journal article·2025-12

Lead-free halide double perovskite Cs4CuSb2Cl12 for self-powered humidity sensing devices

Udith Unnikrishnan P, Ashna K. Pramod, Sudip K Batabyal

Applied Physics A· Volume 131· Issue 12
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Perovskite Materials and Applications · Gas Sensing Nanomaterials and Sensors · Solar-Powered Water Purification Methods

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. S. Fang, H. Li, Y. Xie, H. Li, Y. Wang, Y. Shi, Zero-Dimensional Organic–Inorganic hybrid Copper-Based halides with highly efficient Orange–Red emission. Small. 17(42), 2103831 (2021). https://doi.org/10.1002/SMLL.20210383110.1002/SMLL.202103831 ↗
2. Y. Liu, J. Shen, Y.-F. Chang, A. Albert, C.O. Sreekala, Mixed organic halide perovskite energy harvester for solar cells. J. Phys. Conf. Ser. 2426(1), 012044 (2023). https://doi.org/10.1088/1742-6596/2426/1/01204410.1088/1742-6596/2426/1/012044 ↗
3. M.D. Prasad, M.G. Krishna, S.K. Batabyal, Silver bismuth iodide nanomaterials as Lead-Free perovskite for visible light photodetection. ACS Appl. Nano Mater. 4(2), 1252–1259 (2021). https://doi.org/10.1021/acsanm.0c0285710.1021/acsanm.0c02857 ↗
4. A. Chatterjee, A. Kathirvel, G.M. Thirugnasambandam, S.K. Batabyal, Self-powered bio-photodetector from the paper-like free-standing film of cyanobacteria Nostoc commune. Mater. Lett. 325, 132802 (2022). https://doi.org/10.1016/j.matlet.2022.13280210.1016/j.matlet.2022.132802 ↗
5. B. Chen, Z.J. Yu, S. Manzoor, S. Wang, W. Weigand, Z. Yu, G. Yang, Z. Ni, X. Dai, Z.C. Holman, J. Huang, Blade-Coated perovskites on textured silicon for 26%-Efficient monolithic Perovskite/Silicon tandem solar cells. Joule. 4(4), 850–864 (2020). https://doi.org/10.1016/j.joule.2020.01.00810.1016/j.joule.2020.01.008 ↗
6. J. Pal, S. Manna, A. Mondal, S. Das, K.V. Adarsh, A. Nag, Colloidal synthesis and photophysics of M 3 Sb 2 I 9 (M = Cs and Rb) nanocrystals: Lead-Free perovskites. Angew. Chem. Int. Ed. 56(45), 14187–14191 (2017). https://doi.org/10.1002/anie.20170904010.1002/anie.201709040 ↗
7. L. Zhang, K. Wang, B. Zou, Bismuth Halide Perovskite-Like Materials: current opportunities and challenges. ChemSusChem 12(8), 1612–1630 (2019). https://doi.org/10.1002/cssc.20180293010.1002/cssc.201802930 ↗
8. T. Cai, W. Shi, S. Hwang, K. Kobbekaduwa, Y. Nagaoka, H. Yang, K. Hills-Kimball, H. Zhu, J. Wang, Z. Wang, Y. Liu, D. Su, J. Gao, O. Chen, Lead-Free Cs 4 CuSb 2 Cl 12 layered double perovskite nanocrystals. J. Am. Chem. Soc. 142(27), 11927–11936 (2020). https://doi.org/10.1021/jacs.0c0491910.1021/jacs.0c04919 ↗
9. G.M. Mustafa, R. Waqar, S. Saba, N.A. Noor, Z. Farooq, M. Imran, R.B. Behram, Y.M. Alanazi, Theoretical investigations of optoelectronic and transport properties of halide based K 2 YAuX 6 (X = Cl, Br) double perovskites. Phys. Scr. 98(6), 065703 (2023). https://doi.org/10.1088/1402-4896/acd30f10.1088/1402-4896/acd30f ↗
10. G.M. Mustafa, I. Shahid, S. Saba, M. Ali, Z. Farooq, A. Mahmood, N.A. Noor, M. Amin, Exploring the Li2CuAlX6 (X = Cl, Br, I) Lead-Free double perovskites for energy harvesting applications. J. Mater. Res. 39(11), 1633–1643 (2024). https://doi.org/10.1557/s43578-024-01334-410.1557/s43578-024-01334-4 ↗
