Nitrogen and phosphorous Co-Doped Laser-Induced Graphene: A High-Performance electrode material for supercapacitor applications
Source abstract
Abstract
Abstract A versatile and cost-effective strategy is demonstrated to produce N and P co-doped laser-induced graphene (NP-LIG) based on a duplicate laser pyrolysis method. The dopant precursor concentration and laser power significantly affected the surface chemistry and electrochemical performance of the NP-LIG. The NP-LIG optimized with 3 wt% H3PO4 and laser power of 3.5 W (NP3-LIG-3.5) in the second pyrolysis step demonstrated an impressive specific areal capacitance (CA) of 163.6 mF/cm2 at 0.2 mA/cm2 in a three-electrode system where 1 M H2SO4 was used as an aqueous electrolyte. Furthermore, the solid-state NP3-LIG-3.5 supercapacitor (NP3-LIG-SC) assembled with a gel electrolyte (PVA-H2SO4) showed a high CA of 69.7 mF/cm2 at 0.05 mA/cm2, which is 4 and 13 times higher, respectively, than those of N-doped LIG and singly pyrolyzed LIG SCs. In addition, the NP3-LIG-SC exhibited good cycling stability (capacitance retention of 84% after 10,000 cycles), a Coulombic efficiency of approximately 100%, and a high areal energy density of 9.67 µWh/cm2. This study proposes a facile method for the fabrication of heteroatom-co-doped LIG electrodes for use in flexible and wearable electronics.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Sensor and Energy Harvesting Materials · Laser-Ablation Synthesis of Nanoparticles
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (72)
Show source-provided references
1. Electrochemical Capacitors for Energy Management10.1126/science.1158736 ↗
2. Electrochemical Capacitors: Challenges and Opportunities for Real-World Applications, The10.1149/2.F08081IF ↗
3. An activated carbon monolith as an electrode material for supercapacitors10.1016/j.carbon.2008.09.048 ↗
4. Graphene-based materials as supercapacitor electrodes10.1039/c000417k ↗
5. Measurement of the quantum capacitance of graphene10.1038/nnano.2009.177 ↗
6. High-Surface-Area Nitrogen-Doped Reduced Graphene Oxide for Electric Double-Layer Capacitors10.1002/cssc.201500122 ↗
7. Metal Oxide/Graphene Composites for Supercapacitive Electrode Materials10.1002/asia.201501072 ↗
8. Functionalization of Graphene for Efficient Energy Conversion and Storage10.1021/ar300122m ↗
9. Tailoring the structural properties of simultaneously reduced and functionalized graphene oxide via alkanolamine(s)/alkyl alkanolamine for energy storage applications10.1016/j.cej.2019.01.110 ↗
10. Electrochemical behavior of glycine-mediated N-doped reduced graphene oxide10.1039/C7NJ01662J ↗
11. Single precursor mediated one-step synthesis of ternary-doped and functionalized reduced graphene oxide by pH tuning for energy storage applications10.1016/j.cej.2017.08.040 ↗
12. Surface modification of co-doped reduced graphene oxide through alkanolamine functionalization for enhanced electrochemical performance10.1039/C7NJ03592F ↗
13. Heteroatom doped graphene engineering for energy storage and conversion10.1016/j.mattod.2020.04.010 ↗
14. Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications10.1039/c3ee41444b ↗
15. Heteroatom-doped graphene materials: syntheses, properties and applications10.1039/C4CS00141A ↗
16. Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis
17. Transient laser heating induced hierarchical porous structures from block copolymer–directed self-assembly10.1126/science.aab0492 ↗
