journal article·2020-04

Robust corrosion resistance and self-healing characteristics of a novel Ce / Mn conversion coatings on EV31 magnesium alloys

Shun-Yi Jian, Chia-Yu Yang, Jun-Kai Chang

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Abstract

Abstract Magnesium alloys have been widely employed in the aerospace and aviation applications due to the unique properties. Nevertheless, Mg alloys were sensitive to corrosion attacks. The use of hexavalent chromium has been strictly banned because of severe toxicity and harm, even though it provided useful protective coating. Many efforts have been made to find the alternative process to hexavalent chromium conversion process. In this study, the Ce / Mn conversion coating was developed on EV31 Mg alloy. A thin, homogeneous, and compact conversion coating layers was formed. The electrochemical impedance spectroscopy (EIS), potentiodynamic polarization tests and salt spray test (SST) were used to evaluate the corrosion resistance of the coatings accompanying with a cross-cut scratches. The total impedance of the Ce / Mn conversion coating rose to 2.3 × 103 Ω‧cm2 compared with 3.4 × 102 of the bare EV31. Furthermore, the Ce / Mn conversion coating passed the 168 h of SST with less than 3% corrosion area, and meanwhile the self-healing worked effectively. Both barrier protection and characteristic self-healing effect enhanced corrosion resistance on EV31. Furthermore, a corrosion mechanism for the coating in practice was proposed to discussion.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Corrosion Behavior and Inhibition · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (72)

