journal article·2020-07-25Open access

Ammonia Gas Sensors: Comparison of Solid-State and Optical Methods

Zbigniew Bielecki, Tadeusz Stacewicz, Janusz Smulko, Jacek Wojtas

Applied Sciences· Volume 10· Issue 15

Abstract

High precision and fast measurement of gas concentrations is important for both understanding and monitoring various phenomena, from industrial and environmental to medical and scientific applications. This article deals with the recent progress in ammonia detection using in-situ solid-state and optical methods. Due to the continuous progress in material engineering and optoelectronic technologies, these methods are among the most perceptive because of their advantages in a specific application. We present the basics of each technique, their performance limits, and the possibility of further development. The practical implementations of representative examples are described in detail. Finally, we present a performance comparison of selected practical application, accumulating data reported over the preceding decade, and conclude from this comparison.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors · Advanced Chemical Sensor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Optoelectronics, Military University of Technology, 00-908 Warsaw, Poland

Institute of Experimental Physics, Faculty of Physics, University of Warsaw, 02-093 Warsaw, Poland

Faculty of Electronics, Telecommunications and Informatics, Gdansk University of Technology, 80-233 Gdansk, Poland

References (80)

Show source-provided references
1. An open-path optical fibre sensor for ammonia measurement in the ultraviolet region
2. Fast and accurate exhaled breath ammonia measurement
3. Ammonia gas sensors: A comprehensive review10.1016/j.talanta.2019.06.034 ↗
4. A potentiometric flow biosensor based on ammonia-oxidizing bacteria for the detection of toxicity in water10.3390/s130606936 ↗
5. An NH4+ biosensor based on ammonia-oxidizing bacteriafor use under anoxic conditions10.1016/j.snb.2004.06.030 ↗
6. A nonenzymatic biosensor based on gold electrodes modified with peptide self-assemblies for detecting ammonia and urea oxidation10.1021/la502315m ↗
7. Khan, I.R., Mohammad, A., and Asiri, A.M. (2019). Advanced Biosensors for Health Care Application, Elsevier. [1st ed.].
8. Nasiri, N., and Clarke, C. (2019). Nanostructured gas sensors for medical and health applications: Low to high dimensional materials. Biosensors, 9.10.3390/bios9010043 ↗
9. Highly sensitive and selective gas sensors using p-type oxide semiconductors: Overview10.1016/j.snb.2013.11.005 ↗
10. Highly sensitive NH3 sensor using Pt catalyzed silica coating over WO3 thick films10.1016/j.snb.2008.01.066 ↗
11. Determination of ammonia and urea in urine and of urea in blood by use of an ammonia-selective electrode10.1093/clinchem/25.11.1888 ↗
12. Ammonia sensors and their applications—A review10.1016/j.snb.2004.11.054 ↗
13. Determination Of Gas Mixture Components Using Fluctuation Enhanced Sensing And The LS-SVM Regression Algorithm10.1515/mms-2015-0039 ↗
14. Engineering approaches for the improvement of conductometric gas sensor parameters: Part 1. Improvement of sensor sensitivity and selectivity (short survey)10.1016/j.snb.2013.07.101 ↗
15. Extracting information from noise spectra of chemical sensors: Single sensor electronic noses and tongues10.1016/S0925-4005(00)00586-4 ↗
16. Dziedzic, A., Kolek, A., and Licznerski, B. (1999, January 18–20). Noise and nonlinearity of gas sensors–preliminary results. Proceedings of the 22nd International Spring Seminar on Electronics Technology, Dresden-Freital, Germany.
17. Hazardous gases detection by fluctuation-enhanced gas sensing10.1142/S0219477510000277 ↗
18. Fluctuation enhanced gas sensing with WO3-based nanoparticle gas sensors modulated by UV light at selected wavelengths10.1016/j.snb.2016.05.032 ↗
19. Portable exhaled breath analyzer employing fluctuation-enhanced gas sensing method in resistive gas sensors10.24425/123892 ↗
20. Pattern analysis for machine olfaction: A review10.1109/JSEN.2002.800688 ↗
