Enhanced photoconversion efficiency in cesium-antimony-halide perovskite derivatives by tuning crystallographic dimensionality
Source abstract
Abstract
Abstract Lead-based perovskites have reached prominence in optoelectronic and photovoltaic research, yet their toxicity has prompted the search for alternative lead-free compounds. All-inorganic antimony-/bismuth-halide perovskite derivatives have been identified as a promising class of materials. Despite attractive bulk optoelectronic properties, their optoelectronic device performance has been lagging behind. Here we examine one of their most promising embodiments, the all-inorganic cesium-antimony-halide system. Through solution-based halide mixing, we achieve its structural conversion from a zero-dimensional to a layered phase at processing temperatures
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Research context
OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · Quantum Dots Synthesis And Properties
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References (70)
Show source-provided references
1. Methylammonium chloride induces intermediate phase stabilization for efficient perovskite solar cells10.1016/j.joule.2019.06.014 ↗
2. Quantum dots supply bulk- and surface-passivation agents for efficient and stable perovskite solar cells10.1016/j.joule.2019.05.005 ↗
3. Photovoltaic solar cell technologies: analysing the state of the art10.1038/s41578-019-0097-0 ↗
4. Halide perovskite photovoltaics: background, status, and future prospects10.1021/acs.chemrev.8b00539 ↗
5. Tuning the luminescence of layered halide perovskites10.1021/acs.chemrev.8b00477 ↗
6. Photodetectors based on organic–inorganic hybrid lead halide perovskites10.1002/advs.201700256 ↗
7. Ambient blade coating of mixed cation, mixed halide perovskites without dripping: in situ investigation and highly efficient solar cells10.1039/C9TA12890E ↗
8. Kinetic stabilization of the sol-gel state in perovskites enables facile processing of high-efficiency solar cells
9. Impact of the solvation state of lead iodide on its two‐step conversion to MAPBI3: an in situ investigation10.1002/adfm.201807544 ↗
10. Room‐temperature partial conversion of α‐FAPbI3 perovskite phase via PbI2 solvation enables high‐performance solar cells10.1002/adfm.201907442 ↗
11. NREL, N.R.E.L. Research cell record efficiency chart, (2019). https://www.nrel.gov/pv/cell-efficiency.html(accessed September 25, 2019).
12. Toxicity of organometal halide perovskite solar cells10.1038/nmat4572 ↗
13. Perovskite-inspired lead-free Ag2BiI5 for self-powered NIR-blind visible light photodetection10.1007/s40820-020-0371-0 ↗
14. Opportunities and challenges of lead-free perovskite optoelectronic devices10.1016/j.trechm.2019.04.004 ↗
15. Recent progress in lead-free perovskite (-like) solar cells10.1016/j.mtener.2018.03.001 ↗
16. Perovskite solar cells go lead free10.1016/j.joule.2017.09.007 ↗
17. Research update: bismuth-based perovskite-inspired photovoltaic materials10.1063/1.5029484 ↗
18. Bismuth‐based perovskite‐inspired solar cells: in situ diagnostics reveal similarities and differences in the film formation of bismuth‐ and lead‐based films10.1002/solr.201800305 ↗
19. Green fabrication of stable lead-free bismuth based perovskite solar cells using a non-toxic solvent10.1038/s42004-019-0195-3 ↗
20. From lead halide perovskites to lead-free metal halide perovskites and perovskite derivatives10.1002/adma.201803792 ↗
21. Beyond methylammonium lead iodide: prospects for the emergent field of ns2 containing solar absorbers
22. Methylammonium bismuth iodide as a lead-free, stable hybrid organic-inorganic solar absorber10.1002/chem.201505055 ↗
23. Optoelectronic properties of (CH3NH3)3Sb2I9 thin films for photovoltaic applications10.1021/acsenergylett.6b00170 ↗
24. A-site cation in inorganic A3Sb2I9 perovskite influences structural dimensionality, exciton binding energy, and solar cell performance10.1021/acs.chemmater.8b00676 ↗
25. Organic-inorganic bismuth (III)-based material: a lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites10.1007/s12274-015-0948-y ↗
26. Thin-film preparation and characterization of Cs3Sb2I9: a lead-free layered perovskite semiconductor10.1021/acs.chemmater.5b01989 ↗
27. Crystal and electronic structures of complex bismuth iodides A3Bi2I9 (A = K, Rb, Cs) related to perovskite: aiding the rational design of photovoltaics10.1021/acs.chemmater.5b03147 ↗
28. Rb as an alternative cation for templating inorganic lead-free perovskites for solution processed photovoltaics10.1021/acs.chemmater.6b03310 ↗
29. Photovoltaic performance of vapor-assisted solution-processed layer polymorph of Cs3Sb2I910.1021/acsami.7b16349 ↗
30. Dimensionality controlling of Cs3Sb2I9 for efficient all-inorganic planar thin film solar cells by HCl-assisted solution method10.1002/adom.201801368 ↗