Show source-provided references
1. Elektron 21 – an aerospace magnesium alloy for sand cast and investment cast applications10.1002/adem.200700165 ↗
2. Corrosion resistance of Elektron 21magnesium alloy
3. On the corrosion of binary magnesium-rare earth alloys10.1016/j.corsci.2008.12.012 ↗
4. Electrochemical behaviour and corrosion of Mg–Y alloys10.1016/j.corsci.2011.03.010 ↗
5. Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5 wt.% NaCl solution10.1016/j.corsci.2011.10.033 ↗
6. Corrosion mitigation of rare-earth metals containing magnesium EV31A-T6 alloy via chrome-free conversion coating treatment10.1016/j.electacta.2013.07.043 ↗
7. DSC investigation on WE43 and Elektron 21 Mg alloys10.1007/s10853-006-6375-4 ↗
8. Kielbus · J. Achiev. Mater. Manuf. Eng. · 2007 · 20 · 127
9. Effects of Nd on microstructures and properties at the elevated temperature of a Mg–0.3Zn–0.32Zr alloy10.1016/j.matdes.2010.04.021 ↗
10. Macroscopic, thermodynamic, kinetic and microscopic study of nitric acid pickling of Elektron 21 (EV31A) magnesium alloy10.1016/j.jma.2014.11.009 ↗
11. Corrosion rate determination of rare-earth Mg alloys in a Na2SO4 solution by electrochemical measurements and inductive coupled plasma-optical emission spectroscopy10.1016/j.jma.2018.12.002 ↗
12. A phosphate-permanganate conversion coating for magnesium10.1016/0026-0576(96)80428-4 ↗
13. A chromium-free conversion coating of magnesium alloy by a phosphate–permanganate solution10.1016/j.surfcoat.2005.07.064 ↗
14. Formation of phosphate/permanganate conversion coating on AZ31 magnesium alloy10.1149/1.2164787 ↗
15. Evaluation of electrochemical and surface characteristics of conversion coatings on ZM21 magnesium alloy10.1179/174329406X122892 ↗
16. A chrome-free conversion coating for magnesium–lithium alloy by a phosphate–permanganate solution10.1016/j.surfcoat.2007.07.094 ↗
17. Protective coating for magnesium alloy10.1007/s10853-007-1796-2 ↗
18. Structure and formation mechanism of phosphate conversion coating on die-cast AZ91D magnesium alloy10.1016/j.corsci.2007.08.007 ↗
19. Corrosion behaviour of chemical conversion treatments on as-cast Mg–Al alloys: Electrochemical and non-electrochemical methods10.1016/j.corsci.2010.02.036 ↗
20. Effect of permanganate concentration on the formation and properties of phosphate/permanganate conversion coating on AZ31 magnesium alloy10.1016/j.corsci.2013.01.014 ↗
21. Deposition, characterization and electrochemical properties of permanganate-based coating treatments over ZE41 Mg-Zn-rare earth alloy10.1016/S1452-3981(23)13192-0 ↗
22. The effect of solution pH of permanganate coating on the electrochemical characteristics of ZE41 magnesium alloy in chloride media10.1016/S1452-3981(23)07956-7 ↗
23. Permanganate conversion coating on AZ31 magnesium alloys with enhanced corrosion resistance10.1016/j.corsci.2015.01.040 ↗
24. An investigation of Mn−Ce−Based conversion coating on LZ91 magnesium alloy10.20964/2018.08.69 ↗
25. Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys10.1016/j.corsci.2004.06.016 ↗
26. Cerium conversion coatings for AZ91D magnesium alloy in ethanol solution and its corrosion resistance10.1016/j.corsci.2009.08.003 ↗
27. Advanced microcapsules for self-healing conversion coating on magnesium alloy in Ce(NO3)3 solution with microcapsules containing La(NO3)310.1016/j.surfcoat.2016.09.024 ↗
28. Corrosion resistance of ceria/polymethyltrimethoxy silane modified magnesium hydroxide coating on AZ31 magnesium alloy10.1016/j.surfcoat.2017.08.039 ↗
29. Stannate and permanganate conversion coatings on AZ31 magnesium alloy10.1016/j.corsci.2007.04.011 ↗
30. Stannate conversion coatings on Mg–8Li alloy10.1016/j.jallcom.2008.03.041 ↗
31. Characteristics and corrosion studies of vanadate conversion coating formed on Mg–14wt%Li–1wt%Al–0.1wt%Ce alloy10.1016/j.apsusc.2012.07.069 ↗
32. Mechanism of the formation of stannate and cerium conversion coatings on AZ91D magnesium alloys10.1016/j.apsusc.2013.03.136 ↗
33. Yellow chromate conversion coatings on zinc: Electrochemical measurements and corrosion tests10.1002/maco.19780291004 ↗
34. On the structure and chemical composition of chromium based conversion coatings on aluminium: a TOF SIMS study10.1039/a807389i ↗
35. Thin film analysis of chromium-phosphate conversion coatings on aluminium probed by ToF-SIMS and electron probe x-ray analysis10.1002/1096-9918(200008)30:1<589::AID-SIA706>3.0.CO;2-N ↗
36. Cerium-based chemical conversion coating on AZ63 magnesium alloy10.1016/S0257-8972(03)00336-0 ↗
37. Corrosion behaviors in physiological solution of cerium conversion coatings on AZ31 magnesium alloy10.1016/j.apsusc.2011.04.141 ↗
38. Effect of cerium additive on aluminum-based chemical conversion coating on AZ91D magnesium alloy10.1016/j.apsusc.2013.05.012 ↗