18. Laser-Induced Graphene: En Route to Smart Sensing10.1007/s40820-020-00496-0 ↗
19. Physical Sensors Based on Laser-Induced Graphene: A Review10.1109/JSEN.2020.3034845 ↗
20. Laser-Induced Graphene from Wood Impregnated with Metal Salts and Use in Electrocatalysis10.1021/acsanm.8b01163 ↗
21. Oxidized Laser-Induced Graphene for Efficient Oxygen Electrocatalysis10.1002/adma.201707319 ↗
22. Facile Patterning of Laser-Induced Graphene with Tailored Li Nucleation Kinetics for Stable Lithium-Metal Batteries10.1002/aenm.201901796 ↗
23. Quasi-Solid-State Li–O2 Batteries with Laser-Induced Graphene Cathode Catalysts10.1021/acsaem.9b02182 ↗
24. Three-dimensional laser-induced holey graphene and its dry release transfer onto Cu foil for high-rate energy storage in lithium-ion batteries10.1016/j.apsusc.2021.150416 ↗
25. Laser-Induced Graphene: From Discovery to Translation10.1002/adma.201803621 ↗
26. Flexible and Stackable Laser-Induced Graphene Supercapacitors10.1021/am509065d ↗
27. Laser-Induced Graphene Derived from Kraft Lignin for Flexible Supercapacitors10.1021/acsomega.0c01293 ↗
28. Flexible Boron-Doped Laser-Induced Graphene Microsupercapacitors10.1021/acsnano.5b00436 ↗
29. Facile fabrication of flexible all solid-state micro-supercapacitor by direct laser writing of porous carbon in polyimide10.1016/j.carbon.2014.11.017 ↗
30. Low-resistance laser-induced graphitic carbon by maximizing energy delivery and pulse overlap10.1016/j.carbon.2021.05.037 ↗
31. Highly Efficient Laser Scribed Graphene Electrodes for On-Chip Electrochemical Sensing Applications10.1002/aelm.201600185 ↗
32. Laser-Scribed Graphene Electrodes for Aptamer-Based Biosensing10.1021/acssensors.7b00066 ↗
33. All in the graphene family – A recommended nomenclature for two-dimensional carbon materials10.1016/j.carbon.2013.08.038 ↗
34. Laser-induced porous graphene films from commercial polymers10.1038/ncomms6714 ↗
35. Laser-Induced Graphene10.1021/acs.accounts.8b00084 ↗
36. Laser-induced graphene for environmental applications: progress and opportunities, Materials Chemistry
37. In situ formation of phosphorus-doped porous graphene via laser induction10.1039/D0RA03363D ↗
38. One-step laser fabrication of phosphorus-doped porous graphene electrodes for high-performance flexible microsupercapacitor10.1016/j.carbon.2021.05.001 ↗
39. Facile and Scalable Fabrication of High-Performance Microsupercapacitors Based on Laser-Scribed In Situ Heteroatom-Doped Porous Graphene10.1021/acsami.1c03219 ↗
40. Simultaneous densification and nitrogen doping of laser-induced graphene by duplicated pyrolysis for supercapacitor applications10.1016/j.jpowsour.2019.227199 ↗
41. Nitrogen and Boron Co-doped Densified Laser-induced Graphene for Supercapacitor Applications10.1016/j.cej.2021.131119 ↗
42. A novel sol-gel strategy for N, P dual-doped mesoporous carbon with high specific capacitance and energy density for advanced supercapacitors10.1016/j.cej.2020.124710 ↗
43. Phosphorus-containing carbons: Preparation, properties and utilization10.1016/j.carbon.2019.10.018 ↗
44. Nitrogen/phosphorus co-doped porous carbon materials for supercapacitor electrodes10.1039/D1NJ01091C ↗
45. Heteroatom-doped graphene-based materials for sustainable energy applications: A review10.1016/j.rser.2021.110849 ↗
46. Ultrahigh rate capability supercapacitors based on tremella-like nitrogen and phosphorus co-doped graphene, Materials Chemistry
