rh B) aqueous solution at ambient temperature under UV and visible-light irradiation. The photocatalytic activity research shows that, with the cooperation of two modified materials, C, Ag co-modified TiO2 microspheres exhibit enhanced photocatalytic activity both in ultraviolet and visible-light region compared with that of pure TiO2 and single Ag modified TiO2 microspheres.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Environmental applications of semiconductor photocatalysis10.1021/cr00033a004 ↗
2. Catalysis with TiO2/gold nanocomposites. Effect of metal particle size on the fermi level equilibration10.1021/ja0315199 ↗
3. Preparation and enhanced photocatalytic activity of Ag@TiO2 core–shell nanocomposite nanowires10.1016/j.jhazmat.2010.01.013 ↗
4. Surface-enhanced Raman scattering (SERS) activity of Ag, Au and Cu nanoclusters on TiO2-nanotubes/Ti substrate10.1016/j.apsusc.2010.12.048 ↗
5. Controlled synthesis of Ag/TiO2 core–shell nanowires with smooth and bristled surfaces via a one-step solution route10.1021/la052337q ↗
6. Spectroscopic studies of interfacial structures of CeO2–TiO2 mixed oxides10.1016/j.apsusc.2007.05.013 ↗
7. Sunlight photocatalytic activity of CdS modified TiO2 loaded on activated carbon fibers10.1016/j.apsusc.2009.12.062 ↗
8. The enhanced photocatalytic activity of CdS/TiO2 nanocomposites by controlling CdS dispersion on TiO2 nanotubes10.1016/j.apsusc.2011.02.007 ↗
9. Preparation and characterization of SnO2/ZnO/TiO2 composite semiconductor with enhanced photocatalytic activity10.1016/j.apsusc.2012.05.078 ↗
10. Characterization of carbon-doped TiO2 nanostructures with enhanced visible light response10.1021/cm071244m ↗
11. EPR analysis of carbon-doped titanium dioxide photocatalysts (TiO2−xC)10.1016/j.ssnmr.2009.02.004 ↗
12. Characterization of TiO2@C core–shell nanoparticles and evaluation of their photocatalytic activities10.1021/cm052790n ↗
13. Nonmetal species in the carbon modified TiO2 and its visible light photocatalytic activity10.1016/j.apsusc.2012.11.154 ↗
14. Surface characteristics and photoactivity of silver-modified palygorskite clays coated with nanosized titanium dioxide particles10.1016/j.matchar.2006.04.024 ↗
15. Controlled method for silica coating of silver colloids. influence of coating on the rate of chemical reactions10.1021/la980047m ↗
16. Nanocomposite of Ag–AgBr–TiO2 as a photoactive and durable catalyst for degradation of volatile organic compounds in the gas phase10.1016/j.apcatb.2011.06.002 ↗
17. Shape-dependent interplay between oxygen vacancies and Ag–CeO2 interaction in Ag/CeO2 catalysts and their influence on the catalytic activity10.1016/j.jcat.2012.06.025 ↗
18. Visible-light-driven photocatalysis on fluorine-doped TiO2 powders by the creation of surface oxygen vacancies10.1016/j.cplett.2004.11.126 ↗
19. Effects of simultaneously doped and deposited Ag on the photocatalytic activity and surface states of TiO210.1021/jp0469618 ↗
20. Enhanced photocatalytic activity of bimodal mesoporous titania powders by C60 modification10.1039/c1dt10274e ↗
21. Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/C3N4 composites10.1021/jp200953k ↗
22. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide10.1016/j.carbon.2007.02.034 ↗
23. Au-Pd alloying-promoted thermal decomposition of PdO supported on SiO2 and its effect on the catalytic performance in CO oxidation10.1016/j.cattod.2010.10.018 ↗
24. Enhanced photocatalytic activity of mesoporous TiO2 aggregates by embedding carbon nanotubes as electron-transfer channel10.1039/C0CP01139H ↗
25. Synthesis and characterization of porous and nonporous mondisperse colloidal TiO2 particles10.1021/cm0348949 ↗