39. Self-repairing vanadium–zirconium composite conversion coating for aluminum alloys10.1016/j.apsusc.2013.05.015 ↗
40. Protective coatings on magnesium and its alloys – a critical review10.1016/S0925-8388(01)01899-0 ↗
41. Evaluation of corrosion resistance and self-healing behavior of zirconium–cerium conversion coating developed on AA2024 alloy10.1016/j.surfcoat.2015.02.049 ↗
42. Evaluation of self-healing ability of Ce–V conversion coating on AZ31 magnesium alloy10.1016/j.jma.2016.06.003 ↗
43. Intelligent saline enabled self-healing of multilayer coatings and its optimization to achieve redox catalytically provoked anti-corrosion ability10.1016/j.apsusc.2016.04.178 ↗
44. Study of selective deposition mechanism of cerium-based conversion coating on Rheo-HPDC aluminium-silicon alloys10.1016/j.electacta.2017.09.182 ↗
45. Effect of inhibitor loading into nanocontainer additives of self-healing corrosion protection coatings on aluminum alloy A35610.1016/j.jallcom.2017.08.037 ↗
46. Self-healing ability of nanoclay-based hybrid sol-gel coatings on magnesium alloy AZ91D10.1016/j.surfcoat.2016.12.018 ↗
47. Study of reinforcing steel corrosion behaviour treated by bluing and cerium chemical conversion treatments, part I: Conventional electrochemical techniques10.1016/j.cemconcomp.2018.03.012 ↗
48. A simple one step cerium conversion coating formation on to magnesium alloy and electrochemical corrosion performance10.1016/j.surfcoat.2018.06.051 ↗
49. The role of post-treatment of an ecofriendly cerium nanostructure conversion coating by green corrosion inhibitor on the adhesion and corrosion protection properties of the epoxy coating10.1016/j.porgcoat.2017.09.015 ↗
50. Evaluation of self-healing properties of inhibitor loaded nanoclay-based anticorrosive coatings on magnesium alloy AZ91D10.1016/j.jma.2018.05.003 ↗
51. Marine corrosion resistance of CeO2/Mg(OH)2 mixed coating on a low alloyed steel10.1016/j.surfcoat.2019.05.053 ↗
52. Crack self-healing of phytic acid conversion coating on AZ31magnesium alloy by heat treatment and the corrosion resistance10.1016/j.apsusc.2014.06.104 ↗
53. Optimization of process factors for self-healing vanadium-based conversion coating on AZ31 magnesium alloy10.1016/j.apsusc.2015.07.052 ↗
54. The effects of a phytic acid/calcium ion conversion coating on the corrosion behavior and osteoinductivity of a magnesium-strontium alloy10.1016/j.apsusc.2019.04.107 ↗
55. L. Huang, J. Li, W. Yuan, X. Liu, Z. Li, Y. Zheng, Y. Liang, S. Zhu, Z. Cui, X. Yang, K.W.K. Yeung, S. Wu, Near-infrared light controlled fast self-healing protective coating on magnesium alloy, Corros. Sci. https://doi.org/10.1016/j.corsci.2019.108257.10.1016/j.corsci.2019.108257 ↗
56. Characterization of protective coatings by electrochemical impedance spectroscopy and a thermostimulated current method: influence of the polymer binder10.1016/S0010-938X(00)00005-6 ↗
57. The anodic dissolution of magnesium in chloride and sulphate solutions10.1016/S0010-938X(97)00090-5 ↗
58. Corrosion behaviour of AZ21, AZ501 and AZ91 in sodium chloride10.1016/S0010-938X(98)00078-X ↗
59. AC impedance spectroscopy in characterizing time-dependent corrosion of AZ91 and AM50 magnesium alloys characterization with respect to their microstructures10.1149/1.1415722 ↗
60. The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions10.1016/S0010-938X(00)00095-0 ↗
61. An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions10.1149/1.2401056 ↗
62. New insights into the fundamental chemical nature of ionic liquid film formation on magnesium alloy surfaces10.1021/am900023j ↗
63. Mcdonald · 1987
64. Fractality and impedance of electrochemically grown silver deposits10.1149/1.2086233 ↗
65. X-ray Photoelectron Spectroscopy Database 20, Version 4.1, National Institute of Standards and Technology.
66. Influence of cerium on passivity behavior of wrought AZ91 alloy10.1016/j.electacta.2008.06.073 ↗
67. Sol–gel coatings doped with organosilane and cerium to improve the properties of hot-dip galvanized steel
68. Investigation of the self-healing properties of shape memory polyurethane coatings with the ‘odd random phase multisine’ electrochemical impedance spectroscopy10.1016/j.electacta.2010.01.027 ↗
69. Copper(II) 8-hydroxyquinolinate 3D network film with corrosion inhibitor embedded for self-healing corrosion protection10.1016/j.corsci.2013.05.014 ↗
70. A kinetic study of the permanganate-manganous ion reaction to form manganic ion in sulfuric acid media10.1021/ic50128a046 ↗
71. Formation of rare earth-permanganate conversion coating on AZ61 magnesium alloy and its properties
72. Inhibition effect of cerium in hybrid sol–gel films on aluminium alloy AA202410.1002/sia.3198 ↗