11. G.M. Mustafa, S. Saba, S.M. Ramay, M. Shahabuddin, N.A. Noor, S. Aftab, S. Atiq, Optoelectronic and transport properties of Lead-Free double perovskites Li2AgTlX6 (X = Cl, Br): A DFT study. Phys. B Condens. Matter. 680, 415831 (2024). https://doi.org/10.1016/j.physb.2024.41583110.1016/j.physb.2024.415831 ↗
12. G.M. Mustafa, M. Maqbool, Z. Ullah, N.A. Noor, M. Muzamil, Y. Mohammed Alanazi, S. Mumtaz, Computational investigations of optoelectronic properties of K2ScAuX6 (X = Cl, Br) double perovskites for energy harvesting devices. Chem. Phys. 571, 111920 (2023). https://doi.org/10.1016/j.chemphys.2023.11192010.1016/j.chemphys.2023.111920 ↗
13. G.M. Mustafa, S. Saba, Q. Mahmood, N.A. Kattan, N. Sfina, T. Alshahrani, A. Mera, G.A.M. Mersal, M.A. Amin, Study of Optoelectronic, Thermoelectric, mechanical properties of double perovskites Cs2AgAsX6 (X = Cl, Br, I) for solar cells and energy harvesting. Opt. Quantum Electron. 55(6), 527 (2023). https://doi.org/10.1007/s11082-023-04666-310.1007/s11082-023-04666-3 ↗
14. G.M. Mustafa, S. Saba, N.A. Noor, K. Ghaffoor, S. Mumtaz, R. Sharma, A. Ibrahim, A. Laref, Optoelectronic and transport properties of Lead-Free halide based Na2AgTlZ6 (Z = Cl, Br, I) double perovskites for energy harvesting applications. Inorg. Chem. Commun. 165, 112539 (2024). https://doi.org/10.1016/j.inoche.2024.11253910.1016/j.inoche.2024.112539 ↗
15. U. Mogera, A.A. Sagade, S.J. George, G.U. Kulkarni, Ultrafast response humidity sensor using supramolecular nanofibre and its application in monitoring breath humidity and flow. Sci. Rep. 4(1), 4103 (2014). https://doi.org/10.1038/srep0410310.1038/srep04103 ↗
16. H. Farahani, R. Wagiran, M. Hamidon, Humidity sensors Principle, Mechanism, and fabrication technologies: A comprehensive review. Sensors. 14(5), 7881–7939 (2014). https://doi.org/10.3390/s14050788110.3390/s140507881 ↗
17. Z. Weng, J. Qin, A.A. Umar, J. Wang, X. Zhang, H. Wang, X. Cui, X. Li, L. Zheng, Y. Zhan, Lead-Free Cs 2 BiAgBr 6 double Perovskite‐Based humidity sensor with superfast recovery time. Adv. Funct. Mater. 29(24) (2019). https://doi.org/10.1002/adfm.20190223410.1002/adfm.201902234 ↗
18. X.-M. Zhang, M.-L. Li, W.-T. Yang, Q.-Y. Wang, S.-C. Liu, C.-W. Zhang, Y.-T. Cao, G.-J. Wang, A general strategy for MOFs coupled to optical fiber for highly sensitive humidity sensing. Rare Met. 42(6), 1821–1828 (2023). https://doi.org/10.1007/s12598-022-02245-110.1007/s12598-022-02245-1 ↗
19. H. Dong, L.-X. Zhang, H. Xu, Y.-Y. Yin, Y.-F. Liu, L.-J. Bie, A highly efficient humidity sensor based on lead (II) coordination polymer via in-Situ decarboxylation and hydrolysis synthesis. Rare Met. 41(5), 1652–1660 (2022). https://doi.org/10.1007/s12598-021-01913-y10.1007/s12598-021-01913-y ↗
20. H. Dong, L.-X. Zhang, H. Xu, Y.-Y. Yin, X.-B. Zhao, L.-J. Bie, H-Bonding interactions enable a 3D pillared Cobalt (II) coordination polymer for touchless finger moisture detection. Tungsten. 5(1), 109–117 (2023). https://doi.org/10.1007/s42864-022-00159-010.1007/s42864-022-00159-0 ↗