21. Balandin, A.A., and Rumyantsev, S. (2019). Low-Frequency Noise in Low-Dimensional van der Waals Materials. arXiv.
22. Donarelli, M., and Ottaviano, L. (2018). 2d materials for gas sensing applications: A review on graphene oxide, MoS2, WS2 and phosphorene. Sensors, 18.10.3390/s18113638 ↗
23. Selective sensing of individual gases using graphene devices10.1109/JSEN.2013.2251627 ↗
24. Investigation of Ammonia Gas Sensing Properties of Graphite Oxide10.1016/j.proeng.2016.11.169 ↗
25. Highly transparent and flexible polyaniline mesh sensor for chemiresistive sensing of ammonia gas10.1039/C7RA13516E ↗
26. Flexible transparent reduced graphene oxide sensor coupled with organic dye molecules for rapid dual-mode ammonia gas detection10.1002/adfm.201505477 ↗
27. A Fully Integrated Wireless Flexible Ammonia Sensor Fabricated by Soft Nano-Lithography10.1021/acssensors.8b01690 ↗
28. Flexible room temperature ammonia sensor based on polyaniline10.1016/j.snb.2016.08.173 ↗
29. Current Trends in Sensors Based on Conducting Polymer Nanomaterials10.3390/nano3030524 ↗
30. Room Temperature Ammonia Gas Sensing Using Polyaniline Nanoparticles Based Sensor
31. Šetka, M., Drbohlavová, J., and Hubálek, J. (2017). Nanostructured polypyrrole-based ammonia and volatile organic compound sensors. Sensors, 17.10.3390/s17030562 ↗
32. Gas sensors based on conducting polymers10.3390/s7030267 ↗
33. SnO2 nanoparticle-coated In2O3 nanofibers with improved NH3 sensing properties10.1016/j.snb.2013.12.115 ↗
34. NH3 gas sensor based on Pd/SnO2/RGO ternary composite operated at room-temperature10.1016/j.snb.2015.09.091 ↗
35. Wu, H., Ma, Z., Lin, Z., Song, H., Yan, S., and Shi, Y. (2019). High-sensitive ammonia sensors based on tin monoxide nanoshells. Nanomaterials, 9.10.3390/nano9030388 ↗
36. A hybrid material consisting of bulk-reduced TiO2, graphene oxide and polyaniline for resistance based sensing of gaseous ammonia at room temperature10.1007/s00604-016-1912-6 ↗
37. FFT analysis of temperature modulated semiconductor gas sensor response for the prediction of ammonia concentration under humidity interference10.1016/j.microrel.2018.03.034 ↗
38. Electrochemically functionalized single-walled carbon nanotube gas sensor10.1002/elan.200603527 ↗
39. Enhanced ammonia-sensing properties of PANI-TiO2-Au ternary self-assembly nanocomposite thin film at room temperature10.1016/j.snb.2017.01.046 ↗
40. Fabrication of polyaniline/titanium dioxide composite nanofibers for gas sensing application10.1016/j.matchemphys.2011.04.045 ↗
41. Room temperature ammonia sensor based on copper nanoparticle intercalated polyaniline nanocomposite thin films10.1016/j.apsusc.2015.02.164 ↗
42. Enhanced sensitivity of ammonia sensor using graphene/polyaniline nanocomposite10.1016/j.snb.2013.01.014 ↗
43. Handheld, Colorimetric Optoelectronic Dynamics Analyzer for Measuring Total Ammonia of Biological Samples10.1109/JTEHM.2018.2840678 ↗
44. Fischbacher, B., Lechner, B., and Brandstätter, B. (2019). Ammonia distribution measurement on a hot gas test bench applying tomographical optical methods. Sensors, 19.10.3390/s19040896 ↗
45. Revisiting the photoabsorption spectrum of NH3 in the 5.4–10.8 eV energy region10.1063/1.5128051 ↗
46. Low and room temperature photoabsorption cross sections of NH3 in the UV region10.1016/S0032-0633(98)00074-9 ↗
47. Roodenko, K., Hinojos, D., Hodges, K.L., Veyan, J.F., Chabal, Y.J., Clark, K., Katzir, A., and Robbins, D. (2019, January 2–3). Non-dispersive infrared (NDIR) sensor for real-time nitrate monitoring in wastewater treatment. Proceedings of the Optical Fibers and Sensors for Medical Diagnostics and Treatment Applications XIX, San Francisco, CA, USA.10.1117/12.2506550 ↗
48. Rapid, Time-Division multiplexed, Direct Absorptionand wavelength modulation-spectroscopy10.3390/s141121497 ↗
49. Mitra, C., and Sharma, R. (2016). Diode Laser-Based Sensors for Extreme Harsh Environment Data Acquisition. High Energy and Short Pulse Lasers, InTech.10.5772/63971 ↗
50. (2020, February 20). IRcell–Long Path in a Compact Design. Available online: https://dea47l1p89u26.cloudfront.net/wp-content/uploads/2017/12/IRcell-green-product.jpg.