47. Manipulation of Heteroatom Substitution on Nitrogen and Phosphorus Co-Doped Graphene as a High Active Catalyst for Hydrogen Evolution Reaction10.1021/acs.jpcc.9b04607 ↗
48. Densified Laser-Induced Graphene for Flexible Microsupercapacitors10.3390/en13246567 ↗
49. Wrinkled, rippled and crumpled graphene: an overview of formation mechanism, electronic properties, and applications10.1016/j.mattod.2015.10.002 ↗
50. Sepia-Derived N
51. SWCNT-bridged laser-induced graphene fibers decorated with MnO2 nanoparticles for high-performance flexible micro-supercapacitors10.1016/j.carbon.2021.07.014 ↗
52. Nitrogen
53. Laser-induced nitrogen-self-doped graphite nanofibers from cyanate ester for on-chip micro-supercapacitors10.1016/j.cej.2020.126375 ↗
54. Effect of surface phosphorus functionalities of activated carbons containing oxygen and nitrogen on electrochemical capacitance10.1016/j.carbon.2009.02.006 ↗
55. P/N co-doped microporous carbons from H3PO4-doped polyaniline by in situ activation for supercapacitors10.1016/j.carbon.2013.03.052 ↗
56. Phosphorus- and Nitrogen-Doped Carbon Nanosheets Constructed with Monolayered Mesoporous Architectures10.1021/acs.chemmater.0c00731 ↗
57. Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation10.1021/ja101749y ↗
58. N/P Codoped Porous Carbon-Coated Graphene Nanohybrid as a High-Performance Electrode for Supercapacitors10.1021/acsanm.8b01552 ↗
59. X-ray photoelectron spectroscopy (XPS) and FTIR studies of vanadium barium phosphate glasses10.1016/j.matchemphys.2013.10.013 ↗
60. Two-Dimensional Carbon Nanosheets for High-Performance Supercapacitors: Large-Scale Synthesis and Codoping with Nitrogen and Phosphorus10.1021/acs.iecr.7b03022 ↗
61. Synthesis of Phosphorus-Doped Graphene and its Wide Potential Window in Aqueous Supercapacitors, Chemistry – A10.1002/chem.201404779 ↗
62. Laser induced graphene printing of spatially controlled super-hydrophobic/hydrophilic surfaces10.1016/j.carbon.2020.03.002 ↗
63. Tuning the Nature of N-Based Groups From N-Containing Reduced Graphene Oxide: Enhanced Thermal Stability Using Post-Synthesis Treatments10.3390/nano10081451 ↗
64. Thiamine-Based Nitrogen
65. Nitrogen–phosphorus co-doped hollow carbon microspheres with hierarchical micro–meso–macroporous shells as efficient electrodes for supercapacitors10.1039/C7TA07488C ↗
66. Energy Storage Data Reporting in Perspective—Guidelines for Interpreting the Performance of Electrochemical Energy Storage Systems10.1002/aenm.201902007 ↗
67. Use of Nutrient Rich Hydrophytes to Create N, P-Dually Doped Porous Carbon with Robust Energy Storage Performance10.1021/acs.est.6b03051 ↗
68. Transforming lignin into porous graphene via direct laser writing for solid-state supercapacitors10.1039/C9RA04073K ↗
69. Laser-induced and KOH-activated 3D graphene: A flexible activated electrode fabricated via direct laser writing for in-plane micro-supercapacitors10.1016/j.cej.2020.124672 ↗
70. Towards high performance flexible planar supercapacitors: In-situ laser scribing doping and reduction of graphene oxide films10.1016/j.apsusc.2021.149457 ↗
71. Tailoring the surface morphology and nanoparticle distribution of laser-induced graphene/Co3O4 for high-performance flexible microsupercapacitors10.1016/j.apsusc.2019.144487 ↗
72. CO2 Laser Direct Written MOF-Based Metal-Decorated and Heteroatom-Doped Porous Graphene for Flexible All-Solid-State Microsupercapacitor with Extremely High Cycling Stability10.1021/acsami.6b10193 ↗