21. W.H. Lee, J. Park, S.G. Yoon, H. Jin, J. Han, Y.S. Kim, Ionovoltaics in energy harvesting and applications: A journey from early development to current state-of‐the‐art. EcoMat. 5(11) (2023). https://doi.org/10.1002/eom2.1240810.1002/eom2.12408 ↗
22. H. Jin, J. Park, S.G. Yoon, W.H. Lee, Y.H. Cho, J. Han, Z. Yin, Y.S. Kim, Verification of carrier concentration-dependent behavior in water‐infiltration‐induced electricity generation by ionovoltaic effect. Small. 17(45) (2021). https://doi.org/10.1002/smll.20210344810.1002/smll.202103448 ↗
23. S.K. Sharma, M. Salesh, M.R. Subramaniam, B. Attarwala, A. Yella, Moisture-Induced ionovoltaic electricity generation by manipulating Organic–Inorganic hybrid halide perovskites. ACS Energy Lett. 8(5), 2259–2266 (2023). https://doi.org/10.1021/acsenergylett.3c0002310.1021/acsenergylett.3c00023 ↗
24. A.K. Pramod, S.S. Pramana, S.K. Batabyal, Ionovoltaic power generation based on Lead-Free layered Cs3Bi2Br9 perovskites nanosheets. Next Mater. 6, 100309 (2025). https://doi.org/10.1016/j.nxmate.2024.10030910.1016/j.nxmate.2024.100309 ↗
25. A.K. Pramod, P. Gayathri, M.R. Subramaniam, S. Ghosh, D.J. Yoo, S.K. Batabyal, Sensing and Ionovoltaic Power Generation of Two-Dimensional Cs 3 Sb 2 X 9 (X = Cl/Br/I) Perovskite Microcrystals. ACS Appl. Electron. Mater. 6(7), 5255–5268 (2024). https://doi.org/10.1021/acsaelm.4c0081810.1021/acsaelm.4c00818 ↗
26. A.K. Pramod, S.K. Batabyal, Moisture-Induced ionovoltaic electricity generation using lead free 2-Dimensional Cs 3 SbBiBr 9 perovskite. Sustain. Energy Fuels. 8(19), 4628–4637 (2024). https://doi.org/10.1039/D4SE00997E10.1039/D4SE00997E ↗
27. X.-D. Wang, N.-H. Miao, J.-F. Liao, W.-Q. Li, Y. Xie, J. Chen, Z.-M. Sun, H.-Y. Chen, D.-B. Kuang, The Top-down synthesis of Single-Layered Cs 4 CuSb 2 Cl 12 halide perovskite nanocrystals for photoelectrochemical application. Nanoscale. 11(12), 5180–5187 (2019). https://doi.org/10.1039/C9NR00375D10.1039/C9NR00375D ↗
28. J.M. Meenu, A. Shyam, A.G. Aswin, R. Swaminathan, Structural and optoelectronic studies of bicuos semiconductor: A potential photoconverter. Mater. Sci. Engineering: B 309, 117665 (2024). https://doi.org/10.1016/j.mseb.2024.11766510.1016/j.mseb.2024.117665 ↗
29. A. Shyam, S.A. Batabyal, S.K. Swaminathan, Exploration of the broadband photodetection feasibility of bicuos based heterostructure. Sens. Actuators Phys. 360, 114559 (2023). https://doi.org/10.1016/j.sna.2023.11455910.1016/j.sna.2023.114559 ↗
30. A.K. Pramod, M. Raj Subramaniam, S.A. Hevia, S.K. Batabyal, Synthesis of Lead-Free Cs3Sb2Cl3Br6 halide perovskite through solution processing method for Self-Powered photodetector applications. Mater. Lett. 306, 130874 (2022). https://doi.org/10.1016/j.matlet.2021.13087410.1016/j.matlet.2021.130874 ↗
31. P.M. Jayasankar, A.K. Pathak, S.P. Madhusudanan, S. Murali, S.K. Batabyal, Double perovskite Cs4CuSb2Cl12 microcrystalline device for cost effective photodetector applications. Mater. Lett. 263, 127200 (2020). https://doi.org/10.1016/J.MATLET.2019.12720010.1016/J.MATLET.2019.127200 ↗