51. A computerized classification technique for screening for the presence of breath biomarkers in lung cancer10.1093/clinchem/34.8.1613 ↗
52. Cavity ring-down spectroscopy: Experimental schemes and applications10.1080/014423500750040627 ↗
53. Pound-Drever-Hall-locked, frequency-stabilized cavity ring-down spectrometer10.1063/1.3595680 ↗
54. Spectral line-shapes investigation with Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectroscopy10.1140/epjst/e2013-01990-0 ↗
55. Cavity enhanced absorption and cavity enhanced magnetic rotation spectroscopy10.1063/1.1149176 ↗
56. Sensitive detection of NO2 with cavity enhanced spectroscopy
57. Applying CEAS method to UV, VIS, and IR spectroscopy sensors
58. Stacewicz, T., Wojtas, J., Bielecki, Z., Nowakowski, M., Mikołajczyk, J., Mędrzycki, R., and Rutecka, B. (2012). Cavity ring down spectroscopy: Detection of trace amounts of substance. Opto-Electron. Rev., 20.10.2478/s11772-012-0006-1 ↗
59. Wojtas, J., Bielecki, Z., Stacewicz, T., Mikołajczyk, J., and Nowakowski, M. (2012). Ultrasensitive laser spectroscopy for breath analysis. Opto-Electron. Rev., 20.10.2478/s11772-012-0011-4 ↗
60. Quartz-enhanced photoacoustic spectroscopy employing pilot line manufactured custom tuning forks10.1016/j.pacs.2019.100158 ↗
61. Quartz tuning fork embedded off-beam quartz-enhanced photoacoustic spectroscopy10.1364/OL.44.002562 ↗
62. A calibration-free ammonia breath sensor using a quantum cascade laser with WMS 2f/1f10.1007/s00340-013-5701-1 ↗
63. Open-path cavity ring-down spectroscopy sensor for atmospheric ammonia10.1007/s00340-016-6461-5 ↗
64. High-resolution spectral analysis of ammonia near 6.2 μm using a cw EC-QCL coupled with cavity ring-down spectroscopy10.1039/C7AN02008B ↗
65. Off-axis cavity enhanced spectroscopy based on a pulsed quantum cascade laser for sensitive detection of ammonia and ethylene10.1364/AO.49.005302 ↗
66. Current status of mid-infrared semiconductor-laser-based sensor technologies for trace-gas sensing applications
67. Lewicki, R., Kosterev, A.A., Bakhirkin, Y.A., Thomazy, D.M., Doty, J., Dong, L., Tittel, F.K., Risby, T.H., Solga, S., and Kane, D. (2009). Real Time Ammonia Detection in Exhaled Human Breath with a Quantum Cascade Laser Based Sensor. Conference on Lasers and Electro-Optics/International Quantum Electronics Conference, OSA.10.1364/CLEO.2009.CMS6 ↗
68. Application of quantum cascade lasers to trace gas detection
69. Detection of gaseous compounds with different techniques10.1515/mms-2016-0026 ↗
70. Breath Analysis Using Laser Spectroscopic Techniques: Breath Biomarkers, Spectral Fingerprints, and Detection Limits10.3390/s91008230 ↗
71. Breath ammonia measurement in Helicobacter pylori infection10.1023/A:1020568227868 ↗
72. A selected ion flow tube mass spectrometry study of ammonia in mouth- and nose-exhaled breath and in the oral cavity10.1002/rcm.3434 ↗
73. Detection of volatile organic compounds as biomarkers in breath analysis by different analytical techniques10.4155/bio.13.183 ↗
74. Cavity-enhanced optical frequency comb spectroscopy: Application to human breath analysis10.1364/OE.16.002387 ↗
75. Detection of disease markers in human breath with laser absorption spectroscopy
76. MOFs for the Sensitive Detection of Ammonia: Deployment of fcu-MOF Thin Films as Effective Chemical Capacitive Sensors10.1021/acssensors.7b00304 ↗
77. Mixed-Valence Cobalt(II/III) Metal–Organic Framework for Ammonia Sensing with Naked-Eye Color Switching10.1021/acsami.8b07770 ↗
78. Galstyan, V., Bhandari, M.P., Sberveglieri, V., Sberveglieri, G., and Comini, E. (2018). Metal Oxide Nanostructures in Food Applications: Quality Control and Packaging. Chemosensors, 6.10.3390/chemosensors6020016 ↗
79. Gutowski, P., Sankowska, I., Słupiński, T., Pierścińska, D., Pierściński, K., Kuźmicz, A., Gołaszewska-Malec, K., and Bugajski, M. (2019). Optimization of MBE Growth Conditions of In0.52Al0.48As Waveguide Layers for InGaAs/InAlAs/InP Quantum Cascade Lasers. Materials, 12.10.20944/preprints201905.0081.v1 ↗
80. Comparison of performance limits of HOT HgCdTe photodiodes with 2D material infrared photodetectors