31. Influence of the iodide to bromide ratio on crystallographic and optoelectronic properties of rubidium antimony halide perovskites10.1021/acsaem.8b01572 ↗
32. High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells10.1038/nature18306 ↗
33. Fine multi‐phase alignments in 2D perovskite solar cells with efficiency over 17% via slow post‐annealing10.1002/adma.201903889 ↗
34. Dynamical transformation of two-dimensional perovskites with alternating cations in the interlayer space for high-performance photovoltaics10.1021/jacs.8b13104 ↗
35. Factors determining the vertical orientation of two-dimensional perovskites10.1039/C9CE00631A ↗
36. Low-temperature synthesis TiOx passivation layer for organic-silicon heterojunction solar cell with a high open-circuit voltage10.1016/j.nanoen.2017.02.024 ↗
37. Trap healing for high-performance low-voltage polymer transistors and solution-based analog amplifiers on foil10.1002/adma.201606938 ↗
38. Reconstructive phase transformation and kinetics of Cs3Sb2I9 by means of Rietveld analysis of X-ray diffraction and 127INQR10.1006/jssc.1997.7562 ↗
39. Alloy-induced phase transition and enhanced photovoltaic performance: the case of Cs3Bi2I9−xBrx perovskite solar cells10.1039/C9TA01978B ↗
40. From 0D Cs3Bi2I9 to 2D Cs3Bi2I6Cl3: dimensional expansion induces a direct band gap but enhances electron–phonon coupling10.1021/acs.chemmater.9b00636 ↗
41. Anionic order and band gap engineering in vacancy ordered triple perovskites10.1039/C8CC09947B ↗
42. Chlorine-incorporation-induced formation of the layered phase for antimony-based lead-free perovskite solar cells10.1021/jacs.7b10739 ↗
43. Cs3Sb2I9 and Cs3Bi2I9 with the hexagonal Cs3Cr2Cl9 structure type10.1107/S0567740878003684 ↗
44. Kinetics of precipitation
45. The growth of crystals and the equilibrium structure of their surfaces
46. Scanning Electron Microscopy
47. Scanning Electron Microscopy and X-Ray Microanalysis
48. Detailed balance limit of efficiency of p‐n junction solar cells10.1063/1.1736034 ↗
49. Technology and market perspective for indoor photovoltaic cells10.1016/j.joule.2019.03.026 ↗
50. Efficiency and spectral performance of narrowband organic and perovskite photodetectors: a cross-sectional review10.1088/2515-7639/ab336a ↗
51. Addition of adamantylammonium iodide to hole transport layers enables highly efficient and electroluminescent perovskite solar cells10.1039/C8EE02404A ↗
52. High-bandgap perovskite materials for multijunction solar cells10.1016/j.joule.2018.05.008 ↗
53. Recombination processes in insulators and semiconductors10.1103/PhysRev.97.322 ↗
54. A new mechanism for superlinear photoconductivity with relevance to amorphous silicon10.1063/1.355310 ↗
55. Performance of photoconductors10.1109/JRPROC.1955.278047 ↗
56. Double extraction of uniformly generated electron-hole pairs from insulators with noninjecting contacts10.1063/1.1660633 ↗
57. Field nonuniformity due to photogenerated carriers in a p-i-n solar cell
58. Bube · 1992
59. Hall measurements on low-mobility materials and high resistivity materials
60. The effects of crystallinity on charge transport and the structure of sequentially processed F4TCNQ-doped conjugated polymer films10.1002/adfm.201702654 ↗
61. Combined charge carrier transport and photoelectrochemical characterization of BiVO4 single crystals: intrinsic behavior of a complex metal oxide10.1021/ja405550k ↗
62. Electrical characterization of Cu(In,Ga)Se2 thin films peeled off from Mo-coated soda-lime glass substrate by AC Hall measurement10.7567/JJAP.54.018001 ↗
63. A universal interface layer based on an amine-functionalized fullerene derivative with dual functionality for efficient solution processed organic and perovskite solar cells10.1002/aenm.201401692 ↗
64. The effect of structural dimensionality on carrier mobility in lead-halide perovskites10.1039/C9TA05241K ↗
65. Organic Narrowband Photodetectors: Materials, devices and applications
66. Improve efficiency of perovskite solar cells by using Magnesium doped ZnO and TiO2 compact layers10.1016/j.spmi.2016.01.026 ↗
67. New strategy to overcome the instability that could speed up the commercialization of perovskite solar cells10.1002/admi.201900134 ↗
68. Facile and novel chemical synthesis, characterization, and formation mechanism of copper sulfide (Cu2S, Cu2S/CuS, CuS) nanostructures for increasing the efficiency of solar cells10.1021/acs.jpcc.5b11566 ↗
69. Facile synthesis of graphene quantum dots from corn powder and their application as down conversion effect in quantum dot-dye-sensitized solar cell10.1016/j.molliq.2017.12.059 ↗
70. Wavelength conversion effect-assisted dye-sensitized solar cells for enhanced solar light harvesting10.1039/C6TA04526J ↗