journal article·2023-09

Suppressed carrier recombination and boosted open-circuit voltage of indoor organic photovoltaic device with fullerene acceptor

Fenghua Zhang, Xiong Li, Yujiao Yan, Mandi Li, Tao Lin, Jun Zhou, Yaohui Zhu, Denghui Xu

Applied Physics A· Volume 129· Issue 9
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Abstract

Indoor organic photovoltaic provides a promising energy for the off-grid self-power supply technology of the Internet of Things industry. In this work, the indoor organic photovoltaic devices were prepared with wide bandgap polymer PM6 as donor and fullerene derivatives PC71BM as acceptor. The photovoltaic performances, the carrier recombination characteristics, and the molecular packing of the PM6:PC71BM device were studied in detail as compared with the photovoltaic device with non-fullerene acceptor Y6. The matched spectral response range with indoor lighting source and rational energy level alignment of PC71BM suppresses carrier recombination under slim light illumination, improving the open-circuit voltage and fill factor of the prepared fullerene device, and an enhanced power conversion efficiency (PCE) of 18.7% is achieved under white LED illumination with intensity of 1000 Lux, while the PCE of the photovoltaic device with Y6 acceptor is only 14.7%. The superior photovoltaic performance of PM6:PC71BM organic photovoltaic device indicates that fullerene acceptors are effective materials choice for preparing high-performance organic photovoltaic devices under slim light illumination, and fullerene derivatives would play an important role in the preparation of high-efficiency indoor photovoltaic devices for Internet of Things utilization.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · solar cell performance optimization · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Y. Cui, L. Hong, J. Hou, Recent progress of indoor organic photovoltaics—from device performance to multifunctional applications. Organ. Electron. 114, 106736 (2021)
2. M.A. Saeed, S.H. Kim, H. Kim, J. Liang, H.Y. Woo, T.G. Kim, H. Yan, J.W. Shim, Indoor organic photovoltaics: optimal cell design principles with synergistic parasitic resistance and optical modulation effect. Adv. Energy Mater. 11, 2003103 (2021)10.1002/aenm.202003103 ↗
3. X. Xu, W. Liu, X. Luo, H. Chen, Q. Wei, J. Yuan, Y. Zou, An overview of high-performance indoor organic photovoltaics. Chemsuschem 14, 3428–3448 (2021)10.1002/cssc.202100386 ↗
4. V. Pecunia, L.G. Occhipinti, R.L.Z. Hoye, Emerging indoor photovoltaic technologies for sustainable internet of things. Adv. Energy Mater. 11, 2100698 (2021)10.1002/aenm.202100698 ↗
5. H.S. Ryu, S.Y. Park, T.H. Lee, J.Y. Kim, H.Y. Woo, Recent progress in indoor organic photovoltaics. Nanoscale 12, 5792–5804 (2020)10.1039/D0NR00816H ↗
6. Y. Zhang, C. Duan, L. Ding, Indoor organic photovoltaics. Science Bulletin 65, 2040–2042 (2020)10.1016/j.scib.2020.08.030 ↗
7. T. Zhang, C. An, Y. Xu, P. Bi, Z. Chen, J. Wang, N. Yang, Y. Yang, B. Xu, H. Yao, X. Hao, S. Zhang, J. Hou, A medium-bandgap nonfullerene acceptorenabling organic photovoltaic cells with 30% efficiency under indoor artificial light. Adv. Mater. 34, e2207009 (2022)10.1002/adma.202207009 ↗
8. J.K.W. Ho, H. Yin, S.K. So, From 33% to 57% – an elevated potential of efficiency limit for indoor photovoltaics. J. Mater. Chem. A 8, 1717–1723 (2020)10.1039/C9TA11894B ↗
9. X. Hou, Y. Wang, H.K.H. Lee, R. Datt, N. UslarMiano, D. Yan, M. Li, F. Zhu, B. Hou, W.C. Tsoi, Z. Li, Indoor application of emerging photovoltaics—progress, challenges and perspectives. J. Mater. Chem. A 8, 21503–21525 (2020)10.1039/D0TA06950G ↗
10. L.K. Ma, Y. Chen, P.C.Y. Chow, G. Zhang, J. Huang, C. Ma, J. Zhang, H. Yin, A.M. Hong Cheung, K.S. Wong, S.K. So, H. Yan, High-efficiency indoor organic photovoltaics with a band-aligned interlayer. Joule 4, 1486–1500 (2020)10.1016/j.joule.2020.05.010 ↗
11. N.G. An, J.E. Lee, W. Lee, D. Yuk, S. Song, C. Wang, S.-K. Kwon, Y.-H. Kim, J.Y. Kim, Non-fullerene acceptors with alkylthiothiophene side chains for efficient non-halogenated solvent processed indoor organic photovoltaics. J. Mater. Chem. C 10, 15781–15791 (2022)10.1039/D2TC03297J ↗