32. S. Parveen, L.T. Manamel, A. Mukherjee, S. Sagar, B.C. Das, Analog memristor of Lead-Free Cs4CuSb2Cl12 layered double perovskite nanocrystals as Solid-State electronic synapse for neuromorphic computing. Adv. Mater. Interfaces. 9(30), 2200562 (2022). https://doi.org/10.1002/ADMI.20220056210.1002/ADMI.202200562 ↗
33. B. Vargas, E. Ramos, E. Pérez-Gutiérrez, J.C. Alonso, D.A. Solis-Ibarra, Direct bandgap Copper–Antimony halide perovskite. J. Am. Chem. Soc. 139(27), 9116–9119 (2017). https://doi.org/10.1021/jacs.7b0411910.1021/jacs.7b04119 ↗
34. N. Singhal, R. Chakraborty, P. Ghosh, A. Nag, Low-Bandgap, Cs 4 CuSb 2 Cl 12 layered double perovskite: Synthesis, reversible thermal Changes, and magnetic interaction. Chem. Asian J. 13(16), 2085–2092 (2018). https://doi.org/10.1002/asia.20180063510.1002/asia.201800635 ↗
35. A. Shyam, A.M. Parameswaran, R. Raju, N.K. Amal Kaitheri, B. Devakumar, R. Swaminathan, A comprehensive study on the impact of Off-Stoichiometry and Mg doping in CuCrO 2 thin films for heterojunction device fabrication. ACS Appl. Electron. Mater. 7(1), 348–359 (2025). https://doi.org/10.1021/acsaelm.4c0183810.1021/acsaelm.4c01838 ↗
36. D. Wu, X. Zhao, Y. Huang, J. Lai, J. Yang, C. Tian, P. He, Q. Huang, X. Tang, Synthesis and CO 2 photoreduction of Lead-Free cesium bismuth halide perovskite nanocrystals. J. Phys. Chem. C 125(33), 18328–18333 (2021). https://doi.org/10.1021/acs.jpcc.1c0511010.1021/acs.jpcc.1c05110 ↗
37. Q. Sun, J. Xu, F. Tao, W. Ye, C. Zhou, J. He, J. Lu, Boosted inner surface charge transfer in perovskite Nanodots@Mesoporous Titania frameworks for efficient and selective photocatalytic CO 2 reduction to methane. Angew. Chem. Int. Ed. 61(20) (2022). https://doi.org/10.1002/anie.20220087210.1002/anie.202200872 ↗
38. Z. Zheng, Q. Hu, H. Zhou, P. Luo, A. Nie, H. Zhu, L. Gan, F. Zhuge, Y. Ma, H. Song, T. Zhai, Submillimeter and Lead-Free Cs 3 Sb 2 Br 9 perovskite nanoflakes: inverse temperature crystallization growth and application for ultrasensitive photodetectors. Nanoscale Horiz. 4(6), 1372–1379 (2019). https://doi.org/10.1039/C9NH00426B10.1039/C9NH00426B ↗
39. Z. Imran, S.S. Batool, H. Jamil, M. Usman, M. Israr-Qadir, S.H. Shah, S. Jamil-Rana, M.A. Rafiq, M.M. Hasan, M. Willander, Excellent humidity sensing properties of cadmium titanate nanofibers. Ceram. Int. 39(1), 457–462 (2013). https://doi.org/10.1016/j.ceramint.2012.06.04810.1016/j.ceramint.2012.06.048 ↗
40. Y. Zhang, X. Pan, Z. Wang, Y. Hu, X. Zhou, Z. Hu, H. Gu, Fast and highly sensitive humidity sensors based on NaNbO 3 nanofibers. RSC Adv. 5(26), 20453–20458 (2015). https://doi.org/10.1039/C5RA00205B10.1039/C5RA00205B ↗
41. K. Ren, L. Huang, S. Yue, S. Lu, K. Liu, M. Azam, Z. Wang, Z. Wei, S. Qu, Z. Wang, Turning a disadvantage into an advantage: synthesizing High-Quality organometallic halide perovskite nanosheet arrays for humidity sensors. J. Mater. Chem. C Mater. 5(10), 2504–2508 (2017). https://doi.org/10.1039/C6TC05165K10.1039/C6TC05165K ↗
42. J.H. Anderson, G.A. Parks, Electrical conductivity of silica gel in the presence of adsorbed water. J. Phys. Chem. 72(10), 3662–3668 (1968). https://doi.org/10.1021/j100856a05110.1021/j100856a051 ↗