12. S.Y. Park, C. Labanti, J. Luke, Y.C. Chin, J.S. Kim, Organic bilayer photovoltaics for efficient indoor light harvesting. Adv. Energy Mater. 12, 2103237 (2021)10.1002/aenm.202103237 ↗
13. Y. Yang, Z. Chen, T. Wang, J. Qiao, F. Cui, L. Xu, C. Qin, H. Yin, X. Hao, High performance indoor light harvesters with a wide-gap donor polymer PBDB-T. Organ. Electron. 98, 106289 (2021)10.1016/j.orgel.2021.106289 ↗
14. X. Zhou, H. Wu, B. Lin, H.B. Naveed, J. Xin, Z. Bi, K. Zhou, Y. Ma, Z. Tang, C. Zhao, Q. Zheng, Z. Ma, W. Ma, Different morphology dependence for efficient indoor organic photovoltaics: the role of the leakage current and recombination losses. ACS Appl. Mater. Interfaces 13, 44604–44614 (2021)10.1021/acsami.1c09600 ↗
15. S. Zeiske, W. Li, P. Meredith, A. Armin, O.J. Sandberg, Light intensity dependence of the photocurrent in organic photovoltaic devices. Cell Rep. Phys. Sci. 3, 101096 (2022)10.1016/j.xcrp.2022.101096 ↗
16. M. Cui, A. Lv, Z. Ma, Optimizing the photovoltaic performance of organic solar cells for indoor light harvesting. ChemPhysChem 23, e202200091 (2022)10.1002/cphc.202200091 ↗
17. H. Wang, W. Wang, Y. Zhong, D. Li, Z. Li, X. Xu, X. Song, Y. Chen, P. Huang, A. Mei, H. Han, T. Zhai, X. Zhou, Approaching the external quantum efficiency limit in 2D photovoltaic devices. Adv. Mater. 34, e2206122 (2022)10.1002/adma.202206122 ↗
18. B. Qi, J. Wang, Fill factor in organic solar cells. Phys. Chem. Chem. Phys. 15, 8972–8982 (2013)10.1039/c3cp51383a ↗
19. A. Kramer, W. Kaiser, B. Zhang, L.N.S. Murthy, A. Gagliardi, J.W.P. Hsu, W.G. Vandenberghe, Understanding morphology effects on fill factor losses in dilute-donor organic solar cells. Nano Energy 103, 107793 (2022)10.1016/j.nanoen.2022.107793 ↗
20. Y. Yan, X. Zhou, F. Zhang, J. Zhou, T. Lin, Y. Zhu, D. Xu, X. Ma, Y. Zou, X. Li, High-performance pseudo-bilayer ternary organic solar cells with PC71BM as the third component. J. Mater. Chem. A 10, 23124–23133 (2022)10.1039/D2TA04784E ↗
21. W. Xu, X. Zhu, X. Ma, H. Zhou, X. Li, S.Y. Jeong, H.Y. Woo, Z. Zhou, Q. Sun, F. Zhang, Achieving 15.81% and 15.29% efficiency of all-polymer solar cells based on layer-by-layer and bulk heterojunction structures. J. Mater. Chem. A 10, 13492–13499 (2022)10.1039/D2TA02914F ↗
22. R. Yu, G. Wu, Z. Tan, Realization of high performance for PM6:Y6 based organic photovoltaic cells. J. Energy Chem. 61, 29–46 (2021)10.1016/j.jechem.2021.01.027 ↗
23. Q. Guo, Q. Guo, Y. Geng, A. Tang, M. Zhang, M. Du, X. Sun, E. Zhou, Recent advances in PM6:Y6-based organic solar cells. Mater. Chem. Front. 5, 3257–3280 (2021)10.1039/D1QM00060H ↗
24. X. Zhou, T. Dai, X. Li, Y. Yan, W. Xiong, T. Lin, J. Zhou, D. Xu, Y. Zhu, J. Zhao, A. Geng, Improved charge transport and reduced carrier recombination of nonfullerene organic solar cells with the binary solvent. ACS Appl. Energy Mater. 4, 8175–8182 (2021)10.1021/acsaem.1c01447 ↗
25. F. Liu, L. Zhou, W. Liu, Z. Zhou, Q. Yue, W. Zheng, R. Sun, W. Liu, S. Xu, H. Fan, L. Feng, Y. Yi, W. Zhang, X. Zhu, Organic solar cells with 18% efficiency enabled by an alloy acceptor: a two-in-one strategy. Adv. Mater. 33, e2100830 (2021)10.1002/adma.202100830 ↗
26. M. Nam, C. Lee, D.-H. Ko, Sequentially processed quaternary blends for high-performance indoor organic photovoltaic applications. Chem. Eng. J. 438, 135576 (2022)10.1016/j.cej.2022.135576 ↗
27. Y. Zheng, G. Wang, D. Huang, J. Kong, T. Goh, W. Huang, J. Yu, A.D. Taylor, Binary solvent additives treatment boosts the efficiency of PTB7:PCBM polymer solar cells to over 9.5%. Sol. RRL 2, 1700144 (2018)10.1002/solr.201700144 ↗
28. W. Chen, T. Xu, F. He, W. Wang, C. Wang, J. Strzalka, Y. Liu, J. Wen, D.J. Miller, J. Chen, K. Hong, L. Yu, S.B. Darling, Hierarchical nanomorphologies promote exciton dissociation in polymer/fullerene bulk heterojunction solar cells. Nano Lett. 11, 3707–3713 (2011)10.1021/nl201715q ↗
29. A. Mahmood, J.L. Wang, Review of grazing incidence small-and wide-angle X-ray scattering techniques for exploring the film morphology of organic solar cells. Sol. RRL 4, 2000337 (2020)10.1002/solr.202000337 ↗